Heterometallic coordination polymers as heterogeneous electrocatalysts

Heterometallic coordination polymers are emerging as a class of crystalline materials for sustainable energy production via electrocatalysis thanks to the synergistic and cooperative effects of different kinds of metal centres...

Solvothermal synthesis, structure and magnetic properties of heterometallic coordination polymers based on a phenolato-oxamato co-bidentate-tridentate ligand

First examples of 1D oxamate-based coordination polymers obtained solvothermally.

Heterometallic coordination polymers: Treatment activity on diabetic foot by reducing the excess inflammatory response in the plantar tissue

Two new heterometallic coordination polymers formulated as {[LaCo(2.5-pydc)2(H2O)4]Cl·4H2O}n (1, 2,5-H2pydc = pyridine-2,5-dicarboxylic acid) and {[LaCo2Cl3(4,4′-bpdc)2(H2O)3]·H2O}n (2, 4,4′-H2bpdc = 2,2′-bipyridyl-4,4′-dicarboxylic acid) have been solvothermally synthesized using the coordination between rare earth/transition metal ions and pyridinedicarboxylic acids. To develop new candidates for enhancing the therapeutic effect of improved negative pressure suction for diabetic foot, the activities of compounds 1 and 2 were studied. First, the ELISA (enzyme linked immunosorbent assay) detection kit was used and the inflammatory cytokines in the plantar tissue were measured. Besides, the TLR-4-NF-κB signaling pathway was measured with real-time reverse transcription-polymerase chain reaction.

Single molecule magnets of cobalt and zinc homo- and heterometallic coordination polymers prepared by a one-step synthetic procedure

One-pot synthesis of heterometallic (Zn(ii)/Co(ii)) nodes directing CP magnetic behaviour to single molecule magnets.

Heterometallic coordination polymers based on homo- and heteroleptic Au(iii) dithiolene complexes

Two novel hetero- and homoleptic Au(iii) dithiolene complexes have been designed, synthesized, characterized and employed for the elaboration of heterometallic coordination networks.