KARAKTERISTIK FLUIDA PEMBAWA MINERALISASI PIT RAMBA JORING DEPOSIT MARTABE, SUMATRA UTARA

Penelitian ini bertujuan untuk mengetahui evolusi hidrotermal dari fluida pembawa mineralisasi yang terdapat di Pit Ramba Joring, meliputi temperatur, tekanan, densitas dan kedalaman pembentukan mineralisasi. Penelitian ini menggunakan analisis inklusi fluida. Sampel yang dianalisis merupakan sampel yang terindikasi terbentuk bersamaan dengan mineralisasi bijih (syngenetik), pada dua tekstur utama bijih yaitu batuan dengan tekstur silica vuggy yang terbentuk pada kisaran Th 331ºC hingga 394ºC, Tm -15,19ºC hingga -12,94ºC dengan salinitas 14,42 wt% hingga 14,89 wt%. NaCl equivalent dan batuan dengan tekstur brecciated terbentuk pada kisaran Th 287,8°C hingga 398,2°C, Tm -14,89°C hingga -11,76ºC serta salinitas 13,91 wt% hingga 4,87 wt%. NaCl equivalent. Korelasi positif antara temperatur homogenisasi pembentukan mineralisasi dengan salinitas larutan menandakan bahwa proses leaching yang membentuk rongga pada batuan terjadi pada stage awal proses alterasi hidrotermal yang diawali dengan proses leaching membentuk rongga (vuggy silica) yang diikuti proses silisifikasi dengan tekstur brecciated, pada fase ini berlangsung pengendapan mineralisasi. Asal larutan yang menjadi larutan pembentuk endapan hidrotermal merupakan jenis larutan basinal water-seawater dalam bentuk connate water yang masih dipengaruhi oleh air permukaan/meteoric water yang menunjukkan adanya indikasi hubungan dengan magmatic water. Densitas fluida pembentuk bijih logam berkisar pada 0,8 gr/cm3 sampai dengan 0,9 gr/cm3 sedangkan proses pembentukan bijih pada Pit Ramba Joring termasuk dalam isothermal mixing dengan sedikit pengaruh pemanasan/boiling.

Theoretical inversion of the fossil hydrothermal systems with oxygen isotopes of constituent minerals partially re-equilibrated with externally infiltrated fluids

ABSTRACT While the external infiltration of water has been identified from modern geothermal and/or fossil hydrothermal systems through stable isotopes, the physicochemical boundary conditions like the initial oxygen isotopes of water $( {{\rm \delta }^{ 18}{\rm O}_{\rm W}^{\rm i} } ) $ and rock as well as alteration temperature were implicitly presumed or empirically estimated by the conventional forward modelling. In terms of a novel procedure proposed to deal with partial re-equilibration of oxygen isotopes between constituent minerals and water, the externally infiltrated meteoric and magmatic water are theoretically inverted from the early Cretaceous post-collisional granitoid and intruded Triassic gneissic country rock across the Dabie orogen in central-eastern China. The meteoric water with a $ {{\rm \delta }^{ 18}{\rm O}_{\rm W}^{\rm i} } $ value of −11.01 ‰ was externally infiltrated with a granitoid and thermodynamically re-equilibrated with rock-forming minerals at 140°C with a minimum water/rock (W/R)o ratio around 1.10 for an open system. The lifetime of this meteoric hydrothermal system is kinetically constrained less than 0.7 million years (Myr) via modelling of surface reaction oxygen exchange. A gneissic country rock, however, was externally infiltrated by a magmatic water with $ {{\rm \delta }^{ 18}{\rm O}_{\rm W}^{\rm i} } $ value of 4.21 ‰ at 340°C with a (W/R)o ratio of 1.23, and this magmatic hydrothermal system could last no more than 12 thousand years (Kyr) to rapidly re-equilibrate with rock-forming minerals. Nevertheless, the external infiltration of water can be theoretically inverted with oxygen isotopes of re-equilibrated rock-forming minerals, and the ancient hydrothermal systems driven by magmatism or metamorphism within continental orogens worldwide can be reliably quantified.

Investigating H2O contents in clinopyroxene from explosive versus effusive eruption products from Merapi volcano, Indonesia

<p>The 2010 eruption of Merapi produced pyroclastic deposits and lava flows that are compositionally very similar, raising the question as to the underlying reason of the differences in eruptive styles between the various phases of the 2010 eruptive events. To test whether primary magmatic volatile content is the reason for the different eruption styles, we analyzed magmatic water contents in nominally anhydrous clinopyroxene crystals contained in lava and ash from the 2010 eruptive events. We utilized two analytical approaches: (i) Fourier-transform infrared spectroscopy (FTIR) analysis of fresh clinopyroxene from the ash and lava samples and (ii) FTIR analysis of clinopyroxene both prior to and after experimental re-hydration. By employing calculated partition coefficients, we determined the magmatic water content of the magma from which the various crystals grew. The magmatic water content determined from the unmodified clinopyroxenes from lava samples yield a range of 0.35 wt.% to 2.02 wt.% H<sub>2</sub>O, whereas magmatic water contents determined from untreated clinopyroxene contained in the ash samples range between 0.04 and 3.25 wt.%, with two outliers at 4.62 and 5.19 and wt.%, respectively. In contrast, for the rehydrated crystals the range for lava derived clinopyroxene crystals is between 1.94 and 2.19 wt.% and for ash between 1.74 and 2.66 wt.%, with two crystals at extreme values of 0.85 and 3.20 wt.%. We interpret these results to indicate that crystals from different populations are present in the 2010 eruptive products, with the dominant group reflecting relatively low magmatic H<sub>2</sub>O contents (around 2 wt.%) due to storage in shallow magma reservoirs and pockets at high levels within the Merapi plumbing systems (e.g. top 3 km). The overall higher H<sub>2</sub>O range and the occasionally more extreme values recorded in clinopyroxenes from ash deposits may then represent the presence of a crystal population that last equilibrated at deeper levels and at higher water contents, i.e. these crystals derive from the replenishing magma that activated the shallow portion of the plumbing system during the 2010 events. While this is work in progress, our results so far seem to suggest that the pyroclastic deposits of the 2010 Merapi eruption may contain a higher fraction of clinopyroxene derived from ‘deeper magma’ with higher H<sub>2</sub>O contents then what we have detected in associated lavas.</p>

Fluid Evolution and Ore Genesis of the Qibaoshan Polymetallic Ore Field, Shandong Province, China: Constraints from Fluid Inclusions and H–O–S Isotopic Compositions

The Qibaoshan polymetallic ore field is located in the Wulian area, Shandong Province, China. Four ore deposits occur in this ore field: the Jinxiantou Au–Cu, Changgou Cu–Pb–Zn, Xingshanyu Pb–Zn, and Hongshigang Pb–Zn deposits. In the Jinxiantou deposit, three paragenetic stages were identified: quartz–pyrite–specularite–gold (Stage 1), quartz–pyrite–chalcopyrite (Stage 2), and quartz–calcite–pyrite (Stage 3). Liquid-rich aqueous (LV type), vapor-rich aqueous (V type), and halite-bearing (S type) fluid inclusions (FIs) are present in the quartz from stages 1–3. Microthermometry indicates that the initial ore-forming fluids had temperatures of 351–397 °C and salinities of 42.9–45.8 mas. % NaCl equivalent. The measured hydrogen and calculated oxygen isotopic data for fluid inclusion water (δ18OFI = 11.1 to 12.3‰; δDFI = −106.3 to −88.6‰) indicates that the ore-forming fluids were derived from magmatic water; then, they were mixed with meteoric water. In the Changgou deposit, three paragenetic stages were identified: quartz–pyrite–specularite (Stage 1), quartz–pyrite–chalcopyrite (Stage 2), and quartz–galena–sphalerite (Stage 3). LV, V, and S-type FIs are present in the quartz from stages 1–3. Microthermometry indicates that the initial ore-forming fluids had temperatures of 286–328 °C and salinities of 36.7–40.2 mas. % NaCl equivalent. The measured hydrogen and calculated oxygen isotopic data for fluid inclusion water (δDFI = −115.6 to −101.2‰; δ18OFI = 12.2 to 13.4‰) indicates that the ore-forming fluids were derived from magmatic water mixed with meteoric water. The characteristics of the Xingshanyu and Hongshigang deposits are similar. Two paragenetic stages were identified in these two deposits: quartz–galena–sphalerite (Stage 1) and quartz–calcite–poor sulfide (Stage 2). Only LV-type FIs are present in the quartz in stages 1–2. The ore-forming fluids had temperatures of 155–289 °C and salinities of 5.6–10.5 mas. % NaCl equivalent. The measured hydrogen and calculated oxygen isotopic data for fluid inclusion water (δDFI = −109.8 to −100.2‰; δ18OFI = 10.2 to 12.1‰) indicates that the ore-forming fluids were derived from circulating meteoric waters. The sulfur isotopes (δ34Ssulfide = 0.6 to 4.3‰) of the four deposits are similar, indicating a magmatic source for the sulfur with minor contributions from the wall rocks. The ore field underwent at least two phases of mineralization according to the chronology results of previous studies. Based on the mineral assemblage and fluid characteristics, we suggest that the late Pb–Zn mineralization was superimposed on the early Cu (–Au) mineralizaton in the Changgou deposit.

Mineralization of Luziyuan Pb–Zn skarn deposit, Baoshan, Yunnan Province, SW China: evidence from petrography, fluid inclusions and stable isotopes

The Luziyuan Pb–Zn skarn deposit, located in the Baoshan–Narong–Dongzhi block metallogenic belt in SW China, is hosted by marble and slate in the upper Cambrian Shahechang Formation. Three skarn zones have been identified from the surface (1495 m above sea level (asl)) to a depth of 1220 m asl: zone 1 consists of chlorite–actinolite–calcite–quartz, zone 2 of rhodonite–actinolite–fluorite–quartz–calcite, and zone 3 contains garnet–rhodonite–actinolite–fluorite–quartz–calcite. The deposit formed in four distinct mineralization stages: an early anhydrous skarn (garnet, rhodonite and bustamite) stage (Stage 1), a hydrous skarn (actinolite and chlorite) stage (Stage 2), an early quartz (coarse barren quartz veins) stage (Stage 3) and a late sulphide-forming (fine sulphide-bearing quartz veins) stage (Stage 4). The Stage 1 skarn-forming fluid temperature was at least 500 °C according to the geothermometer with rhodonite/bustamite trace elements measured by laser ablation – inductively coupled plasma – mass spectrometry (LA-ICP-MS). A decrease in ore fluid temperatures with time is consistent with the decreases in the δ18Ofluid and δDfluid values from Stage 3 to 4. This trend suggests that the ore fluid was mainly derived from magmatic water and mixed with large amounts of meteoric water during mineralization. The δ34S values of Stage 4 chalcopyrite, sphalerite and galena are similar to those of an Ordovician gypsum layer, and together with the high-salinity fluids in Stage 4 indicate the dissolution of evaporites in the Luziyuan region. Overall, the results of this study suggest that the Luziyuan deposit is a distal Pb–Zn skarn deposit that formed in response to multi-stage alteration associated with a combination of magmatic water and meteoric water.

Origin and Evolution of the Ore-Forming Fluids in the Liyuan Gold Deposit, Central North China Craton: Constraints from Fluid Inclusions and H-O-C Isotopic Compositions

The Liyuan gold deposit is hosted within Archean basement metamorphic rocks and controlled by the NNE-trending faults in the central North China Craton. The ore-forming processes can be divided into three stages (early, middle, and late). Three types of primary fluid inclusions (FIs) are identified in the Liyuan, including pure carbonic, carbonic-aqueous, and aqueous inclusions. The primary FIs of three stages are mainly homogenized at temperatures of 318–408°C, 201–329°C, and 136–229°C, with salinities of 2.1–8.9, 0.5–12.4, and 0.4–6.3 wt.% NaCl equivalent, respectively. The main Au mineralization is related to the middle stage, and water-rock interaction caused rapid precipitation of gold in this stage. The initial ore-forming fluids were likely magmatic water or metamorphic fluid and mixed with meteoric water at later stages. Due to the lack of granite body at the present mining levels, we speculate that it was magmatic water that might have been exsolved from a concealed granite body at greater depth or it was metamorphic fluid that was directly transported from depth via deep faults. Based on all the available geological and geochemical evidence, we suggest that the Liyuan deposit belongs to orogenic gold deposit that located in the interior North China Craton.