Characterizing Biaxially Stretched Polypropylene / Graphene Nanoplatelet Composites

In this work, polypropylene (PP) nanocomposites containing different weight concentration of graphene nanoplatelets (GNP) were prepared by melt-mixing using an industrial-scale, co-rotating, intermeshing, twin-screw extruder. The materials were then compression moulded into sheets, and biaxially stretched at different stretching ratios (SRs) below the PP melting temperature. The effects of GNP content and biaxial stretching on the bulk properties of unfilled PP and PP/GNP nanocomposites have been investigated in details. Results show that the addition of GNP (>5wt%) can lead to electrically conductive composites due to the formation of percolation network. The GNP have led to increased polymer crystallinity and enhanced materials stiffness and strength. Biaxial stretching process further enhances the materials mechanical properties but has slightly decreased the composites electrical conductivity. The PP/GNP nanocomposites were also processed into 3D demonstrator parts using vacuum forming, and the properties of which were comparable with biaxially stretched composites.

The Role of Solvent Additive on Polymer Crystallinity During Physical Supercritical Fluid Deposition

We investigated the self-assembly of polymers in supercritical fluids by depositing thin films of isotactic polypropylene from n-pentane:acetone solutions and studying their structure. The deposition technique leverages a maximum in...

Sustainable Additive Manufacturing: Mechanical Response of Polypropylene over Multiple Recycling Processes

The recycling of polymeric materials has received a steadily growing scientific and industrial interest due to the increase in demand and production of durable and lightweight plastic parts. Recycling of such materials is mostly based on thermomechanical processes that significantly affect the mechanical, as well as the overall physicochemical properties of polymers. The study at hand focuses on the recyclability of Fused Filament Fabrication (FFF) 3D printed Polypropylene (PP) for a certain number of recycling courses (six in total), and its effect on the mechanical properties of 3D printed parts. Namely, 3D printed specimens were fabricated from non-recycled and recycled PP material, and further experimentally tested regarding their mechanical properties in tension, flexion, impact, and microhardness. Comprehensive dynamic scanning calorimetry (DSC), thermogravimetric analysis (TGA), Raman spectroscopy, and morphological investigations by scanning electron microscopy (SEM) were performed for the different 3D printed PP samples. The overall results showed that there is an overall slight increase in the material’s mechanical properties, both in tension and in flexion mode, while the DSC characterization indicates an increase in the polymer crystallinity over the recycling course.

Effects of polymer crystallinity on non-fullerene acceptor based organic solar cell photostability

Organic solar cell shows significantly different degradation rate with different donor polymer crystallinity, even the donors and acceptors are all photostable.