ChemInform Abstract: Allylsilanes in Organic Synthesis: Stereoselective Synthesis of trans- Alkene Peptide Isosteres.

ChemInform ◽  
2010 ◽  
Vol 27 (4) ◽  
pp. no-no
Author(s):  
M. J. DALY ◽  
R. A. WARD ◽  
D. F. THOMPSON ◽  
G. PROCTER
Keyword(s):  
Organic Synthesis ◽  
Stereoselective Synthesis ◽  
Peptide Isosteres

Allylsilanes in organic synthesis; stereoselective synthesis of trans-alkene peptide isosteres

1995 ◽  
Vol 36 (41) ◽  
pp. 7545-7548 ◽  
Author(s):  
Matthew J. Daly ◽  
Richard A. Ward ◽  
David F. Thompson ◽  
Garry Procter
Keyword(s):  
Organic Synthesis ◽  
Stereoselective Synthesis ◽  
Peptide Isosteres

Synergistic Catalysis for Stereodivergent Synthesis of trans- and cis-Skipped Dienes

Synlett ◽  
2020 ◽  
Vol 31 (18) ◽  
pp. 1741-1746
Author(s):  
Shenqqing Zhu ◽  
Lingling Chu ◽  
Fang Wang
Keyword(s):  
Transition Metal ◽  
Organic Synthesis ◽  
Stereoselective Synthesis ◽  
Triplet Energy ◽  
Synergistic Catalysis ◽  
The Cross ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Vinyl Triflates

Catalytic, stereoselective synthesis of skipped dienes is an important topic in organic synthesis. Summarized here are the transition-metal-catalyzed stereoselective approaches and a new, photoinduced stereodivergent strategy reported by our group recently. Our strategy utilizes a synergistic photoredox/nickel protocol to enable the cross-electrophile coupling of allylic carbonates and vinyl triflates to construct 1,4-dienes, the stereoselectivity of which was tuned by the triplet energy (E T) photocatalysts employed, offering a convenient and stereodivergent solution to (E)- and (Z)-1,4-dienes from one set of substrates.

Sign in / Sign up

Export Citation Format

Share Document