hydrogen phthalate esters
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Preparation and Structural Elucidation of cis-and trans-Phenyl-2-methylcyclohexanol

1971 ◽  
Vol 49 (24) ◽  
pp. 4116-4118 ◽  
Author(s):  
K. G. Rutherford ◽  
S. Wassenaar ◽  
J. F. Brien ◽  
D. P. C. Fung
Keyword(s):  
Phthalate Esters ◽  
Structural Elucidation ◽  
Hydrogen Phthalate ◽  
Isomeric Mixture ◽  
Hydrogen Phthalate Esters ◽  
Cis And Trans ◽  
Hydrolysis Of

The preparation of cis- and trans-1-phenyl-2-methylcyclohexanol by hydrolysis of an isomeric mixture of the corresponding hydrogen phthalate esters is described. The elucidation of the structures of the alcohols is also described.

The reaction of some benzhydryl hydrogen phthalate esters with thionyl chloride:

Tetrahedron ◽  
1971 ◽  
Vol 27 (13) ◽  
pp. 2627-2630 ◽  
Author(s):  
K.G. Rutherford ◽  
J.F. Brien ◽  
O.A. Mamer
Keyword(s):  
Thionyl Chloride ◽  
Phthalate Esters ◽  
Hydrogen Phthalate ◽  
Hydrogen Phthalate Esters

LOW-TEMPERATURE PYROLYSIS: I. THE PYROLYSIS OF HYDROGEN PHTHALATE ESTERS OF SOME TERTIARY ALCOHOLS

1964 ◽  
Vol 42 (12) ◽  
pp. 2657-2664 ◽  
Author(s):  
K. G. Rutherford ◽  
D. P. C. Fung
Keyword(s):  
Liquid Phase ◽  
Low Temperature ◽  
Phthalic Acid ◽  
Phthalate Esters ◽  
Ionic Character ◽  
Hydrogen Phthalate ◽  
Tertiary Alcohols ◽  
Hydrogen Phthalate Esters ◽  
Low Temperature Pyrolysis

Some hydrogen phthalate esters of tertiary alcohols have been subjected to liquid phase pyrolysis. Olefinic mixtures and phthalic acid are the only products of the reaction. A study of the olefin distribution for each of the compounds pyrolyzed was made. Evidence of ionic character in liquid phase pyrolysis is presented.

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