Development of a technological complex for thermofriction hardening of products with a circular cross section

There are many methods of influencing the structural state of the surface of products of different shapes and different purposes. At the same time, the increase in the relevance of the application of a particular method is closely related to its ability to provide high hardening rates while reducing the cost of such products. The TFН technology has already shown its high efficiency in strengthening surfaces [1]. In addition, studies were conducted on the hardening of surfaces of different profiles [2]. However, the best results are achieved when hardening flat surfaces. In this regard, it is entirely appropriate to conduct research that is related to the development of a technological complex that would include the optimal ratio of processing factors to ensure the necessary level of hardening in the studied objects that have a circular cross-section. Goal. The purpose of this work is to develop a technological complex for processing objects with a circular cross-section. To achieve this goal, metallographic and durometric studies of samples in the initial state and after processing were carried out. At the same time, the changes in the structure and mechanical properties that occur in steel due to processing were studied. Method. The method of thermal friction hardening includes a combined effect of heat and deformation on the treated surface. The peculiarity of this method is the deformation under short-term heating conditions. This makes it possible to further strengthen pre-hardened materials. Results. Under the influence of TFC, significant changes are observed in the structure of cylindrical samples made of 65G steel. This is expressed by the formation of a so-called "white surface layer" in the surface of these samples, which has an ultra-high microhardness [13, 14]. The properties of this layer depend on the initial state of the material, the conditions and modes of conducting TFН.

The microstructure and mechanical properties of Co/YCF102 composite coating

Purpose Laser cladding has been used in the field of repairing damaged parts of machine tools due to its advantages of less processing restrictions and easy formation of a good metallurgical bond with the base material. However, the mechanical properties of the coating sometimes cannot meet the process requirements. Therefore, the purpose of this paper is to prepare coatings with high microhardness and flexural strength. Design/methodology/approach The YCF102 alloy powder was mixed with different contents of Co and tested for laser cladding on AISI 1045 substrate under the same process parameters. The main phase composition of the coating was revealed by the XRD results. The main chemical composition of the coating was determined by the SEM and EDS results. In addition, the effect of Co content on the microstructure, microhardness and flexural strength of the coatings was investigated. Findings The results show that when the Co content is 2 wt% and 4 wt%, Co does not form compounds with other elements, but is uniformly distributed in the coating. And when the Co content is 6 wt% and 8 wt%, the Co reacts with Fe in the coating and generates Co3Fe7 in situ. The increase in Co did not result in a monotonic change in microhardness, but significantly improved the flexural strength and the flatness of the microstructure of the coating. When the Co content of the mixed powder is 8 wt%, the coating has high microhardness and flexural strength. Originality/value Co/YCF102 composite coating with high microhardness and flexural strength was prepared. This paper provides a theoretical and practical basis for research in the area of repairing damaged parts of machine tools by laser cladding.

Fabrication of Ultra-Fine-Grained W-TiC Alloys by a Simple Ball-Milling and Hydrogen Reduction Method

In this paper, a simple method to fulfill the ideal microstructural design of particle reinforced tungsten (W) alloys with promising mechanical properties is presented. W-0.5 wt.% TiC powders with core-shell (TiC/W) structure are prepared by ball-milling and controlled hydrogen reduction processes. TEM observation demonstrates that the nano TiC particles are well coated by tungsten. The W-TiC powders are sintered by spark plasma sintering (SPS) under 1600 °C. The sintered microstructures are characterized by FESEM and TEM. It is found that the W-0.5TiC alloys obtain an ultra-fine-sized tungsten grain of approximately 0.7 μm. The TiC particles with the original nano sizes are uniformly distributed both in tungsten grain interiors and at tungsten grain boundaries with a high number density. No large agglomerates of TiC particles are detected in the microstructure. The average diameter of the TiC particles in the tungsten matrix is approximately 47.1 nm. The mechanical tests of W-0.5 TiC alloy show a significantly high microhardness and bending fracture strength of 785 Hv0.2 and 1132.7 MPa, respectively, which are higher than the values obtained in previous works. These results indicate that the methods used in our work are very promising to fabricate particle-dispersion-strengthened tungsten-based alloys with high performances.

Structure and properties of titanium oxide-based protective coatings

The presented work examined the composition of nitrogen plasma with weight average temperature 49 kК. Correlation between the treatment mode and the structural-phase composi-tion and hydrophobic properties of the titanium oxide coating was found. It was shown that regardless of the plasma treatment mode, all coatings had a high microhardness value of more than 25 GРa and a high resistivity of more than 3105 Om cm.

Formation of Nanolaminated Structure with Enhanced Thermal Stability in Copper

Nanolaminated structure with an average boundary spacing of 67 nm has been fabricated in copper by high-rate shear deformation at ambient temperature. The nanolaminated structure with an increased fraction of low angle grain boundaries exhibits a high microhardness of 2.1 GPa. The structure coarsening temperature is 180 K higher than that of its equiaxial nanograined counterpart. Formation of nanolaminated structure provides an alternative way to relax grain boundaries and to stabilize nanostructured metals with medium to low stacking faults energies besides activation of partial dislocations.

Characterization of the AZ31/AW-6060 Joint Fabricated using Compound Casting with a Zn Interlayer at Relatively Low Temperature Conditions

The work deals with the fabrication of a joint between AZ31 magnesium alloy and AW-6060 aluminium alloy with the use of a Zn interlayer. The Zn layer was produced on the surface of an AW-6060 alloy insert by diffusion bonding. The insert was then placed inside a steel mould and kept at room temperature. The joint was produced using compound casting by filling the mould with liquid AZ31 alloy, heated to 650 °C. The microstructure of the bonding zone formed between joined alloys was analysed using an optical microscope and a scanning electron microscope equipped with an energy dispersive X-ray spectroscope. The properties of the joint were examined using Vickers microhardness measurements and simple shear strength testing. As a result of the experiment, the 400 μm thick bonding zone with a complex microstructure was formed between the alloys. The microstructural analysis showed that the bonding zone reveals a high concentration of Zn and Mg. The layers of a eutectoid (a MgZn phase + a solid solution of Al and Zn in Mg), a Mg5Al2Zn2 phase and a Mg(Al,Zn)2 phase with fine particles of other phases were observed there. The bonding zone was characterized by relatively high microhardness, which was related to the brittleness of the constituents. The shear strength of the examined joint was 19.6 ± 2.5 MPa.

Influence of pulse plasma treatment on the phase composition and microhardness of detonation coatings based on Ti-Si-C

The paper considers the study results of the phase composition and microhardness of detonation coatings based on Ti-Si-C after exposure to pulsed plasma treatment. The CCDS2000 detonation complex was used to obtain the coatings. Coatings surface modification was carried out using pulsed plasma exposure (PPE). The detonation coatings were treated with varying the distance H (30 mm mode 1, 40 mm mode 2, 50 mm mode 3) from the plasmatron to the hardened surface. It is shown that the treated coatings are generally characterized by high microhardness compared to the original coating. It was determined that after treatment by pulsed plasma effects an increase in the intensity of all reflexes phase Ti3SiC2 was observed, and the appearance of reflexes (101, 102, 112, 204, 0016) phase Ti3SiC2 was found, which indicates the increase of the content of Ti3SiC2 phase. The change in the fraction of phases indicates a solid-phase transformation during pulsed-plasma activation. High hardness is observed on the coating surface treated according to mode 3 (50 mm) and as it approaches the surface of the substrate modes 2 (40 mm) and 1 (30 mm) the hardness decreases. It is established that the increase in the microhardness of detonation coatings after pulse-plasma treatment is associated with an increase in the content of Ti3SiC2 phases in the coatings, as well as an increase in the defects density in the modified layer.

MODIFICATION OF COATINGS BASED ON Al2O3 WITH CONCENTRATED ENERGY FLOWS

This paper presents the study results of structural-phase composition and mechano-tribological properties of Al2O3 coatings after exposure of concentrated energy flows. Revealed that the treated coatings are generally characterized by high microhardness compared to the initial coating. Determined that after treatment with detonation and air-plasma action is observed an increase in the intensity of α-Al2O3 reflexes. Established that the increasing hardness of detonation coatings is associated with an increasing density of the material and the recovery of the α-phase Al2O3 in the composition of the protective layer under the influence of thermal activation of the surface. Determined that after treatment with detonation and plasma exposure is observed an increase in the intensity of reflexes α-Al2O3. Established that the treatment with detonation and air-plasma action leads to a decrease in the friction coefficient. The obtained data indicate that the tribological characteristics of coating based on aluminium oxide can be improved by exposure to concentrated energy flows. Established that coatings treated with plasma action showed high tribological properties.

PHYSICAL AND MECHANICAL PROPERTIES OF MULTI-ELEMENT COATINGS

A number of experiments were conducted to measure the physical and mechanical properties of multielement coatings. To apply CrNiTiFeCu coatings on a nickel-chromium substrate, the technology of magnetron deposition in an atmosphere of argon or nitrogen was used. The results of measurements of the microhardness as well as the coefficients of friction and wear resistance of the applied CrNiTiFeCu thin films are presented. The findings indicate that the studied samples show a high microhardness and wear resistance. Consequently, there is a possibility to extend the lifespan of mechanisms and machines parts.

Characteristics of Cr-B Coatings Produced on Vanadis® 6 Tool Steel Using Laser Processing

The paper presents the results of a study of the microstructure, chemical composition, microhardness and corrosion resistance of Cr-B coatings produced on Vanadis 6 tool steel. In this study, chromium and boron were added to the steel surface using a laser alloying process. The main purpose of the study was to determine the impact of those chemical elements on surface properties. Chromium and boron as well as their mixtures were prepared in various proportions and then were applied on steel substrate in the form of precoat of 100 µm thickness. Depending on the type of precoat used and laser processing parameters, changes in microstructure and properties were observed. Coatings produced using precoat containing chromium and boron mixture were characterized by high microhardness (900 HV0.05–1300 HV0.005) while maintaining good corrosion resistance. It was also found that too low laser beam power contributed to the formation of cracks and porosity.