Release and distribution changes of phosphorus in three alkaline sandy soils as a function of bone char applications

An incubation experiment was carried out to assess bone char application on the availability and distribution of phosphorus in agricultural alkaline sandy soils. Three alkaline agricultural sandy soils in Upper Egypt have been collected from Arab El-Awamer at Assiut governorate, West El-Minia at El-Minia governorate, and New Valley Governorate. 100 grams were taken from each soil under study and placed in a plastic jar. The bone char is applied at level 0.4 g jar-1 into these soils. This experiment was incubated at 23 ºC in the dark for periods of 7, 16, 35, 65, and 84 days and arranged in a completely randomized design with three replicates. The results revealed that bone char applications to the soils resulted in a significant positive increase in the availability of phosphorus affected by the soil type and incubation periods in Arab El-Awamer soil. The percentage of increase in available phosphorous after adding bone char compared to before incubation was as follows: Arab El-Awamer soil ˃New Valley soil ˃West El-Minia soil. The available phosphorous was negatively correlated with electrical conductivity (r=-0.288*), soluble calcium (r=-0.306*), and soluble sulfate (r=-0.413*). The concentrations of NH4Cl-Pi, NaHCO3-Pi, NaOH-Pi, HCl-Pi, residual-P fractions increased significantly in some soil types with applying bone char. The concentrations of available phosphorous in all soils under study were positively correlated with all phosphorus fractions. We conclude that bone char applications into P-poor soil are important to potentially enhance phosphorus availability. Bone char is considered a promising strategy in sustainable agriculture.

Characterization of Mellowing Process to Control Expansion in High-Sulfate-Bearing Soil

Calcium-based stabilizing materials (CBSMs) such as lime and fly ash are extensively used in subgrade primarily to enhance mechanical strength and improve resistance to chemical attack, resulting in more durable roadway. The soluble sulfate phase contained in some soils, however, can react with CBSMs and form ettringite minerals. If the soil is compacted before the end of this reaction, large, unstable, and volumetric swelling can occur. Among several methods to control sulfate-induced swelling, a “mellowing” approach is typically used because of its efficient, economical, and practical benefits when dealing with calcium-based stabilization of soils with significant soluble sulfate contents. Although the mellowing method is one of the frequently used methods, little data is available on the characterization of the specified mellowing process in the high-sulfate-bearing soil during the mellowing period. A research program investigated key factors influencing the mellowing process during the mellowing period, explaining how stabilizer type and content, remixing interval, mellowing period, and temperature play a role in reducing soluble sulfate content. Moreover, for selected mixtures, the 3-dimensional volumetric expansion and retained strength were measured after the mellowing process. Laboratory test results have revealed that a single mellowing process with higher lime content and daily remixing at high temperature leads to the rapid reduction of sulfate content in the soil. Moreover, after the mellowing process, additional soil treatment with fly ash or a combination of lime and fly ash leads to lower expansion and higher retained unconfined compressive strength of the soil mixture.

Engineering geology and geotechnical characterization of Tabriz Metro Line 2, Iran

The present study was performed in order to determine the engineering geology and geotechnical details of soils and rocks along Tabriz Metro Line 2(TML2) by using the information and raw data which were acquired by borehole drilling and all field and laboratory tests in the study area. The minimum and maximum depths of the boreholes were 15 and 40 m, respectively. The results of their analysis revealed that geologically, the areas of metro route, mainly formed by alternating layers of claystone, siltstone, marl, and conglomerate, covered mainly by the alluvial deposits and in addition to older, dextral, strike-slip North Tabriz Fault (NTF) which is a major and most important geological structure of Tabriz area, there are also many minor and generally young and seismically active faults. The results of investigation on the groundwater depth in boreholes of TML2 also indicated that the groundwater depth varies between 1.5 and 30 m, along the route of metro. Eventually, based on the standard penetration test values (N-SPT), it was revealed that soils of the western parts of TML2 are in the group of dense to very dense, the central parts are in the group of very dense (Bazaar area) and dense (Fahmideh area), and the eastern parts are very dense. And finally the results achieved from determining groundwater sulfate values according to Concrete Code of Iran (CCI) indicated that the amount of soluble sulfate in the soil is mild to extremely high. Accordingly, the amount of sulfate increases from the western to the eastern parts. So that, this value is between 200 and 26,500 ppm. Based on these studies, the average of sulfate in the western, central and eastern parts is, respectively, 1118, 1275 and 4840 ppm. Thus, the groundwater in the east part is highly aggressive, and deterioration of concrete lining of the tunnel is expected in the near future.

Barite Concretions in Wadi Halfa Oolitic Ironstone Formation, North Sudan

During our examination of the outcrops of the sedimentary formations in northern Sudan, we found discoidal-shape grains of the heavy mineral, barite in a sandstone of the Wadi Halfa Oolitic Ironstone Formation, which was recorded by all the earlier workers as a reworked sandstone. Petrography-wise, the framework of the sandstone consists of very angular to angular quartz grains, in which monocrystalline grains dominate over polycrystalline grains. Barite is the main cementing material of this sandstone, which occurs as concretions. Barite concretions indicate that more of the original porosity has been destroyed by cementation rather than by compaction processes with the inter-granular porosity being reduced mainly due to cementation. The origin of these concretions, as a cementing material in the sandstone, is ascribed to the reaction of Ba with some soluble sulfate to form the extremely insoluble heavy barite that appears as rounded concretions. The sulfur of the sulfate may be from the hydrothermal fluids related to submarine volcanism and/or biogeochemical processes. The deposition of these concretions might have taken place not long after the formation of the sandstone. The source of the barium, however, remains an unsolved problem. Further work is needed to interpret the origin and occurrence of these concretions along the region of Wadi Halfa.

Geotechnical characterization of sulfur species in UK Jurassic mudrocks

Weathering of pyritic mudrocks results in the oxidation of sulfides and generation of sulfates in concentrations potentially hazardous to civil engineering works. Geochemical and petrographic analyses undertaken on samples from sites underlain by the Kimmeridge Clay Formation and Oxford Clay Formation proved three distinct zones: an upper sulfur-leached zone, an intermediate weathered zone with sulfate-rich horizons and a lower relatively unweathered zone of low-sulfate, high-sulfide material. It was found that water-soluble sulfate and total potential sulfate may vary by up to 1500 mg SO42− l−1 and 8% SO42− respectively, over a depth interval of only 0.2 m. A targeted sampling strategy and ground aggressivity assessment approach can be applied to these formations based upon the sulfur species zones identified.