Silafunctional compounds in organic synthesis. 46. Platinum-catalyzed intramolecular hydrosilation of allylamines: formation of 1-aza-2-silacyclobutanes and application to stereoselective synthesis of 2-amino alcohols

1990 ◽  
Vol 55 (11) ◽  
pp. 3438-3439 ◽  
Author(s):  
Kohei Tamao ◽  
Yoshiki Nakagawa ◽  
Yoshihiko Ito
Keyword(s):  
Organic Synthesis ◽  
Stereoselective Synthesis ◽  
Amino Alcohols

Direct Stereoselective Synthesis of Enantiomerically Pure anti-β-Amino Alcohols

2014 ◽  
Vol 79 (15) ◽  
pp. 6775-6782 ◽  
Author(s):  
Gastón Silveira-Dorta ◽  
Osvaldo J. Donadel ◽  
Víctor S. Martín ◽  
José M. Padrón
Keyword(s):  
Stereoselective Synthesis ◽  
Amino Alcohols ◽  
Enantiomerically Pure

Stereoselective synthesis of anti-2-oxazolidinones by Ph3P–CCl4–Et3N mediated SN2 cyclization of N-Boc-β-amino alcohols

2003 ◽  
Vol 44 (33) ◽  
pp. 6323-6325 ◽  
Author(s):  
G Madhusudhan ◽  
G Om Reddy ◽  
J Ramanatham ◽  
P.K Dubey
Keyword(s):  
Stereoselective Synthesis ◽  
Amino Alcohols

Synergistic Catalysis for Stereodivergent Synthesis of trans- and cis-Skipped Dienes

Synlett ◽  
2020 ◽  
Vol 31 (18) ◽  
pp. 1741-1746
Author(s):  
Shenqqing Zhu ◽  
Lingling Chu ◽  
Fang Wang
Keyword(s):  
Transition Metal ◽  
Organic Synthesis ◽  
Stereoselective Synthesis ◽  
Triplet Energy ◽  
Synergistic Catalysis ◽  
The Cross ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Vinyl Triflates

Catalytic, stereoselective synthesis of skipped dienes is an important topic in organic synthesis. Summarized here are the transition-metal-catalyzed stereoselective approaches and a new, photoinduced stereodivergent strategy reported by our group recently. Our strategy utilizes a synergistic photoredox/nickel protocol to enable the cross-electrophile coupling of allylic carbonates and vinyl triflates to construct 1,4-dienes, the stereoselectivity of which was tuned by the triplet energy (E T) photocatalysts employed, offering a convenient and stereodivergent solution to (E)- and (Z)-1,4-dienes from one set of substrates.

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