Ultrafast Deep-Ultraviolet Laser-Induced Voltage Response of Pyrite

Ultrafast, high-sensitivity deep-ultraviolet (UV) photodetectors are crucial for practical applications, including optical communication, ozone layer monitoring, flame detection, etc. However, fast-response UV photodetectors based on traditional materials suffer from issues of expensive production processes. Here, we focused on pyrite with simultaneously cheap production processes and ultrafast response speed. Nanoseconds photovoltaic response was observed under UV pulsed laser irradiation without an applied bias at room temperature. In addition, the response time of the laser-induced voltage (LIV) signals was ~20 ns, which was the same as the UV laser pulse width. The maximum value of the responsivity is 0.52 V/mJ and the minimum value of detectivity was about to ~1.4 × 1013 Jones. When there exists nonuniform illumination, a process of diffusion occurs by which the carriers migrate from the region of high concentration toward the region of low concentration. The response speed is limited by a factor of the diffusion of the carriers. With an increment in laser energy, the response speed of LIV is greatly improved. The high response speed combined with low-cost fabrication makes these UV photodetectors highly attractive for applications in ultrafast detection.

Research and Progress of Transparent, Flexible Tin Oxide Ultraviolet Photodetector

Optical detection is of great significance in various fields such as industry, military, and medical treatment, especially ultraviolet (UV) photodetectors. Moreover, as the demand for wearable devices continues to increase, the UV photodetector, which is one of the most important sensors, has put forward higher requirements for bending resistance, durability, and transparency. Tin oxide (SnO2) has a wide band gap, high ultraviolet exciton gain, etc., and is considered to be an ideal material for preparing UV photodetectors. At present, SnO2-based UV photodetectors have a transparency of more than 70% in the visible light region and also have excellent flexibility of 160% tensile strain. Focusing on SnO2 nanostructures, the article mainly summarizes the progress of SnO2 UV photodetectors in flexibility and transparency in recent years and proposes feasible optimization directions and difficulties.