Synthesis and self-sensitized photo-oxidation of 2-fulleropyrrolines by palladium(ii)-catalyzed heteroannulation of [60]fullerene with benzoyl hydrazone esters

2018 ◽  
Vol 16 (45) ◽  
pp. 8845-8853 ◽  
Author(s):  
Tian Zheng ◽  
Dong-Shi Shan ◽  
Bo Jin ◽  
Ru-Fang Peng

A Pd(OAc)2-catalyzed N-heteroannulation reaction was exploited to synthesize N-unsubstituted 2-fulleropyrrolines and the photo-oxidation of 2-fulleropyrrolines was first investigated.

2021 ◽  
Vol 168 ◽  
pp. 591-600
Author(s):  
Mohammad Ekrami ◽  
Zahra Emam-Djomeh ◽  
Parham Joolaei-Ahranjani ◽  
Shaghayegh Mahmoodi ◽  
Sina Khaleghi

1939 ◽  
Vol 35 ◽  
pp. 559 ◽  
Author(s):  
A. E. Callow ◽  
R. O. Griffith ◽  
A. McKeown
Keyword(s):  

Author(s):  
Sunduz Sezer Kiralan ◽  
Sermin Goksu Karagoz ◽  
Gulcan Ozkan ◽  
Mustafa Kiralan ◽  
Onur Ketenoglu

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ayse N. Koyun ◽  
Julia Zakel ◽  
Sven Kayser ◽  
Hartmut Stadler ◽  
Frank N. Keutsch ◽  
...  

AbstractSurface microstructures of bitumen are key sites in atmospheric photo-oxidation leading to changes in the mechanical properties and finally resulting in cracking and rutting of the material. Investigations at the nanoscale remain challenging. Conventional combination of optical microscopy and spectroscopy cannot resolve the submicrostructures due to the Abbe restriction. For the first time, we report here respective surface domains, namely catana, peri and para phases, correlated to distinct molecules using combinations of atomic force microscopy with infrared spectroscopy and with correlative time of flight—secondary ion mass spectrometry. Chemical heterogeneities on the surface lead to selective oxidation due to their varying susceptibility to photo-oxidation. It was found, that highly oxidized compounds, are preferentially situated in the para phase, which are mainly asphaltenes, emphasising their high oxidizability. This is an impressive example how chemical visualization allows elucidation of the submicrostructures and explains their response to reactive oxygen species from the atmosphere.


2019 ◽  
Vol 7 (5) ◽  
pp. 2253-2260 ◽  
Author(s):  
Quanquan Shi ◽  
Guicheng Ping ◽  
Xiaojia Wang ◽  
Hui Xu ◽  
Jingmei Li ◽  
...  

This study demonstrates the synthesis of an efficient photocatalyst, CuO/TiO2 heterojunction, for selective aerobic photo-oxidation of methanol to methyl formate.


1997 ◽  
Vol 93 (2) ◽  
pp. 221-229 ◽  
Author(s):  
Takayuki Kitamura ◽  
Hiroyuki Fudemoto ◽  
Yuji Wada ◽  
Kei Murakoshi ◽  
Mitsuhiro Kusaba ◽  
...  

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