fries reaction
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2017 ◽  
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2017 ◽  
Vol 129 (26) ◽  
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2015 ◽  
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Vol 2014 ◽  
pp. 1-6 ◽  
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Irradiation ofN-arylO-aryl carbamates has been carried out in H2O/CH3CN (1 : 1 v/v) solutions atλ>290 nm. When chlorine is on theN-aryl ring, halogen-substituted products are found. These photoproducts derive from the trapping of the intermediate radical cation by water and, even, by acetonitrile leading to phenols andN-arylacetamides (photo-Ritter products), respectively. UnsubstitutedN-aryl carbamates slowly undergo photo-Fries reaction.


Author(s):  
Arun Parikh ◽  
Hansa Parikh ◽  
Khyata Parikh
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