Exploring the Possibility of Using Ionic Copolymer Poly (Ethylene-co-Methacrylic) Acid as Modifier and Self-Healing Agent in Asphalt Binder and Mixture

It is well-accepted that the ionic copolymer poly (ethylene-co-methacrylic) acid (also named EMAA) is one type of self-healing material. This particular capability has great potential for extending the service life of infrastructures. In order to improve the rheological, mechanical, and self-healing properties of asphalt binder and asphalt mixtures, EMAA and styrene butadiene rubber (SBR) were selected as the additives. In this study, the effects of EMAA and SBR on the performance of bitumen and asphalt mixtures were examined and characterized using various parameters including rheological indices, Glover–Rowe parameter, ductility self-healing rate, fluorescence microscopy, and scanning electron microscope (SEM) test on binders, and different testing methods such as complex modulus, thermal stress-restrained specimen test (TSRST), disk-shaped compact tension (DCT), and fatigue–healing–fatigue test on the mixtures. The results showed that EMAA can significantly improve the stiffness and self-healing capacity of virgin and SBR modified binders and mixtures. Moreover, the cracking resistance of EMAA/SBR compound modified binder and mixture showed a significant improvement. However, EMAA is not recommended to be added as a modifier to virgin binders and mixtures due to its poor cracking resistance. Some novel tests and parameters mentioned in this paper are recommended for characterizing binders and mixtures in the future.

Nanocomposites of ionic copolymer integrating Gd-containing polyoxometalate as a multiple platform for enhanced MRI and pH-response chemotherapy

Nanocomposites from the co-assemblies of block copolymers and a gadolinium-grafting inorganic cluster were constructed as a multifunctional platform for MRI enhancement, drug loading, and environment-response release at local positions.

An amphiphilic manganese porphyrin-paired ionic copolymer: a highly efficient biphasic transfer catalyst for the selective oxidation of olefins with O2 and TBHP

A novel amphiphilic manganese porphyrin-paired ionic copolymer, {ADA-INA-[Mn(TPPS)(OAc)]}n, was prepared by the self-assembly process of non-cross-linked amphiphilic polymeric ligands with inorganic species.

POSS-derived mesoporous ionic copolymer–polyoxometalate catalysts with a surfactant function for epoxidation reactions

Novel mesoporous POSS-derived POM-paired polymeric hybrids were demonstrated to be highly efficient interfacial solid catalysts for the epoxidation of alkenes with H2O2.