Магнитные превращения и полиморфный переход ферромагнитных сталей при ударно-волновом нагружении

A.M. Molodets A.A. Golyshev, A.N. Emelyanov, A.A. Kozlov The method for recording magnetic transformation is presented for ferromagnetic steels under shock-wave loading. The operation of the magnetic transformation gauge is considered under shock-wave loading at the polymorphic transition pressure of ARMCO iron and 15Kh2NMFA (in Russian) nuclear reactors case steel. It is shown that the pressures of magnetic transformations of steels correlate with the pressures of polymorphic transitions of these shocked steels. Comparison of gauge readings and parameters of polymorphic transitions was performed for iron and steel during shock-wave compression and subsequent unloading

Gas-Dependent Reversible Structural and Magnetic Transformation between Two Ladder Compounds

We report reversible structural transformation that occurs in two ladder compounds: Cu2CO3(ClO4)2(NH3)6 (1) and Cu2CO3(ClO4)2(NH3)5(H2O) (2), when they are exposed to gaseous vapors. The ladder structures of both 1 and 2 consist of two Cu2+ ions and one CO32− ion. In 1, the Cu2+ ions are coordinated by three NH3 molecules on each side, while those in 2 are coordinated by three NH3 molecules on one side, and two NH3 molecules and one H2O molecule on the other side. We demonstrated reversible transformation of 1 and 2 via the exposure of 1 to H2O vapor and the exposure of 2 to NH3 vapor using a simple bench-scale method. The minor structural change observed led to a significant difference in physical properties, which we observed using several methods.