Electrochemical Passivation Properties of Valve Transition Metal Carbides

Transition metal carbides have the potential to be employed as corrosion protective coating for a variety of applications such as e.g. steel based bipolar plates, porous transport layers or as catalyst support in polymer electrolyte membrane fuel cells and water electrolyzers. Yet, little is known of their fundamental, intrinsic corrosion and passivation properties. Herein, we conducted a detailed electrochemical passivation study of various valve transition metal carbides such as titanium carbide, tantalum carbide or tungsten carbide. Via flow cell measurements coupled to an inductively coupled plasma mass spectrometer, the in-situ transition metal dissolution was monitored, and the faradaic dissolution efficiency was calculated. Together with the determination of the grown oxide layer via X-ray photoelectron spectroscopy, a thorough evaluation of the passivation efficiency was conducted. Moreover, it was shown that a beneficial stabilization effect can be achieved through alloying of different carbides, which paves the way towards tailor-made coatings or catalyst support materials.

Inducing Liquid Crystallinity in Dilute MXene Dispersions for Facile Processing of Multifunctional Fibers

The liquid crystal (LC) phases of two-dimensional (2D) transition metal carbides/nitrides (MXenes) has enabled the production of their unique macro-architectures with ordered microstructure and enhanced properties. However, LC phases in...

Two-dimensional MXenes for electrochemical energy storage applications

Since the discovery of Ti3C2Tx in early 2011, a newly emerging family of post-graphene two-dimensional transition metal carbides and nitrides (MXenes) has been rigorously investigated owing to their high conductivity....

Atomistic and electronic structure of metal clusters supported on transition metal carbides: implications for catalysis

Novel research avenues have been explored over the last decade on the use of transition metal carbides (TMCs) as catalytically active supports for metal nanoclusters, which display high catalytic activity...

Computational design of double transition metal MXenes with intrinsic magnetic properties

Two-dimensional transition metal carbides (MXenes) have a great potential to achieve intrinsic magnetism due to their available chemical and structural diversity. In this work, by spin-polarized density functional theory calculations,...

Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review

Dry reforming of hydrocarbons (DRH) is a pro-environmental method for syngas production. It owes its pro-environmental character to the use of carbon dioxide, which is one of the main greenhouse gases. Currently used nickel catalysts on oxide supports suffer from rapid deactivation due to sintering of active metal particles or the deposition of carbon deposits blocking the flow of gases through the reaction tube. In this view, new alternative catalysts are highly sought after. Transition metal carbides (TMCs) can potentially replace traditional nickel catalysts due to their stability and activity in DR processes. The catalytic activity of carbides results from the synthesis-dependent structural properties of carbides. In this respect, this review presents the most important methods of titanium, molybdenum, and tungsten carbide synthesis and the influence of their properties on activity in catalyzing the reaction of methane with carbon dioxide.

Comparative Analysis of the Phase Interaction in Plasma Surfaced NiBSi Overlays with IVB and VIB Transition Metal Carbides

Important applications of transition metal carbides (TMCs) are as wear resistant composite layers deposited by plasma transferred arc welding (PTAW) and laser methods. Growing interest in them has also been observed in additive manufacturing and in HEA technology (bulk composite materials and layers), and in the area of energy conversion and storage. This paper presents the results of comparative studies on interfacial interactions in the NiBSi−TMCs system for two border IVB and VIB TM groups of the periodic table. Model (wettability and spreadability) and application experiments (testing of the PTAW-obtained carbide particle−matrix boundaries) were performed. Fe from partially melted steel substrates is active in the liquid NiBSi−TMCs system. It was revealed that the interaction of TMCs with the liquid NiBSi matrix tends to increase with the group number, and from the top to bottom inside individual groups. Particles of IVB TMCs are decomposed by penetration of the liquid along the grain boundaries, whereas those of VIB are decomposed by solubility in the matrix and secondary crystallization. No transition zones formed at the interfacial boundaries of the matrix−IVB group TMCs, unlike in the case of the VIB group. The experimental results are discussed using the data on the TMC electronic structure and the physicochemical properties.