The Moon as a Climate-Quality Radiometric Calibration Reference

On-orbit calibration requirements for a space-based climate observing system include long-term sensor response stability and reliable inter-calibration of multiple sensors, both contemporaneous and in succession. The difficulties with achieving these for reflected solar wavelength instruments are well known. The Moon can be considered a diffuse reflector of sunlight, and its exceptional photometric stability has enabled development of a lunar radiometric reference, manifest as a model that is queried for the specific conditions of Moon observations. The lunar irradiance model developed by the Robotic Lunar Observatory (ROLO) project has adequate precision for sensor response temporal trending, but a climate-quality lunar reference will require at least an order of magnitude improvement in absolute accuracy. To redevelop the lunar calibration reference with sub-percent uncertainty and SI traceability requires collecting new, high-accuracy Moon characterization measurements. This paper describes specifications for such measurements, along with a conceptual framework for reconstructing the lunar reference using them. Three currently active NASA-sponsored projects have objectives to acquire measurements that can support a climate-quality lunar reference: air-LUSI, dedicated lunar spectral irradiance measurements from the NASA ER-2 high altitude aircraft; ARCSTONE, dedicated lunar spectral reflectance measurements from a small satellite; and Moon viewing opportunities by CLARREO Pathfinder from the International Space Station.

Optically functional isoxanthopterin crystals in the mirrored eyes of decapod crustaceans

The eyes of some aquatic animals form images through reflective optics. Shrimp, lobsters, crayfish, and prawns possess reflecting superposition compound eyes, composed of thousands of square-faceted eye units (ommatidia). Mirrors in the upper part of the eye (the distal mirror) reflect light collected from many ommatidia onto the photosensitive elements of the retina, the rhabdoms. A second reflector, the tapetum, underlying the retina, back-scatters dispersed light onto the rhabdoms. Using microCT and cryo-SEM imaging accompanied by in situ micro–X-ray diffraction and micro-Raman spectroscopy, we investigated the hierarchical organization and materials properties of the reflective systems at high resolution and under close-to-physiological conditions. We show that the distal mirror consists of three or four layers of plate-like nanocrystals. The tapetum is a diffuse reflector composed of hollow nanoparticles constructed from concentric lamellae of crystals. Isoxanthopterin, a pteridine analog of guanine, forms both the reflectors in the distal mirror and in the tapetum. The crystal structure of isoxanthopterin was determined from crystal-structure prediction calculations and verified by comparison with experimental X-ray diffraction. The extended hydrogen-bonded layers of the molecules result in an extremely high calculated refractive index in the H-bonded plane, n = 1.96, which makes isoxanthopterin crystals an ideal reflecting material. The crystal structure of isoxanthopterin, together with a detailed knowledge of the reflector superstructures, provide a rationalization of the reflective optics of the crustacean eye.