Biotechnological synthesis of Pd-based nanoparticle catalysts

Cell supported Pd metal nanoparticles are sustainably synthesised via microbial bioreduction. Bio-Pd nanoparticles are effective heterogeneous catalysts that catalyse industrially important reactions, such as hydrogenation and C–C coupling reactions.

Swift Reduction of Nitroaromatics By Gold Nanoparticles Anchored On Steam-Activated Carbon Black Via Simple Preparation

Gold (Au) nanoparticles supported on certain platforms display highly efficient activity on nitroaromatics reduction. In this study, steam-activated carbon black (SCB) was used as a platform to fabricate Au/SCB catalysts via a green and simple method for 4-nitrophenol (4-NP) reduction. The obtained Au/SCB catalysts exhibit efficient catalytic performance in reduction of 4-NP (rate constant kapp = 2.1925 min-1). The effects of SCB activated under different steam temperature, Au loading amount, pH and reaction temperature were studied. The structural advantages of SCB as a platform were analyzed by various characterizations. Especially, the result of N2 adsorption-desorption method showed that steam activating process could bring higher surface area (from 185.9689 m²/g to 249.0053 m²/g), larger pore volume (from 0.073268 cm³/g to 0.165246 cm³/g) and more micropore for SCB when compared with initial CB, demonstrating the suitable of SCB for Au NPs anchoring, thus promoting the catalytic activity. This work contributes to the fabrication of other supported metal nanoparticle catalysts for preparing different functional nanocomposites for different applications.