ruthenium oxidation
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2015 ◽  
Vol 118 (5) ◽  
pp. 055303 ◽  
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R. Coloma Ribera ◽  
R. W. E. van de Kruijs ◽  
A. E. Yakshin ◽  
F. Bijkerk

ACS Nano ◽  
2015 ◽  
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Jan Ingo Flege ◽  
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Herbert Over ◽  
Eugene E. Krasovskii ◽  
...  

2013 ◽  
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Shiguo Sun ◽  
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Xiaojun Peng

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The effects of ruthenium (Ru)-oxidation states were investigated on Ru dissolution from PtRu thin-film electrodes, with the 200 cycles between 0.4 and 1.05 V (versus normal hydrogen electrode). The Ru-oxidation states of the PtRu thin films were systematically modified by an anodic (oxidation) treatment. The anodic-treated PtRu electrodes, whose methanol-oxidation activity was similar to untreated electrodes before the 200 cycles, showed a remarkable decrease in methanol oxidation after the cycles, because of the Ru dissolution from the PtRu surface. The results suggest that the Ru-oxide species are the origin of Ru dissolution in the PtRu alloy.


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