LOW-TEMPERATURE PYROLYSIS: I. THE PYROLYSIS OF HYDROGEN PHTHALATE ESTERS OF SOME TERTIARY ALCOHOLS

1964 ◽  
Vol 42 (12) ◽  
pp. 2657-2664 ◽  
Author(s):  
K. G. Rutherford ◽  
D. P. C. Fung
Keyword(s):  
Liquid Phase ◽  
Low Temperature ◽  
Phthalic Acid ◽  
Phthalate Esters ◽  
Ionic Character ◽  
Hydrogen Phthalate ◽  
Tertiary Alcohols ◽  
Hydrogen Phthalate Esters ◽  
Low Temperature Pyrolysis

Some hydrogen phthalate esters of tertiary alcohols have been subjected to liquid phase pyrolysis. Olefinic mixtures and phthalic acid are the only products of the reaction. A study of the olefin distribution for each of the compounds pyrolyzed was made. Evidence of ionic character in liquid phase pyrolysis is presented.

The reaction of some benzhydryl hydrogen phthalate esters with thionyl chloride:

Tetrahedron ◽  
1971 ◽  
Vol 27 (13) ◽  
pp. 2627-2630 ◽  
Author(s):  
K.G. Rutherford ◽  
J.F. Brien ◽  
O.A. Mamer
Keyword(s):  
Thionyl Chloride ◽  
Phthalate Esters ◽  
Hydrogen Phthalate ◽  
Hydrogen Phthalate Esters

Low-temperature pyrolysis. II. An isotope study of the pyrolysis of the hydrogen phthalate ester of trans-1,2-dimethylcyclohexanol

1967 ◽  
Vol 45 (7) ◽  
pp. 679-681
Author(s):  
K. G. Rutherford ◽  
R. M. Ottenbrite
Keyword(s):  
Thermal Decomposition ◽  
Low Temperature ◽  
Phthalic Anhydride ◽  
Ion Pair ◽  
Phthalate Ester ◽  
Hydrogen Phthalate ◽  
Isotope Study ◽  
Sterically Hindered ◽  
Low Temperature Pyrolysis

The hydrogen phthalate ester of trans-l,2-dimethylcyclohexanol was prepared by using phthalic anhydride enriched in 18O. The ester was partially decomposed at 128°. An observed enrichment of 18O in the alcohol portion of the undecomposed ester supports an earlier postulate that an ion pair is involved in the thermal decomposition of this sterically hindered ester.

Preparation and Structural Elucidation of cis-and trans-Phenyl-2-methylcyclohexanol

1971 ◽  
Vol 49 (24) ◽  
pp. 4116-4118 ◽  
Author(s):  
K. G. Rutherford ◽  
S. Wassenaar ◽  
J. F. Brien ◽  
D. P. C. Fung
Keyword(s):  
Phthalate Esters ◽  
Structural Elucidation ◽  
Hydrogen Phthalate ◽  
Isomeric Mixture ◽  
Hydrogen Phthalate Esters ◽  
Cis And Trans ◽  
Hydrolysis Of

The preparation of cis- and trans-1-phenyl-2-methylcyclohexanol by hydrolysis of an isomeric mixture of the corresponding hydrogen phthalate esters is described. The elucidation of the structures of the alcohols is also described.

Chemical yields from low-temperature pyrolysis of CCA-treated wood

2009 ◽  
Author(s):  
Qirong Fu ◽  
Dimitris Argyropolous ◽  
Lucian Lucia ◽  
David Tilotta ◽  
Stan Lebow
Keyword(s):  
Low Temperature ◽  
Treated Wood ◽  
Low Temperature Pyrolysis

Preparation of Organic/Inorganic Membrane by PDMS Low-temperature Pyrolysis

2014 ◽  
Vol 29 (2) ◽  
pp. 137-142
Author(s):  
Jiao-Zhu YU ◽  
Lin LI ◽  
Xin JIN ◽  
Ling-Hua DING ◽  
Tong-Hua WANG
Keyword(s):  
Low Temperature ◽  
Inorganic Membrane ◽  
Low Temperature Pyrolysis
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