Effect of Low-Pressure Plasma Nitriding with Hollow Cathode Discharge on the Surface Microstructure of WC-Co Cermet

WC-Co cermet was plasma-nitrided with the assistance of a hollow cathode ion source at 400 °C under a vacuum of 3–8 Pa. Hot film chemical vapor deposition (HFCVD) of a diamond coating was carried out on the nitrided specimen, without chemical etching. Scanning electronic microscopy, electron probing microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy were used to characterize the surface microstructure of the nitride specimens and the coatings. A thin surface conversion layer with a specific structure was formed, in which the primary Co binder was transformed into Co-rich particles. The Co-rich particles consisted of a γ-Co core and a Co4N outer layer. This specific surface conversion layer significantly suppresses the out-diffusion and catalytic graphitization of Co during HFCVD. The existent phase, morphology, and density distribution of Co compounds can be tuned by varying the nitriding parameters, such as gas media, ionization ratio, bombardment energy flux, and nitriding duration.

Negative Hydrogen and Deuterium Ion Density in a Low Pressure Plasma in Front of a Converter Surface at Different Work Functions

Negative ion sources of neutral beam injection (NBI) systems for future fusion devices like ITER (“The Way” in Latin) rely on the surface conversion of hydrogen (or deuterium) atoms and positive ions to negative ions in an inductively coupled plasma (ICP). The efficiency of this process depends on the work function of the converter surface. By introducing caesium into the ion source the work function decreases, enhancing the negative ion yield. In order to study the isotope effect on the negative ion density at different work functions, fundamental investigations are performed in a planar ICP laboratory experiment where the work function and the negative ion density in front of a sample can be simultaneously and absolutely determined. For work functions above 2.7 eV, the main contribution to the negative hydrogen ion density is solely due to volume formation, which can be modeled via the rate balance model YACORA H−, while below 2.7 eV the surface conversion become significant and the negative ion density increases. For a work function of 2.1 eV (bulk Cs), the H− density increases by at least a factor of 2.8 with respect to a non-caesiated surface. With a deuterium plasma, the D− density measured at 2.1 eV is a factor of 2.5 higher with respect to a non-caesiated surface, reaching densities of surface produced negative ions comparable to the hydrogen case.

Vacancy defective perovskite Na0.85Ni0.45Co0.55F3.56 nanocrystal anodes for advanced lithium-ion storage driven by surface conversion and insertion hybrid mechanisms

A vacancy defective perovskite Na0.85Ni0.45Co0.55F3.56 nanocrystal anode material constructs advanced lithium-ion storage devices with surface conversion and insertion hybrid mechanisms.