Microstructure-dependent rate theory model of defect segregation and phase stability in irradiated polycrystalline LiAlO2

Gamma lithium aluminate (LiAlO2) is a breeder material for tritium and is one of key components in a tritium-producing burnable absorber rod (TPBAR). Dissolution and precipitation of second phases such as LiAl5O8 and voids are observed in irradiated LiAlO2. Such microstructure changes cause the degradation of thermomechanical properties of LiAlO2 and affect tritium retention and release kinetics, and hence, the TPBAR performance. In this work, a microstructure-dependent model of radiation-induced segregation (RIS) has been developed for investigating the accumulation of species and phase stability in polycrystalline LiAlO2 structures under irradiation. Three sublattices (i.e., [Li, Al, V]I [O, Vo]II [Lii, Ali, Oi, Vi]III), and concentrations of six diffusive species (i.e., Li; vacancy of Li or Al at [Li, Al, V]I sublattice, O vacancy at [O, Vo]II sublattice, and Li, Al and O interstitials at [Lii, Ali, Oi, Vi]III interstitial sublattices; are used to describe spatial and temporal distributions of defects and chemistry. Microstructure-dependent thermodynamic and kinetic properties including the generation, reaction, and chemical potentials of defects and defect mobility are taken into account in the model. The parametric studies demonstrated the capability of the developed RIS model to assess the effect of thermodynamic and kinetic properties of defects on the segregation and depletion of species in polycrystalline structures and to explain the phase stability observed in irradiated LiAlO2 samples. The developed RIS model will be extended to study the precipitation of LiAl5O8 and voids and tritium retention by integrating the phase-field method.

A Finnish District Heating Reactor: Neutronics Design and Fuel Cycle Simulations

The development of a small PWR for district heating applications has been started at VTT Technical Research Centre of Finland, and the pre-conceptual design phase was completed by the end of year 2020. The heating plant consists of one or multiple 50 MW reactor modules, operating on natural circulation at around 120°C temperature. This paper presents the neutronics design and fuel cycle simulations carried out using VTT’s Kraken computational framework. The reactor is operated without soluble boron, which together with low operating temperature and pressure brings certain challenges to the use of control rods and burnable absorber. The reactor core is loaded with 37 truncated AP1000-type fuel assemblies with 2.0–3.0% fuel enrichment and erbium burnable absorber. The resulting cycle length is around 900 days. The results show that the criteria set for stability, reactivity control and thermal margins are fulfilled. More importantly, it is concluded that the new Kraken framework is a viable tool for the core design task.

Subcriticality control elements in a reactor system with an extended plasma source of neutrons with regard for temperature

Materials have been selected for the shim rods and burnable absorbers to compensate for the excessive reactivity of the facility’s blanket part and to provide for the possibility of reactivity control in conjunction with a plasma source of neutrons. Burnable absorber is a layer of zirconium diboride (ZrB2) with a thickness of 100 μm applied to the surface of fuel compacts. Boron carbide (B4C) rods installed in the helium flow channels and used to bring the entire system into a state with keff = 0.95 have been selected as the shim rod material. Throughout its operating cycle, the facility is subcritical and is controlled using the neutron flux from the plasma source. Verified codes, WIMS-D5B (ENDF/B-VII.0) and MCU5TPU (MCUDВ50), as well as a modern system of constants were used for the calculations. The facility’s neutronic performance was simulated with regard for the changes in the inner structure and temperature of the microencapsulated fuel and fuel compact materials caused by long-term irradiation and by the migration of fission fragments and gaseous chemical compounds.

Truly-optimized PWR lattice for innovative soluble-boron-free small modular reactor

A novel re-optimization of fuel assembly and new innovative burnable absorber (BA) concepts are investigated in this paper to pursue a high-performance soluble-boron-free (SBF) small modular reactor (SMR), named autonomous transportable on-demand reactor module (ATOM). A truly optimized PWR (TOP) lattice concept has been introduced to maximize the neutron economy while enhancing the inherent safety of an SBF pressurized water reactor. For an SBF SMR design, the 3-D centrally-shielded BA (CSBA) design is utilized and another innovative 3-D BA called disk-type BA (DiBA) is proposed in this study. Both CSBA and DiBA designs are investigated in terms of material, spatial self-shielding effects, and thermo-mechanical properties. A low-leakage two-batch fuel management is optimized for both conventional and TOP-based SBF ATOM cores. A combination of CSBA and DiBA is introduced to achieve a very small reactivity swing (< 1000 pcm) as well as a long cycle length and high fuel burnup. For the SBF ATOM core, safety parameters are evaluated and the moderator temperature coefficient is shown to remain sufficiently and similarly negative throughout the whole cycle. It is demonstrated that the small excess reactivity can be well managed by mechanical shim rods with a marginal increase in the local power peaking, and a cold-zero shutdown is possible with a pseudo checker-board control rod pattern. In addition, a thermal–hydraulic-coupled neutronic analysis of the ATOM core is discussed.

Analysis of Doppler reactivity of SMART reactor core for hybrid fuel configurations of UO2, MOX and (Th/U)O2 using OpenMC

In this study, the Doppler reactivity coefficient has been investigated for UO2, MOX, and (Th/U)O2 fuel types. The calculation has been carried out using the Monte Carlo method ( OpenMC). The effective multiplication factor keff has been evaluated for three materials with four different configurations without Integral Fuel Burnable Absorber (IFBA) rods and soluble boron. The results of MOX fuel, homogenous and heterogeneous thorium fuel configuration has been compared with the core of the reference fuel assembly (UO2). The calculation showed that the effective multiplication factor at 1 000 K was 1.26052, 1.14254, 1.22018 and 1.23771 for reference core, MOX, homogenous and heterogeneous configurations respectively. The results shows that reactivity has decreased with increasing temperature while the doppler reactivity coefficient remained negative. Moreover, the use of (Th/U)O2 homogenous and heterogeneous configuration had shown an improved response compared to the reference core at 600 K and 1 000 K. The doppler reactivity coefficient has been found as –8.98E-3 pcm/K, -0.8 655 pcmK for the homogenous and –8.854 pcm/K, -1.2253 pcm/K for the heterogeneous configuration. However, the pattern remained the same as for the reference core at other temperature points. MOX fuel has shown less response compared to the other fuel configuration because of the high resonance absorption coefficient of Plutonium. This study showed that the SMART reactor could be operated safely with investigated fuel and models.