p-Type Dye-Sensitized Solar Cells with a CdSeS Quantum-Dot-Sensitized NiO Photocathode for Outstanding Short-Circuit Current

2015 ◽  
Vol 32 (12) ◽  
pp. 1078-1082 ◽  
Author(s):  
Wenping Kong ◽  
Shengjun Li ◽  
Zeng Chen ◽  
Chaochao Wei ◽  
Wei Li ◽  
...  
2018 ◽  
Vol 6 (45) ◽  
pp. 22508-22512 ◽  
Author(s):  
Naohiko Kato ◽  
Shinya Moribe ◽  
Masahito Shiozawa ◽  
Ryo Suzuki ◽  
Kazuo Higuchi ◽  
...  

To realize highly efficient solid-state dye-sensitized solar cells (SDSCs), the absorption range of the dye should be extended to the near-IR range to increase short-circuit current density (Jsc); a high Jsc in turn requires a highly conductive p-type semiconductor.


2010 ◽  
Vol 123-125 ◽  
pp. 284-287 ◽  
Author(s):  
Xue Ming Lü ◽  
Xiao Ping Zou ◽  
Jin Cheng ◽  
Gong Qing Teng ◽  
Xiang Min Meng ◽  
...  

As a kind of semiconducting and promising material, ZnO has been extensively used in dye-sensitized solar cells (DSSCs). Quantum dot sensitized solar cells (QDSSCs) has more potential to increase the efficiency of solar cells compared with DSSCs. Here we developed a simple and effective way to fabricate ZnO porous plate films by electrochemical deposition and anneal in air on ITO-coated glass substrates. CdS quantum dots were attached to the surface of the porous plate films by chemical bath deposition technique. Quantum dot-sensitized ZnO porous plate films solar cells exhibited short-circuit current ranging from 0.22-0.57mA/cm2 and open-circuit voltage of 0.42 -0.57V when illuminated with 100 mW/cm2 simulated AM 1.5 G irradiation.


2021 ◽  
Vol 1016 ◽  
pp. 863-868
Author(s):  
Tika Erna Putri ◽  
Yuan Hao ◽  
Fadzai Lesley Chawarambwa ◽  
Hyunwoong Seo ◽  
Min Kyu Son ◽  
...  

The losses of solar cells are consisted of electrical losses and optical losses. Optical losses chiefly reduce the short-circuit current. Here we apply bifacial cell approach to increase light absorption and the short-circuit current of dye sensitized solar cells (DSSCs). We have employed activated carbon (AC) as a very low cost counter electrode, an alternative to Pt counter electrode. Addition of dimethyl sulfoxide (DMSO) and titanium carbonitride (TiCN) to AC increase the efficiency of bifacial DSSC at a mirror angle of from 5.10% to and , respectively. These results indicate that AC has the potential to replace Pt as a very low cost counter electrode of bifacial DSSCs. The bifacial DSSC system using double plane mirrors improve PCE to for Pt counter electrode at a mirror angle of , and for AC counter electrode at a mirror angle of , respectively.


Materials ◽  
2020 ◽  
Vol 13 (13) ◽  
pp. 2936
Author(s):  
Junfeng Wei ◽  
Zhipeng Shao ◽  
Bin Pan ◽  
Shuanghong Chen ◽  
Linhua Hu ◽  
...  

The tandem pn-type dye-sensitized solar cells (pn-DSCs) have received much attention in the field of photovoltaic technologies because of their great potential to overcome the Shockley-Queisser efficiency limitation that applies to single junction photovoltaic devices. However, factors governing the short-circuit current densities (Jsc) of pn-DSC remain unclear. It is typically believed that Jsc of the pn-DSC is limited to the highest one that the two independent photoelectrodes can achieve. In this paper, however, we found that the available Jsc of pn-DSC is always determined by the larger Jsc that the photoanode can achieve but not by the smaller one in the photocathode. Such experimental findings were verified by a simplified series circuit model, which shows that a breakdown will occur on the photocathode when the photocurrent goes considerably beyond its threshold voltage, thus leading to an abrupt increase in Jsc of the circuit. The simulation results also suggest that a higher photoconversion efficiency of the pn-DSCs can be only achieved when an almost equivalent photocurrent is achieved for the two photoelectrodes.


BIBECHANA ◽  
2015 ◽  
Vol 13 ◽  
pp. 23-28
Author(s):  
Leela Pradhan Joshi

Aluminium doped Zinc Oxide (AZO) seed layers were deposited on Fluorine doped Tin Oxide (FTO) substrates using a spin coating technique. These were then immersed in growth solutions of zinc nitrate, hexamethylenetetramine and distilled water to develop nanoplates of Zinc Oxide (ZnO). The nanostructures of ZnO grown on FTO were studied using x-ray diffraction techniques. Dye-sensitized solar cells (DSSC) were fabricated using two prepared electrodes, one of dye-loaded zinc oxide and another that was platinum coated. The electrolyte used was potassium iodide iodine solution. The performance of the assembled DSCCs was tested by drawing an IV curve. The results showed that the short circuit current and open circuit voltages were about 10 microamperes and 270 millivolts respectively.BIBECHANA 13 (2016) 23-28


2014 ◽  
Vol 32 (4) ◽  
pp. 547-554 ◽  
Author(s):  
Hatem El-Ghamri ◽  
Taher El-Agez ◽  
Sofyan Taya ◽  
Monzir Abdel-Latif ◽  
Amal Batniji

AbstractThe application of natural dyes extracted from plant seeds in the fabrication of dye-sensitized solar cells (DSSCs) has been explored. Ten dyes were extracted from different plant seeds and used as sensitizers for DSSCs. The dyes were characterized using UV-Vis spectrophotometry. DSSCs were prepared using TiO2 and ZnO nanostructured mesoporous films. The highest conversion efficiency of 0.875 % was obtained with an allium cepa (onion) extract-sensitized TiO2 solar cell. The process of TiO2-film sintering was studied and it was found that the sintering procedure significantly affects the response of the cell. The short circuit current of the DSSC was found to be considerably enhanced when the TiO2 semiconducting layer was sintered gradually.


Materials ◽  
2019 ◽  
Vol 12 (24) ◽  
pp. 4181 ◽  
Author(s):  
Mariia Karpacheva ◽  
Vanessa Wyss ◽  
Catherine E. Housecroft ◽  
Edwin C. Constable

By systematic tuning of the components of the electrolyte, the performances of dye-sensitized solar cells (DSCs) with an N-heterocyclic carbene iron(II) dye have been significantly improved. The beneficial effects of an increased Li+ ion concentration in the electrolyte lead to photoconversion efficiencies (PCEs) up to 0.66% for fully masked cells (representing 11.8% relative to 100% set for N719) and an external quantum efficiency maximum (EQEmax) up to approximately 25% due to an increased short-circuit current density (JSC). A study of the effects of varying the length of the alkyl chain in 1-alkyl-3-methylimidazolium iodide ionic liquids (ILs) shows that a longer chain results in an increase in JSC with an overall efficiency up to 0.61% (10.9% relative to N719 set at 100%) on going from n-methyl to n-butyl chain, although an n-hexyl chain leads to no further gain in PCE. The results of electrochemical impedance spectroscopy (EIS) support the trends in JSC and open-circuit voltage (VOC) parameters. A change in the counterion from I− to [BF4]− for 1-propyl-3-methylimidazolium iodide ionic liquid leads to DSCs with a remarkably high JSC value for an N-heterocyclic carbene iron(II) dye of 4.90 mA cm−2, but a low VOC of 244 mV. Our investigations have shown that an increased concentration of Li+ in combination with an optimized alkyl chain length in the 1-alkyl-3-methylimidazolium iodide IL in the electrolyte leads to iron(II)-sensitized DSC performances comparable with those of containing some copper(I)-based dyes.


2017 ◽  
Vol 8 ◽  
pp. 287-295 ◽  
Author(s):  
Saif Saadaoui ◽  
Mohamed Aziz Ben Youssef ◽  
Moufida Ben Karoui ◽  
Rached Gharbi ◽  
Emanuele Smecca ◽  
...  

In this work, two natural dyes extracted from henna and mallow plants with a maximum absorbance at 665 nm were studied and used as sensitizers in the fabrication of dye-sensitized solar cells (DSSCs). Fourier transform infrared (FTIR) spectra of the extract revealed the presence of anchoring groups and coloring constituents. Two different structures were prepared by chemical bath deposition (CBD) using zinc oxide (ZnO) layers to obtain ZnO nanowall (NW) or nanorod (NR) layers employed as a thin film at the photoanode side of the DSSC. The ZnO layers were annealed at different temperatures under various gas sources. Indeed, the forming gas (FG) (N2/H2 95:5) was found to enhance the conductivity by a factor of 103 compared to nitrogen (N2) or oxygen (O2) annealing gas. The NR width varied between 40 and 100 nm and the length from 500 to 1000 nm, depending on the growth time. The obtained NWs had a length of 850 nm. The properties of the developed ZnO NW and NR layers with different thicknesses and their effect on the photovoltaic parameters were studied. An internal coverage of the ZnO NWs was also applied by the deposition of a thin TiO2 layer by reactive sputtering to improve the cell performance. The application of this layer increased the overall short circuit current J sc by seven times from 2.45 × 10−3 mA/cm2 to 1.70 × 10−2 mA /cm2.


Sign in / Sign up

Export Citation Format

Share Document