Cobalt(II) nitrate promoted cyclization of benzoyl hydrazone for the synthesis of 2,5-diphenyl-1,3,4-oxadiazole derivatives

A Co(NO3)2 method to promote cyclization of benzoyl hydrazone for the formation of 2,5-diphenyl-1,3,4-oxadiazoles has been developed. The reaction proceeded smoothly and was promoted by Co(NO3)2 under air at 110 °C in DCE; 16 examples of products were obtained.

Additive-free photo-mediated oxidative cyclization of pyridinium acylhydrazones to 1,3,4-oxadiazoles: solid-state conversion in a microporous organic polymer and supramolecular energy-level engineering

We discovered the efficient catalyst-free, photo-mediated oxidative cyclization reaction of bis-p-pyridinium benzoyl hydrazone (BH1) to 2-pyridinium-5-phenyl-1,3,4-oxadiazoles.

Synthesis and self-sensitized photo-oxidation of 2-fulleropyrrolines by palladium(ii)-catalyzed heteroannulation of [60]fullerene with benzoyl hydrazone esters

A Pd(OAc)2-catalyzed N-heteroannulation reaction was exploited to synthesize N-unsubstituted 2-fulleropyrrolines and the photo-oxidation of 2-fulleropyrrolines was first investigated.

SYNTHESIS AND CHARACTERIZATION OF COBALT (III) COMPLEX OF SALICYLALDEHYDE BENZOYL HYDRAZONE

Cobalt Complex of type [Co(Hsbh)2(NO3)(H2O)]. 3H2O was synthesized and characterized by different analytical procedures, molar conductance, infrared and electronic spectral studies. The complex was found to be 1:2 metal ligand ratio. Molar conductance measurement shows non electrolyte nature of complex. Dehydration studies indicate the presence of coordinated as well as lattice water molecules. Infrared spectral studies indicate that ligand undergo keto enol tautomerism and bond to the metal ion via enolic oxygen and NH2 group. The electronic spectrum shows octahedral geometry around central cobalt (III) atom.Journal of Institute of Science and TechnologyVolume 22, Issue 1, July 2017, page: 132-136