scholarly journals From n-butyl acrylate Arrhenius parameters for backbiting and tertiary propagation to β-scission via stepwise pulsed laser polymerization

2019 ◽  
Vol 10 (30) ◽  
pp. 4116-4125 ◽  
Author(s):  
Anil B. Vir ◽  
Yoshi W. Marien ◽  
Paul H. M. Van Steenberge ◽  
Christopher Barner-Kowollik ◽  
Marie-Françoise Reyniers ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Butyl Acrylate ◽  
Pulsed Laser ◽  
Arrhenius Parameters ◽  
Stepwise Method ◽  
Pulsed Laser Polymerization

A stepwise method to estimate the Arrhenius parameters for backbiting, tertiary propagation, and β-scission in acrylate radical polymerization.

Investigating the propagation kinetics of a novel class of nitrogen-containing methacrylates via PLP-SEC

2016 ◽  
Vol 7 (26) ◽  
pp. 4342-4351 ◽  
Author(s):  
Katrin B. Kockler ◽  
Friederike Fleischhaker ◽  
Christopher Barner-Kowollik
Keyword(s):  
Size Exclusion Chromatography ◽  
Rate Coefficient ◽  
Pulsed Laser ◽  
Propagation Rate ◽  
Size Exclusion ◽  
Arrhenius Parameters ◽  
Exclusion Chromatography ◽  
Kinetics Of ◽  
Propagation Rate Coefficient ◽  
Pulsed Laser Polymerization

The Mark–Houwink–Kuhn–Sakurada parameters as well as Arrhenius parameters of the propagation rate coefficient for a new group of nitrogen-containing methacrylates were determined via triple detector SEC and pulsed laser polymerization–size exclusion chromatography, respectively.

Pulsed-Laser Polymerization Measurements of the Propagation Rate Coefficient for Butyl Acrylate

1996 ◽  
Vol 29 (6) ◽  
pp. 1918-1927 ◽  
Author(s):  
Robert A. Lyons ◽  
Jelica Hutovic ◽  
Mark C. Piton ◽  
David I. Christie ◽  
Paul A. Clay ◽  
...  
Keyword(s):  
Butyl Acrylate ◽  
Rate Coefficient ◽  
Pulsed Laser ◽  
Propagation Rate ◽  
Propagation Rate Coefficient ◽  
Pulsed Laser Polymerization

scholarly journals Pulsed laser polymerisation studies of methyl methacrylate in the presence of AlCl3 and ZnCl2 – evidence of propagation catalysis

2017 ◽  
Vol 8 (38) ◽  
pp. 5948-5953 ◽  
Author(s):  
Jing Y. Jiang ◽  
Leesa M. Smith ◽  
Jason H. Tyrell ◽  
Michelle L. Coote
Keyword(s):  
Methyl Methacrylate ◽  
Radical Polymerization ◽  
Lewis Acids ◽  
Pulsed Laser ◽  
Pulsed Laser Polymerization

Pulsed laser polymerization experiments demonstrate that Lewis acids electrostatically catalyse the propagation step in radical polymerization of methyl methacrylate.

Chain Length Dependent Termination in Butyl Acrylate Free-Radical Polymerization Studied via Stationary and Pulsed Laser Initiated RAFT Polymerization

2005 ◽  
Vol 38 (23) ◽  
pp. 9497-9508 ◽  
Author(s):  
Tanja Junkers ◽  
Alexander Theis ◽  
Michael Buback ◽  
Thomas P. Davis ◽  
Martina H. Stenzel ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Chain Length ◽  
Butyl Acrylate ◽  
Raft Polymerization ◽  
Pulsed Laser ◽  
Free Radical Polymerization
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