Effect of Fly Ash on the Mechanical Properties and Microstructure of Cement-Stabilized Materials with 100% Recycled Mixed Aggregates

The use of recycled mixed aggregates (RMA) in cement-stabilized materials (CSM) is an effective way to dispose of and reuse demolition waste. However, this approach faces various challenges; for example, the drying shrinkage of CSM with 100% RMA is very high, which is unfavorable for use in road engineering. In order to use a simple method to reduce the drying shrinkage of the CSM with 100% RMA and give it reliable strength, the effect of fly ash on the mechanical properties, drying shrinkage, and abrasion resistance of CSM with 100% RMA was investigated in this study, and the mechanism was examined by X-ray Diffraction (XRD), Mercury Intrusion Porosimetry (MIP), and Scanning Electron Microscopy (SEM). The results revealed that the addition of fly ash would decrease the drying shrinkage of CSM with 100% RMA. Moreover, when the amount of fly ash was less than 20%, the later strength increased remarkably despite the slight decrease in the early unconfined compressive strength, indirect tensile strength, compressive and splitting elastic modulus, and abrasion resistance of CSM with 100% RMA. The microstructure analysis results indicated that fly ash increased the decline range of diffraction intensity of C2S and C3S at a later age and also helped to optimize the pore structure. Research results of this article can be used to optimize the mechanical properties of CSM with 100% RMA and guide its application in road base.

Exploiting differential effects of actomyosin contractility to control cell sorting among breast cancer cells

To gain a greater understanding of the factors that drive spatial organization in multicellular aggregates of cancer cells, we investigate the segregation patterns of 6 breast cell lines (MDA-MB-231, MDA-MB-468, MDA-MB-436, MDA-MB-157, ZR-75-1, and MCF-10A) of varying degree of mesenchymal character during formation of mixed aggregates. We consider cell sorting in the context of available adhesion proteins and cellular contractility, biophysical properties that are typically considered in models of cell sorting. We characterize the mechanisms of spheroid formation as being primarily cadherin- or integrin-driven. The primary compaction mediator for a given cell type plays an important role in compaction speed, which in turn is the major factor dictating preference for interior or exterior position within mixed aggregates. In particular, cadherin-deficient, invasion-competent cells tend to position towards the outside of aggregates, facilitating access to extracellular matrix. We show that reducing actomyosin contractility has a differential effect on spheroid formation depending on the compaction mechanism. Inhibition of contractility has a significant stabilizing effect on cell-cell adhesions in integrin-driven aggregation and a mildly destabilizing effect in cadherin-based aggregation. This differential response is exploited as a spheroid formation method and as a method through which to statically control aggregate organization and dynamically rearrange cells in pre-formed aggregates. Sequestration of invasive cells in the interior of spheroids provides a physical barrier that reduces invasion in three-dimensional culture, revealing a potential strategy for containment of invasive cell types. [Media: see text] [Media: see text] [Media: see text]

Resonance Fatigue Behaviour of Concretes with Recycled Cement and Aggregate

The huge increase in production of construction and demolition waste (CDW) worldwide is leading to the valorisation of as recycled aggregates. One of the most promising alternatives is its use as a recycled aggregate in the manufacture of structural concrete, which motivates the study of the dynamic behaviour of these materials in order to ensure their suitability for use in elements subjected to dynamic loads. This work evaluated the resonant compressive fatigue behaviour of structural concretes with 25% or 50% recycled mixed aggregates, either individually or in combination with 25% recycled cement of clay-based materials both from CDW. All mixes were subjected to compressive fatigue tests using the accelerated Locati method. Regarding the fatigue limit, the results showed that for all mixes, it was between 30% and 45% of the compressive strength. In addition, a correlation was also found between the resonance frequency of the test and the deformation suffered by the specimen. This correlation enabled the estimation of the fatigue limit through a more stable parameter than the strain measured by strain gauges, namely, the resonance frequency. In addition, it was found that the resonance frequency of the test changed as the specimen damage increased. This observation enabled the estimation of the fatigue limit through a more stable parameter than the strain measured by strain gauges, namely, the resonance frequency.

Features of Solubilizing Effect of Amphiphilic Compounds during Pulp Deresination

The necessity to improve the existing technology of pulp deresination, in particular, to reduce the surfactants consumption and decrease the environmental load, led to a combination of existing methods of resin removal with the use of enzymatic treatment. The basis of the pulp deresination mechanism by amphiphilic compounds is the solubilization of resinous substances. Thus, the establishment of the patterns of this process and its control predetermines the success of implementation of the selected technology. The features of solubilization of triolein and rosin in the lipase-based systems of individual nonionic surfactants, the enzyme, as well as their synergistic mixtures with the determination of solubilization capacities of micelles and the possible mechanism of solubilizate incorporation into them were studied using spectrophotometry, pH measurement and dynamic light scattering. It was found that synthamide-5 has a low deresination capability in spite of the high solubilization capacity of its micelles and the production of aggregates with a hydrodynamic radius up to 98 nm after diffusion of rosin into them. It is likely that compact micellar structures with a developed surface, which are implemented in mixed systems of amphiphilic compounds, including the presence of synthamide-5 in them, are more preferable for successful deresination of pulp semi-finished products. The addition of lipase leads to an increased solubilization capacity of mixed aggregates and an increase in the intensity of solubilizate molecules incorporation. Thus, depending on the nature of the amphiphilic compound, there is a different mechanism for solubilizate incorporation into micelles. Determination of the size of associates in mixed systems showed the absence of enzyme denaturation, which predicts the successful application of such cooperative systems for deresination of fiber semi-finished products. It is found that the solubilizing capability of the studied systems on resin modeling objects correlates with their deresination capability with respect to different fiber semi-finished products.

Interaction between sodium dodecylsulfate (SDS) and pluronic (L61) in aqueous medium: assessment of the nature and morphology of the formed mixed aggregates by NMR, EPR, SANS and FF-TEM measurements

Interaction of the copolymer L61 i.e., (EO)2(PO)32(EO)2 (where EO and PO are ethylene and propylene oxides, respectively) with the surfactant SDS (Sodium Dodecylsulfate) in relation to their self-aggregation, dynamics and...