2D Perovskite Micro-optics Enabled by Direct Femtosecond-Laser Projection Lithography

Using direct femtosecond-laser projection lithography in chemically synthesized CsPbBr3 perovskite microcrystals we demonstrate high-throughput fabrication of advanced binary microscale optical elements for nanofocusing as well as generation of high-order optical vortex beams. The obtained results highlight the CsPbBr3 microcrystals as a promising material for realization of various complicated 2D micro-optical elements and holograms that can be directly imprinted using non-destructive and practically relevant laser technologies.

Defects and Morphology Contribution to Photoluminescence of CH3NH3PbI3 Nanostructured by Femtosecond Laser Pulses

Despite basic optoelectronic properties of metal-organic perovskites are quite robust to defects, thelatter affect performance of related photovoltaic devices made of such promising materials. Recently,direct femtosecond projection lithography appeared as prospective tool for high-performing nondestructivenano- and microstructuring of perovskite films. Here, we study in details how defects affectthe photoluminescence properties of CH3NH3PbI3 hybrid perovskite films patterned with single- andmulti-pulse irradiation with flat-top femtosecond laser pulses. Scanning electron, wide-field multiphoton,photoluminescence and laser confocal microscopies being combined with photoluminescencedecay measurements are carried out for these studies. The obtained experimental results are analyzedwith a model for carriers kinetics allowed to determine contributions from radiative and non-radiative processes.