Study on the kinetic characteristics of gas hydrate in the dioctyl sodium sulfosuccinate system

Surfactants promote the production of hydrates, which provide a possibility for the industrialization of hydrate technology.

Bacterial aggregation assisted by anionic surfactant and calcium ions

Marine bacteria form small aggregates in the presence of an anionic surfactant, dioctyl sodium sulfosuccinate, and calcium ions.

Sustainable low liquor ratio dyeing of cotton with C.I. Reactive Blue 21 using dioctyl sodium sulfosuccinate

Low liquor ratio (material to liquor ratio = 1:5) dyeing of cotton fabric with C.I. Reactive Blue 21 using dioctyl sodium sulfosuccinate as a surfactant was thoroughly analyzed. The dye–surfactant interactions in the micelles during low liquor ratio dyeing were investigated by ultraviolet-visible spectroscopy and the chemical mechanism of the process was evaluated by Fourier-transform infrared spectroscopy analysis. Cotton fabric was subjected to low liquor ratio dyeing and conventional dyeing by varying the temperature, pH, treatment time, and non-identical chemical concentration. The effectiveness of the process was assessed based on the color strength ( K/ S), exhaustion (%), fixation (%), and levelness. Low liquor ratio dyeing afforded superior dyeing compared to conventional dyeing, attributed to the anti-agglomeration effects of the former, which also had no adverse impact on the fastness of the dye. The lower environmental impact due to the lower effluent footprint (biological oxygen demand, chemical oxygen demand, total dissolved solids, and dissolved oxygen) is another benefit of low liquor ratio dyeing. High-pressure liquid chromatography and gas chromatography-mass spectrometry analyses revealed that the low liquor ratio dyed fabric is free of toxic substances (alkylphenol ethoxylates and formaldehyde). Moreover, low liquor ratio dyeing is more cost-effective and outperformed conventional dyeing in all aspects, while being a sustainable process.

Effects of magnesium sulfate and dioctyl sodium sulfosuccinate on fecal hydration, output and systemic hydration in healthy horses

ABSTRACT Magnesium sulphate (MS) and dioctyl sodium sulphosuccinate (DSS) are laxative drugs frequently used for the treatment of impactions. The aim of this study was to compare the effects of MS and DSS in fecal hydration, output and systemic hydration in healthy horses. Five healthy horses received 3 treatments with a 21-day interval. Treatment 1 was performed with administration of 4 liters of warm water; treatment 2: administration of 4 liters of warm water associated with 1g/kg of MS; and treatment 3: administration of 4 liters of warm water associated with 20mg/kg DSS. General and specific physical examination of the digestive system were performed, alongside with packed cell volume and total plasma protein measurement, abdominal ultrasonography and quantification of the amount and hydration of feces, before and 6, 12, 24, 36 and 48 hours after the treatments. No adverse effects were observed. The administration of laxatives promoted greater fecal output and hydration without resulting in systemic dehydration, yet no differences were observed between treatments. The absence of adverse effects of DSS demonstrates the safety of its use as a laxative drug at a dose of 20mg/kg. Studies comparing the effects of the laxative drugs in horses with large colon impaction are needed.

Dual Catalytic Activity of Amberlyst-15 in the Large-scale and Sustainable Synthesis of Dioctyl Sodium Sulfosuccinate (DOSS)

Dioctyl sodium sulfosuccinate (DOSS) as a unique material both as a drug and surfactant was synthesized by a facile and economical synthetic method. In this project, Amberlyst-15 was selected as a heterogeneous recyclable bronsted solid acid for this synthesis both in the esterification of maleic anhydride and sulfonation of dioctyl maleate (DOM) ester. This catalyst was easily recovered and reused at least for 13 consecutive cycles without a significant loss in the catalytic activity. In this paper, we wish to uncover a catalytic approach for the synthesis of DOSS through a recyclable, easily recoverable, and commercially available catalyst, namely Amberlyst 15, under mild conditions.

Synthesis and Characterization of Hollow-Sphered Poly(N-methyaniline) for Enhanced Electrical Conductivity Based on the Anionic Surfactant Templates and Doping

Poly(N-methylaniline) (PNMA) is a polyaniline derivative with a methyl substituent on the nitrogen atom. PNMA is of interest owing to its higher solubility in organic solvents when compared to the unsubstituted polyaniline. However, the electrical conductivity of polyaniline derivatives suffers from chemical substitution. PNMA was synthesized via emulsion polymerization using three different anionic surfactants, namely sodium dodecylsulfate (SDS), sodium dodecylbenzenesulfonate (SDBS), and dioctyl sodium sulfosuccinate (AOT). The effects of surfactant structures and concentrations on electrical conductivity, doping level, crystallinity, morphology, and thermal stability were investigated. The re-doping step using perchloric acid (HClO4) as a dopant was sequentially proceeded to enhance electrical conductivity. PNMA synthesized in SDBS at five times its critical micelle concentration (CMC) demonstrated the highest electrical conductivity, doping level, and thermal stability among all surfactants at identical concentrations. Scanning electron microscopy (SEM) images revealed that the PNMA particle shapes and sizes critically depended on the surfactant types and concentrations, and the doping mole ratios in the re-doping step. The highest electrical conductivity of 109.84 ± 20.44 S cm−1 and a doping level of 52.45% were attained at the doping mole ratio of 50:1.