Mono-substituted amine-oligosilsesquioxanes as functional tools in Pd(ii) coordination chemistry: synthesis and properties

The unexpected reaction between mono-functionalized amino-POSS and palladium acetate (different from the well-known pathway between a classical amine and a palladium salt) leads to novel coordination entities.

Palladium salt and functional reduced graphene oxide complex: in situ preparation of a generally applicable catalyst for C–C coupling reactions

A simple scheme of Pd2+ fixed on FRGO as a highly efficient coupling catalyst.

Palladium-catalyzed oxidative carbonylative coupling of arylboronic acids with terminal alkynes to alkynones

The first example of palladium-catalyzed oxidative carbonylation of arylboronic acids with terminal alkynes has been developed. By an appropriate combination of a palladium salt, a ligand, and an oxidant, the desired alkynones were isolated in moderate to good yields.