Precipitation and Distribution Behavior of In Situ-Formed TiB Whiskers in Ti64 Composites Fabricated by Selective Laser Melting

The precipitation and distribution behaviors of in situ-formed titanium boride whiskers (TiB) in TiBw-reinforced Ti-6%Al-4%V (Ti64) composites fabricated from an elemental mixture of Ti64 alloy powder and TiB2 particles by selective laser melting were investigated. The primary precipitation of TiB whiskers strongly depends on B content. For a B content of less than 2 mass%, when the liquid → β-phase transformation occurred and B atoms were discharged, the B-enriched area formed around the β-phase resulted in the generation of TiB whiskers and their agglomeration at the prior β-grain boundaries. When the B content was over 2 mass%, TiB whiskers directly precipitated from the liquid phase and moved to the molten pool boundary via Marangoni convection. As a result, the TiB whiskers were located along the boundary. Furthermore, B-enrichment caused a decrease in the liquidus temperature and thus obstructed β-grain coarsening, and as a result, fine equiaxed α’-grains formed during the phase transformation.

Salt activity and diapirism during the Paleogene in the Baronnies Orientales (South-East basin, France) : paleogeographic and structural implications.

<p>The external Alps record a whole Wilson cycle that began at early Mesozoïc times by an extensional phase leading to the deposition of thick marine deposits upon an upper Triassic basement including a thick salt layer. Several diapiric structures (e.g. Astoin, the Barre de Chine ; Célini et al., 2020) are the witnesses of this important salt activity during deposition and the subsequent deformation through the Lower Jurassic. Otherwise, Triassic salt allowed thrusting on several decollement levels and emplacement of major thrusted units, such as the “Nappe de Digne” or the Authon thrust sheet, during the alpine phase s.s, initiated at the Oligocene-Miocene boundary. Between these two periods, the external Alps story is more uncertain and none salt activity has been clearly demonstrated except westwards in the Vocontian basin. In the whole South-East basin, only few clues, as bipyramidal quartz found in Priabonian deposits in the western Baronnies suggest a potential salt activity at surface during the Paleogene. However, in the St-Geniez areas, some Oligocene sediments, located at the vicinity of salt structures suggest a potential diapiric growth during this period. Indeed, some stratigraphic gypsum beds are found in an Oligocene lacustrine series, directly thrusted by the Authon thrust sheet.  None evaporite environments are described in the whole region at Oligocene times, which suggest a possible recycling of Triassic evaporites.</p><p>In order to determine if theses deposits are related to a Paleogene salt activity, a multi-analytical approach was used. First, a field study allowed characterizing the facies and the sedimentary filling and defining the stress regime during the deposit, by kinematic inversion on fractures which indicates a constant N-S compression during the Oligocene. The presence of halophilic fauna at the base of the lacustrine series of the St-Geniez area attests for saline influences during deposit. Moreover, 4km to the SW, a wedge in the conglomerates of the alpine continental molasse (so called red molasse) resting directly on Sorine’s Triassic diapir was put forward. Cargneules and dolomites from the Triassic constitute an important part of the reworked material. These observations indicate that the Sorine's diapir was active during the deposition of the Oligocene series. Then, a precise chemostratigraphic framework was determined by use of δ<sup>13</sup>C and δ<sup>18</sup>O isotopic data on the lacustrine limestones. <sup>87</sup>Sr/<sup>86</sup>Sr isotopic ratio on gypsum beds of the lacustrine series aimed at determining their ages and a possible Triassic evaporite sourcing. Our results gave an age ranging from 6 to 23 Ma, which does not correspond with the Oligocene age of the overlying and underlying sediments. Moreover, the large variation in isotope ratios suggests that this gypsum did not come from primary precipitation but from leaching of a pre-existing evaporite source. In conclusion, field observations, together with geochemical analyses, made it possible to highlight the relationships between tectonics, salt tectonics and sedimentation and also to reconstruct the paleogeography of the region at the end of the Paleogene.</p><p> </p><p><em>References</em></p><p><em>Célini, N., Callot, J.P., Ringenbach, J.C., Graham, R. (2020,). Jurassic salt tectonics in the SW sub-Alpine fold and thrust belt. Tectonics</em></p><p> </p>

The Use of Organic Coagulants in the Primary Precipitation Process at Wastewater Treatment Plants

Measurements for determining the effect of chemically enhanced primary treatment (CEPT) on the efficiency of pollutant removal from wastewater were carried out using conventional inorganic coagulants PIX113 with polymer A110 (Kemipol, Police, Poland) and unconventional cationic organic coagulants Cofloc (Attana, Coalville, UK) C29510 (Kemipol, Police, Poland) and Sedifloc 575 (3F Chimica, Sandrigo, Italy). The average removal efficiency in the 2-h sedimentation process was 46%, 34%, 8%, 12% for the total suspended solids, organic matter (COD), total nitrogen, and total phosphorus, respectively. The use of organic coagulants contributed to 14–81% increase of pollutant removal efficiency. Substantial discrepancies in biological nutrient removal processes were not discovered in two-phase (anaerobic-anoxic) experiments without and with the addition of the organic coagulants. The increase in organic matter removal efficiency as a result of the CEPT process may contribute to a 65–80% increase in biogas production. The conducted research confirms the possibility of using organic coagulants in the primary precipitation process in wastewater treatment plants (WWTPs) in accordance with the principles of maximum energy recovery, thereby promoting renewable energy sources. Additionally, organic coagulants, as opposed to inorganic ones, do not cause a significant increase of chloride and sulfate ion concentrations, which facilitates the use of treated wastewater in the water reuse systems, such as irrigation of agricultural crops.

A Possible Mechanism for the Formation of Exploded Graphite in Nodular Cast Irons

In hypereutectic nodular cast irons, primary precipitation of graphite may lead to graphite flotation in thick section castings. Graphite degeneracy such as so-called exploded graphite is then often associated with this flotation phenomenon and it appears as precipitates where the nodular form is replaced by star-like or flower-like shape. It has been reported that exploded graphite develops after the primary spheroidal nodules have reached some tens of microns in diameter. In this contribution, a model for this transition is presented.

The Effect of Superheating and Cooling Rate on Primary Precipitation of Si in Hypereutectic Al-Si Alloys

The effect of superheating and cooling rate on primary precipitation of Si was studied in hypereutectic Al-Si alloys. Alloys with compositions of 15, 18 and 20 wt% Si were solidified in unidirectional solidification equipment from different temperatures and drawing speeds. The fraction of primary silicon was measured over a certain distance of the sample in the steady state region. Results show a large variation in primary silicon fraction along the sample length and with varying cooling rate. The fraction of primary silicon and primary aluminium around silicon increases with increasing superheat. These fractions decrease with increasing cooling rate and the structure changes to a more refined dendritic-like primary silicon. Different morphologies of Si and their transformation during solidification can be seen over the sample length. An analysis of the quenched solidification front shows the possibility of strong convection ahead of the solidification front. The convection can be caused by density variation in the liquid due to the cluster structure of the melt which changes the microstructure.

Primary precipitation of icosahedral quasicrystal with rearrangement of constitutional elements in Zr65Al7.5Cu27.5 glassy alloy with low oxygen impurity

The primary transformation reaction of the Zr65Al7.5Cu27.5 ternary glassy alloy with a low oxygen impurity of approximately 100 mass ppm was investigated. We have discovered the precipitation of the metastable icosahedral phase with a fine grain size of 50–100 nm in diameter accompanying with the formation of stable Zr2Cu phase at the annealing temperatures ranging from 715 to 730 K. The lattice spacing of Zr2Cu phase decreases at higher temperatures, which is attributed to the rearrangement of Zr and Cu in the decomposition of the icosahedral phase. It is suggested that the formation of the icosahedral phase in the primary stage originates from the existence of the quenched-in icosahedral local atomic configuration in the glassy state.

Stability and Icosahedral Transformation of Supercooled Liquid in Metal-Metal type Bulk Glassy Alloys

ABSTRACTThe glassy structure and the primary precipitation phase from supercooled liquid were examined in metal-metal type Zr-, Hf- and Cu-based alloy systems by various advanced analytical techniques. The icosahedral phase precipitates as the primary phase from supercooled liquid for all the metal-metal type glassy alloys examined in the present study. The icosahedral phase has a rhombic triacontahedra type for the Zr-Al-Ni-Cu-NM (NM=Ag, Pd, Au, Pt), Zr-Cu-NM, Hf-Al-Ni-Cu-NM, Cu-Zr-Ti-Pd and Cu-Hf-Ti alloys. In addition, the short-range atomic configurations in their glassy alloys have the features of highly dense packed atomic configuration, new local atomic configurations and long-range homogeneity with attractive interaction. It is therefore concluded that the high glass-forming ability of the metal-metal type alloys is due to the self-formation of the unique glassy structure with the above-described three features which are consistent with the formation of short-range icosahedral atomic configuration.