Cyclic homo and block copolymers through sequential double click reactions

2010 ◽  
Vol 48 (22) ◽  
pp. 5083-5091 ◽  
Author(s):  
Hakan Durmaz ◽  
Aydan Dag ◽  
Gurkan Hizal ◽  
Umit Tunca
2015 ◽  
Vol 15 (9) ◽  
pp. 1233-1241 ◽  
Author(s):  
Gizem Oyman Eyrilmez ◽  
Sean Doran ◽  
Eljesa Murtezi ◽  
Bilal Demir ◽  
Dilek Odaci Demirkol ◽  
...  

2010 ◽  
Vol 1 (5) ◽  
pp. 621 ◽  
Author(s):  
Aydan Dag ◽  
Hakan Durmaz ◽  
Volkan Kirmizi ◽  
Gurkan Hizal ◽  
Umit Tunca

2013 ◽  
Vol 46 (4) ◽  
pp. 1296-1304 ◽  
Author(s):  
Meng Zhang ◽  
Paul A. Rupar ◽  
Chun Feng ◽  
Kaixiang Lin ◽  
David J. Lunn ◽  
...  

2015 ◽  
Vol 6 (21) ◽  
pp. 3913-3917 ◽  
Author(s):  
Bing Huang ◽  
Min Chen ◽  
Shuxue Zhou ◽  
Limin Wu

A novel and reactive A(B-b-C)20 miktoarm star-shaped block copolymer has been successfully synthesized through ATRP reaction combined with click reactions.


2008 ◽  
Vol 46 (21) ◽  
pp. 7091-7100 ◽  
Author(s):  
Hakan Durmaz ◽  
Aydan Dag ◽  
Alp Hizal ◽  
Gurkan Hizal ◽  
Umit Tunca

2009 ◽  
Vol 111 (1) ◽  
pp. 560-565 ◽  
Author(s):  
Xiaohua He ◽  
Liyuan Liang ◽  
Kai Wang ◽  
Shaoliang Lin ◽  
Deyue Yan ◽  
...  

2002 ◽  
Vol 724 ◽  
Author(s):  
Elizabeth R. Wright ◽  
R. Andrew McMillan ◽  
Alan Cooper ◽  
Robert P. Apkarian ◽  
Vincent P. Conticello

AbstractTriblock copolymers have traditionally been synthesized with conventional organic components. However, triblock copolymers could be synthesized by the incorporation of two incompatible protein-based polymers. The polypeptides would differ in their hydrophobicity and confer unique physiochemical properties to the resultant materials. One protein-based polymer, based on a sequence of native elastin, that has been utilized in the synthesis of biomaterials is poly (Valine-Proline-Glycine-ValineGlycine) or poly(VPGVG) [1]. This polypeptide has been shown to have an inverse temperature transition that can be adjusted by non-conservative amino acid substitutions in the fourth position [2]. By combining polypeptide blocks with different inverse temperature transition values due to hydrophobicity differences, we expect to produce amphiphilic polypeptides capable of self-assembly into hydrogels. Our research examines the design, synthesis and characterization of elastin-mimetic block copolymers as functional biomaterials. The methods that are used for the characterization include variable temperature 1D and 2D High-Resolution-NMR, cryo-High Resolutions Scanning Electron Microscopy and Differential Scanning Calorimetry.


Author(s):  
Mark J. Newman ◽  
Jeffrey K. Actor ◽  
Mannersamy Balusubramanian ◽  
Chinnaswamy Jagannath
Keyword(s):  

2019 ◽  
Author(s):  
Jacob Ishibashi ◽  
Yan Fang ◽  
Julia Kalow

<p>Block copolymers are used to construct covalent adaptable networks that employ associative exchange chemistry (vitrimers). The resulting vitrimers display markedly different nanostructural, thermal and rheological properties relative to those of their statistical copolymer-derived counterparts. This study demonstrates that prepolymer sequence is a versatile strategy to modify the properties of vitrimers.</p>


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