Designing of Green Plasticizers and Assessment of the Effectiveness of Their Use

The growing anthropogenic load on the lithosphere is currently characterized by the alienation of huge areas for solid domestic waste. One of the most common pollutants is traditional plastics with a degradation period of over 100 years. In connection with the increasing environmental requirements, polymer materials, along with a high set of technological and operational parameters, must be environmentally friendly and biodegradable. The development of polymer composite materials that undergo accelerated physicochemical and biological changes in the natural environment due to the introduction of biodegradable additives is one of the potential methods for processing synthetic materials and ensures the release of significant areas of fertile soils and lands from the steadily increasing amount of polymer waste. The use of adipic acid esters as PVC plasticizers contributes to the production of biodegradable composites. The article describes a method for obtaining new esters of adipic acid, presents the results of studying their properties for practical use in PVC composites, and assesses the economic efficiency of preventing damage to the environment when using them.

Influence of heat treatment on the amino acid composition of grape juices direct extraction

Currently, the development of technology for functional beverages based on direct-pressed grape juice is a particularly important and urgent task due to the presence of a diverse and affordable raw material base in the South of Kazakhstan. In view of the fact that high temperatures applied for a short time do not have a profound negative impact on the quality of juice, the assessment of heat treatment as a key technological stage that affects the change in the composition of free amino acids in experimental samples of straight-pressed wine juices was carried out. Taking into account the totality of data from the organoleptic and chemical analysis of experimental samples, for the production of juices with a high level of biological value, we recommended the Sensation and Husain red grape varieties with a high set of amino acids after the pasteurization process: 1504.5 mg / dm3 and 1288.8 mg / dm3 respectively.

Development of recommendations on cooling rates of railway wheels with the use of modeling in the software package qform vx 8.2 for the formation of a homogeneous ferritic-perlite structure

The tests were performed on ER7 steel according to EN 13262. Based on the hardenability test (GOST 5657) by the method of end hardening (Jomen) the distance from the surface from which unilateral cooling was performed, where the hardness met the requirements of regulatory documentation for wheels of test steel, and the distance where the formation of needle structures, including bainite and otmanshtette, no longer took place. Simulation was applied in the software package QForm VX 8.2, as a result, a model was developed, for the adaptation of which the results of the experiment were used. Confirmed the high convergence of the results of the calculation and the experiment. At the same time, the model allowed to obtain an instantaneous cooling rate in a form that is more in line with the physical meaning of the process and to avoid the scatter of actual values associated with the discreteness of data capture. It is established that the instantaneous cooling rate changes in the process of continuous uniform supply of the cooler. The permissible range of cooling rates of the surface and central sections of the wheel rim during accelerated cooling of ER7 steel is determined. The data can be used to improve the heat treatment modes of railway wheels of current production in order to achieve a high set of mechanical properties both with the existing cooling technology and with differentiated cooling on the modernized equipment of the thermal section of the wheel shop. The developed model can be used to build thermokinetic diagrams under continuous cooling and to develop recommendations for heat treatment modes to achieve the specified mechanical properties under a certain structural state.

ANALYSIS OF REGRESSION MODELS OF STRENGTH AND PLASTIC PROPERTIES OF DEFORMATION-THERMALLY HARDENED REINFORCING PROFILE

Numerous studies have shown that the processes of structure formation as aresult of the combined effect of plastic deformation and phase transformations onthe alloy are different from the formation of the structure during conventional heattreatment and provide a high set of mechanical properties that cannot be achievedby conventional methods of heat treatment or complex alloying.Сurrently, in the production of rod reinforcement for reinforced concretestructures, technologies of combined deformation and thermal hardening areincreasingly used. When hot rolling is combined with subsequent heat treatment,intensive and controlled cooling of hotly deformed austenite is performed directlyat the exit from the finishing stand of the rolling mill, which leads to a stronggrinding of the structure, and, consequently, provides high mechanical propertiesof the material than when cooling in air, as was the case at many existing rollingmills.Analytical review of the literature on the problem of combining hotdeformation with heat treatment shows that the efficiency of deformation and heattreatment depends on the temperature of rolling, the total degree of fragmentationand deformation, the degree of a single strain, time interval from the end of hotrolling to the beginning of accelerated cooling, duration of intensive coolingdefines the temperature smoothback, like the original steel (cast or rolled), andfinally, the chemical composition of the processed steel [1].

PSVII-1 A preliminary phenotypic characterization of Raramuri Criollo cattle

Raramuri Criollo (RC) are one of 33 known biotypes of heritage Criollo cattle that exist throughout the Americas today. They have been raised by the Tarahumara peoples of the Copper Canyon in Chihuahua, Mexico, for over 400 years and exhibit remarkable rusticity and adaptation to harsh grazing environments. To date, no quantitative phenotypic description of this biotype exists. Our objective was to characterize RC cattle via 26 phenotype traits to provide a preliminary biotype standard. Twenty-eight multiparous RC cows, 4 primiparous heifers, and 4 bulls were selected from a purebred herd of approximately 200 animals at the USDA-ARS Jornada Experimental Range. These 36 animals were selected by a Criollo cattle expert based on body conformation correctness. SAS 9.4 was used to determine means, SEs or frequency of measured traits. Multiparous pregnant and cycling cows averaged 366.8 ± 9.8 kg live body weight, 121.8 ± 0.9 cm withers height, horn widths of 60.3 ± 1.6 cm, horn diameters of 5.7 ± 0.1 cm, chest girths of 183.6 ± 12.0 cm, hip widths of 44.5 ± 0.5 cm, flank girths of 52.2 ± 0.9 cm, body length of 90.0 ± 1.7 cm, neck lengths of 52.0 ± 0.9 cm, and tail lengths of 83.3 ± 1.4 cm. Bulls consistently averaged higher values for all traits and weighed 618.2 ± 9.8 kg with scrotal circumferences of 36.8 ± 0.7 cm. RC cattle exhibited mostly convex nose bridges (89%), open-back horns (49%), black muzzles, hooves, and eyes (62, 69, and 81%, respectively), small ears (78%), oblique eyes (70%), high-set tail heads (86%), short hooves (95%), and short hair (78%). Our preliminary characterization of RC phenotypes will be useful in selecting RC individuals for genotypic evaluation to eventually maintain a distinct purebred registry of this Criollo biotype.

GWAS reveals the genetic complexity of fructan accumulation patterns in barley grain

We profiled the grain oligosaccharide content of 154 two-row spring barley genotypes and quantified 27 compounds, mainly fructans, that exhibited differential abundance. Clustering revealed two major profile groups where the ‘high’ set contained greater amounts of sugar monomers, sucrose and overall fructans, but lower fructosylraffinose. GWAS identified a significant association for the variability of two fructan types; neoseries-DP7 and inulin-DP9 which showed increased strength when a compound-ratio GWAS was applied. Gene models within this region included five fructan biosynthesis genes, of which three (fructan:fructan 1-fructosyltransferase, sucrose:sucrose 1-fructosyltransferase, and sucrose:fructan 6-fructosyltransferase) have already been described. The remaining two, 6(G)-fructosyltransferase and vacuolar invertase1 have not previously been linked to fructan biosynthesis in barley and showed expression patterns distinct from those of the other three genes, including exclusive expression of 6(G)-fructosyltransferase in outer grain tissues at the storage phase. From exome capture data several SNPs related to inulin- and neoseries-type fructan variability were identified in fructan:fructan 1-fructosyltransferase and 6(G)-fructosyltransferase genes Co-expression analyses uncovered potential regulators of fructan biosynthesis including transcription factors. Our results provide evidence for the distinct biosynthesis of neoseries-type fructans during barley grain maturation plus new gene candidates likely involved in the differential biosynthesis of the various fructan types.HighlightGrain fructan profiles in barley are more complex than previously expected and variations in a diversity panel relate to a genomic region where fructan biosynthesis genes cluster.