In Situ Compensation Method for Precise Integral SQUID Magnetometry of Miniscule Biological, Chemical, and Pow-der Specimens Requiring the Use of Capsules

Steadily growing interest in magnetic characterization of organic compounds for therapeutic purposes or of other irregularly shaped specimens calls for refinements of experimental methodology to satisfy experimental challenges. Encapsulation in capsules remains the method of choice, but its applicability in precise magnetometry is limited. This is particularly true for minute specimens in the single milligram range as they are outweighed by the capsules and are subject to large alignment errors. We present here a completely new experimental methodology that permits 30-fold in situ reduction of the signal of capsules by substantially restoring the symmetry of the sample holder that is otherwise broken by the presence of the capsule. In practical terms it means that the standard 30 mg capsule is seen by the magnetometer as approximately a 1 mg object, effectively opening the window for precise magnetometry of single milligram specimens. The method is shown to work down to 1.8 K and in the whole range of the magnetic fields. The method is demonstrated and validated using the reciprocal space option of MPMS-SQUID magnetometers; however, it can be easily incorporated in any magnetometer that can accommodate straw sample holders (i.e., the VSM-SQUID). Importantly, the improved sensitivity is accomplished relying only on the standard accessories and data reduction method provided by the SQUID manufacturer, eliminating the need for elaborate raw data manipulations.

In Situ Compensation Method for Precise Integral SQUID Magnetometry of Miniscule Biological, Chemical, and Powder Specimens Requiring the Use of Capsules

Steadily growing interest in magnetic characterization of organic compounds for therapeutic purposes or of other irregularly shaped specimens calls for refinements of experimental methodology to satisfy experimental challenges. Encapsulation in capsules remains the method of choice, but its applicability in precise magnetometry is limited. This is particularly true for minute specimens in the single milligram range as they are outweighed by the capsules and are subject to large alignment errors. We present here a completely new experimental methodology that permits 30-fold in situ reduction of the signal of capsules by substantially restoring the symmetry of the sample holder that is otherwise broken by the presence of the capsule. In practical terms it means that the standard 30 mg capsule is seen by the magnetometer as approximately a 1 mg object, effectively opening the window for precise magnetometry of single milligram specimens. The method is shown to work down to 1.8 K and in the whole range of the magnetic fields. The method is demonstrated and validated using the reciprocal space option of MPMS-SQUID magnetometers; however, it can be easily incorporated in any magnetometer that can accommodate straw sample holders (i.e., the VSM-SQUID). Importantly, the improved sensitivity is accomplished relying only on the standard accessories and data reduction method provided by the SQUID manufacturer, eliminating the need for elaborate raw data manipulations.

In Situ Compensation Method for Precise Integral SQUID Magnetometry of Miniscule Biological, Chemical, and Pow-der Specimens Requiring the Use of Capsules

Steadily growing interest in magnetic characterization of organic compounds aiming at therapeutic purposes, or of other irregular-shaped specimens calls for refinements of experimental methodology to satisfy experimental challenges. Encapsulation in capsules remains the method of choice, but its applicability in precise magnetometry is limited. This is particularly true for minute specimens in single mg range since they are outweighed by the capsules and due to large alignment errors. We present here a complete new experimental methodology which permits 30-fold in situ reduction of the signal of capsules. In practical terms it means that the standard 30 mg capsule is seen by the magnetometer as about 1 mg object, effectively opening the window for precise magnetometry of single mg specimens. The method is shown to work down to 1.8 K and in the whole range of the magnetic fields. The method is demonstrated and validated using the reciprocal space option of MPMS-SQUID magnetometers, however it can be easily incorporated in any magnetometer which can accommodate straw sample holders (i.e. the VSM-SQUID). Importantly, the improved sensitivity is accomplished relying only on the standard accessories and data reduction method provided by the SQUID manufacturer, eliminating needs for an elaborate raw data manipulations.

There's more Wrangellia - Magnetic characterization of southern Alaska crust

In southern Alaska, Wrangellia-type magnetic crustal character extends from the Talkeetna Mountains southwest through the Alaska Range to the Bristol Bay region. Magnetic data analyses in the Talkeetna Mountains showed that there are mid-crustal differences in the magnetic properties of Wrangellia and the Peninsular terrane. After converting total field magnetic anomaly data to magnetic potential, we applied Fourier filtering techniques to remove magnetic responses from deep and shallow sources. The resulting mid-crustal magnetic characterization delineates the regional magnetic potential domains that correspond to the Wrangellia and Peninsular terranes throughout southern Alaska. These magnetic potential domains show that Wrangellia-type crust extends southwest to the Illiamna Lake region and that it overlaps the mapped Peninsular terrane. Upon reconsidering geologic ties between Wrangellia, Peninsular, and Alexander terranes we conclude that Peninsular terrane is part of what we here call Western Wrangellia. Western Wrangellia contains the Lower Jurassic Talkeetna volcanic arc and is similar to Wrangellia of the Vancouver Island area, Canada (Southern Wrangellia) which contains the Lower Jurassic Bonanza volcanic arc. Others have previously made this correlation and proposed that the Talkeetna arc-bearing part of southern Alaska was displaced from the Bonanza arc-bearing part of Canada. We generally agree and propose that about 1000 km of dextral displacement along ancestral Border Ranges fault segments and other faults of south-central Alaska separated Western Wrangellia from Southern Wrangellia. We think this displacement was mostly in the Late Jurassic and earliest Cretaceous, perhaps between about 160 and 130 Ma.