Palladium-catalyzed oxidative carbonylative coupling of arylboronic acids with terminal alkynes to alkynones

2014 ◽  
Vol 12 (30) ◽  
pp. 5590-5593 ◽  
Author(s):  
Kishore Natte ◽  
Jianbin Chen ◽  
Helfried Neumann ◽  
Matthias Beller ◽  
Xiao-Feng Wu
Keyword(s):  
Oxidative Carbonylation ◽  
Terminal Alkynes ◽  
Arylboronic Acids ◽  
Palladium Catalyzed ◽  
Palladium Salt

The first example of palladium-catalyzed oxidative carbonylation of arylboronic acids with terminal alkynes has been developed. By an appropriate combination of a palladium salt, a ligand, and an oxidant, the desired alkynones were isolated in moderate to good yields.

ChemInform Abstract: Palladium-Catalyzed Oxidative Carbonylative Coupling of Arylboronic Acids with Terminal Alkynes to Alkynones.

ChemInform ◽  
2015 ◽  
Vol 46 (1) ◽  
Author(s):  
Kishore Natte ◽  
Jianbin Chen ◽  
Helfried Neumann ◽  
Matthias Beller ◽  
Xiao-Feng Wu
Keyword(s):  
Terminal Alkynes ◽  
Arylboronic Acids ◽  
Palladium Catalyzed

Palladium-catalyzed carbonylation of 1,5-cyclooctadiene. Effects of temperature and pressure

1991 ◽  
Vol 56 (3) ◽  
pp. 663-672 ◽  
Author(s):  
Curtis B. Anderson ◽  
Rade Marković
Keyword(s):  
Carbon Monoxide ◽  
Oxidative Carbonylation ◽  
Influence Of Temperature ◽  
Carbonylation Reaction ◽  
Palladium Catalyzed ◽  
Effects Of Temperature ◽  
Temperature And Pressure

The influence of temperature and carbon monoxide pressure on the course of oxidative carbonylation reaction of 1,5-cyclooctadiene in the presence of the palladium(II) salts as a catalyst, was investigated.

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