scholarly journals Gas-Dependent Reversible Structural and Magnetic Transformation between Two Ladder Compounds

Crystals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 841
Author(s):  
Jun Manabe ◽  
Kazuki Nishida ◽  
Xiao Zhang ◽  
Yuki Nakano ◽  
Masaru Fujibayashi ◽  
...  

We report reversible structural transformation that occurs in two ladder compounds: Cu2CO3(ClO4)2(NH3)6 (1) and Cu2CO3(ClO4)2(NH3)5(H2O) (2), when they are exposed to gaseous vapors. The ladder structures of both 1 and 2 consist of two Cu2+ ions and one CO32− ion. In 1, the Cu2+ ions are coordinated by three NH3 molecules on each side, while those in 2 are coordinated by three NH3 molecules on one side, and two NH3 molecules and one H2O molecule on the other side. We demonstrated reversible transformation of 1 and 2 via the exposure of 1 to H2O vapor and the exposure of 2 to NH3 vapor using a simple bench-scale method. The minor structural change observed led to a significant difference in physical properties, which we observed using several methods.

2020 ◽  
Vol 4 (2) ◽  
pp. 416-425
Author(s):  
Teuku Muhammad Afrizal ◽  
Hairul Basri ◽  
Muhammad Rusli Alibasyah

Abstrak. Gambut mengandung bahan organik yang tinggi. Gambut yang didrainase rentan terhadap kebakaran. Pemanfaatan gambut di Aceh sangat luas. Umumnya, gambut sering dibakar agar dapat dengan cepat dimanfaatkan., khususnya di Kecamatan Tripa Makmur Kabupaten Nagan Raya. Penelitian ini bertujuan untuk melihat seberapa jauh tingkat perubahan sifat fisika gambut terbakar Rawa Tripa Kabupaten Nagan Raya. Hasil penelitian menunjukkan bahwa rata-rata berat volume tertinggi terdapat pada sampel T1 (top soil) yaitu  0,36 g cm-3 dan terendah pada T0 (sub soil) yaitu  0,17 g cm-3. Kadar air tertinggi  terdapat pada sampel T0 (sub soil)  yaitu 234,82% dan terendah pada T1 (top soil) yaitu 81,96%. Porositas tertinggi terdapat pada sampel gambut T0  (sub soil) yaitu 94,93% dan terendah pada T1 (top soil) yaitu 65,28%. Permeabilitas tertinggi terdapat pada T0 (sub soil) yaitu 33,80 cm/jam dan terendah pada T1 (top soil) yaitu 16,10 cm/jam. Hasil uji statistik menunjukkan bahwa ada perbedaan yang signifikan pada parameter berat volume dengan t hitung (3,482) t tabel (1, 943), sedangkan pada parameter lainnya tidak ada perbedaan yang signifikan. Tingkat kematangan gambut di kawasan Tripa Makmur adalah hemik. Kedalaman gambut sebesar 3 meter.  Subsiden tertinggi adalah 100 cm pada gambut terbakar di tahun 2015. Warna  gambut adalah coklat kehitaman. The Effect of Burning Peat on Some of The Physical Porperties of Peat Soil in The Tripa Makmur Sub DistrictAbstract. Peat contains high organic matter. Drained peat is susceptible to fire. The use of peat in Aceh is very broad. Peat is often burned so that it can be quickly utilized especially in Tripa makmur Sub Districk, Nagan Raya Districk. This study aims to see how far the rate of change in the physical properties of peat is burning Rawa Tripa in Nagan Raya District. The results showed that the highest average of volume weight was found in T1(top soil) 0,36 g cm-3 and the lowest in T0(sub soil) 0,17 g cm-3. The highest water content was found inT0(sub soil) 234,82%  and the lowest was on T1(top soil) 81,96%. The highest porosity was found T0(sub soil) 94,93% and the lowest in T1(top soil) 65,28%. The highest permeability is found in T0(sub soil) 33,80 cm/hour and the lowest is on T1(top soil) 16,10 cm/hour. The results of statistical tests show that there is a significant difference in the parameters of volume weight with t count 3,482 t table 1,943, while in the other parameters have no significant differences. The level of maturity in the Tripa Makmur area is hemik. Peat depth of 3 meters. The highest subsidance is 100 cm on burning peat in 2015. The color of this peat is blackish brown. 


1986 ◽  
Vol 106 (3) ◽  
pp. 527-535 ◽  
Author(s):  
G. D. Towner

SummaryBatcombe series soils readily break down to good tilths, Beccles series soils form cloddy seed beds that are resistant to weathering, and Stackyard series soils form unstable tilths that readily break down. The soils differ in their particle-size distribution. The proposition that such differences contributed to the differences in field behaviour was examined by forming artificial soils, each of which was made up from particles of one of the soils, but redistributed with respect to size in the proportion in which they occurred in one of the other soils.As a measure of the relevant physical properties, breaking strengths and bulk densities of cylindrical ‘clods’ moulded from the artificial soils were determined. To aid interpretation of the observed soil properties, similar measurements were made on individual fractions, on various other mixtures and on the parent soils.The breaking strengths of the soils made up to a given particle-size distribution from particles from the different parent soils were reasonably close to each other, with those for the Beccles distribution being more variable. There was a significant difference between the two. The strength of the reconstituted Batcombe soil was markedly greater than that of its parent soil, whereas that for Beccles soil was markedly less. There was little difference for the Stackyard soil.The bulk densities of saturated soils reconstituted from all nine fractions could be estimated reasonably accurately from the properties of the separate components. The structure of each of these soils in the air-dry state was inferred from comparisons between measured and calculated bulk densities. The breaking strengths of air-dry reconstituted soils were estimated from the properties of the separate components, and agreed reasonably well with the measured values for soils in which the clay and fine silt fractions predominated.Whereas it was generally possible to predict various physical properties of the reconstituted soils from those of the separate fractions, it was not possible to extrapolate the results to explain field behaviour.


1976 ◽  
Vol 41 (4) ◽  
pp. 523-529 ◽  
Author(s):  
Daniel R. Boone ◽  
Harold M. Friedman

Reading and writing performance was observed in 30 adult aphasic patients to determine whether there was a significant difference when stimuli and manual responses were varied in the written form: cursive versus manuscript. Patients were asked to read aloud 10 words written cursively and 10 words written in manuscript form. They were then asked to write on dictation 10 word responses using cursive writing and 10 words using manuscript writing. Number of words correctly read, number of words correctly written, and number of letters correctly written in the proper sequence were tallied for both cursive and manuscript writing tasks for each patient. Results indicated no significant difference in correct response between cursive and manuscript writing style for these aphasic patients as a group; however, it was noted that individual patients varied widely in their success using one writing form over the other. It appeared that since neither writing form showed better facilitation of performance, the writing style used should be determined according to the individual patient’s own preference and best performance.


1993 ◽  
Vol 69 (01) ◽  
pp. 035-040 ◽  
Author(s):  
A M H P van den Besselaar ◽  
R M Bertina

SummaryFour thromboplastin reagents were tested by 18 laboratories in Europe, North-America, and Australasia, according to a detailed protocol. One thromboplastin was the International Reference Preparation for ox brain thromboplastin combined with adsorbed bovine plasma (coded OBT/79), and the second was a certified reference material for rabbit brain thromboplastin, plain (coded CRM 149R). The other two thromboplastin reagents were another rabbit plain brain thromboplastin (RP) with a lower ISI than CRM 149R and a rabbit brain thromboplastin combined with adsorbed bovine plasma (RC). Calibration of the latter two reagents was performed according to methods recommended by the World Health Organization (W. H. O.).The purpose of this study was to answer the following questions: 1) Is the calibration of the RC reagent more precise against the bovine/combined (OBT/79) than against the rabbit/plain reagent (CRM 149R)? 2) Is the precision of calibration influenced by the magnitude of the International Sensitivity Index (ISI)?The lowest inter-laboratory variation of ISI was observed in the calibration of the rabbit/plain reagent (RP) against the other rabbit/plain reagent (CRM 149R) (CV 1.6%). The highest interlaboratory variation was obtained in the calibration of rabbit/plain (RP) against bovine/combined (OBT/79) (CV 5.1%). In the calibration of the rabbit/combined (RC) reagent, there was no difference in precision between OBT/79 (CV 4.3%) and CRM 149R (CV 4.2%). Furthermore, there was no significant difference in the precision of the ISI of RC obtained with CRM 149R (ISI = 1.343) and the rabbit/plain (RP) reagent with ISI = 1.14. In conclusion, the calibration of RC could be performed with similar precision with either OBT/79 or CRM 149R, or RP.The mean ISI values calculated with OBT/79 and CRM 149R were practically identical, indicating that there is no bias in the ISI of these reference preparations and that these reference preparations have been stable since their original calibration studies in 1979 and 1987, respectively.International Normalized Ratio (INR) equivalents were calculated for a lyophilized control plasma derived from patients treated with oral anticoagulants. There were small but significant differences in the mean INR equivalents between the bovine and rabbit thromboplastins. There were no differences in the interlaboratory variation of the INR equivalents, when the four thromboplastins were compared.


1966 ◽  
Vol 53 (4) ◽  
pp. 673-680 ◽  
Author(s):  
Torsten Deckert ◽  
Kai R. Jorgensen

ABSTRACT The purpose of this study was to investigate whether a difference could be demonstrated between crystalline insulin extracted from normal human pancreas, and crystalline insulin extracted from bovine and porcine pancreas. Using Hales & Randle's (1963) immunoassay no immunological differences could be demonstrated between human and pig insulin. On the other hand, a significant difference was found, between pig and ox insulin. An attempt was also made to determine whether an immunological difference could be demonstrated between crystalline pig insulin and crystalline human insulin from non diabetic subjects on the one hand and endogenous, circulating insulin from normal subjects, obese subjects and diabetic subjects on the other. No such difference was found. From these experiments it is concluded that endogenous insulin in normal, obese and diabetic human sera is immunologically identical with human, crystalline insulin from non diabetic subjects and crystalline pig insulin.


2020 ◽  
Vol 17 (2) ◽  
pp. 172
Author(s):  
HARMAN AGUSAPUTRA ◽  
MARIA SUGENG ◽  
AYLY SOEKAMTO ◽  
ATIK WULANDARI

<p><strong>Abstract</strong></p><p><strong>Background:</strong> Hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) as antiseptic has been used frequently to clean woundsin in hospitals and clinics. Hydrogen peroxide has the effectof strong oxidative that can kill pathogens. It can clean up debris and necrotic tissuesin wounds. Hydrogen peroxidealso has hemostatic effect that can help to stop bleeding. Besides antiseptic effects, hydrogen peroxide i s suspected of having negative effect in wound healing. Hydrogen peroxide presumably could cause delayed wound healing by exudate formation and delayed epithelial growth.</p><p><strong>Method</strong>: This study was conducted in the laboratory using 48 white mice that were divided into 2 groups. All the mice were purposely wounded. Afterwards in one group the wounds were clean up using hydrogen peroxide, while in the other group without hydrogen peroxide as control. The wounds of both groups were observed on day 1, day 3 and day 7. On day 1 and day 3, both groups did not show significant difference.</p><p><strong>R</strong><strong>esult</strong> : on day 7 showed that the wound healing in hydrogen peroxide group were delayed. Fifty percent of them had the formation of exudate and 62.5% of them showed delayed epithelial growth.</p><p><strong>Conclusion </strong>: This study could show hydrogen peroxide as wound antiseptic has delayed wound healing effect.</p><p><strong>Keyword</strong>: hydrogen peroxide, wound healing</p>


2014 ◽  
Vol 4 (2) ◽  
pp. 55-64
Author(s):  
Amir Jayani ◽  
Zulman Efendi ◽  
Devi Silsia

This study aims to gain influence the thickness and concentration variations affect the characteristics of sago binder physical properties of catfish jerky. As well as getting influence the thickness and concentration variations affect the level of binder sago joy panelists in terms of organoleptic test. Data were analyzed by analysis of variance using the Analysis Of Variance (ANOVA). If there is a significant difference followed by a further test of DMRT 5% level (physical properties). While the hedonic test performed using Kruskal Wallis analysis. Results uniformity analysis (ANOVA) showed catfish fillet thickness and concentration of sago affect the physical properties of the water content and the level of violence. Where catfish jerky using sago binder 5% and 10% significantly different. The use of sago binder 5% and 10% led to an increase in water content. Besides the addition of the binder resulted in increasing levels of violence catfish jerky. Based on the statistics found that the influence of the thickness and concentration of the binder sago aroma, flavor and color of the sixth jerky catfish were not significantly different. But the texture was significantly different.


Alloy Digest ◽  
1960 ◽  
Vol 9 (7) ◽  

Abstract HAYNES STELLITE 98M2 Alloy is a cobalt-base alloy having higher compressive strength and higher hardness than all the other cobalt-base alloys at room temperature and in the red heat range. This datasheet provides information on composition, physical properties, hardness, elasticity, tensile properties, and compressive strength as well as fracture toughness. It also includes information on heat treating, machining, and joining. Filing Code: Co-22. Producer or source: Haynes Stellite Company.


2017 ◽  
Vol 05 (02) ◽  
pp. 084-089
Author(s):  
Alisha Dhingra ◽  
Ashu Gupta ◽  
Anshu Minocha ◽  
Nayantara Sen

Abstract Aim: The aim of this study was to compare the reversal of shear bond strength of composite to bleached enamel immediately after bleaching followed by application of various antioxidant solutions. Material and Methods: Seventy central incisors were divided into seven groups. Groups I and II served as unbleached and bleached controls respectively. Groups III, IV, V, VI and VII served as the experimental groups and were subjected to 37.5% hydrogen peroxide bleaching followed by 10 min application of 10% sodium ascorbate, 25% alpha-tocopherol, 6.5% grape seed extract, 5% lycopene and 5% green tea extract respectively. Following composite bonding, shear bond strength was determined and the results were analyzed using ANOVA followed by Post Hoc Multiple Comparisons test. Results: The bond strength values for Group I (positive control) were maximum and significantly different than all the other groups except Grape seed extract group (Group V). When compared to Group II (bleached control), all the groups showed significantly higher bond strength. Significant difference in the bond strength values were seen between Group III (10% sodium ascorbate) and Group V. Also values for Group V were significantly different from Group VI (5% lycopene). All the other values showed insignificantly different results. Conclusion: All the antioxidant solutions improved the shear bond strength values after bleaching but only Grape seed extract application reversed the values to the non bleached levels. Lycopene was least effective. Other antioxidants showed comparable results.


1985 ◽  
Vol 17 (2) ◽  
pp. 341-369 ◽  
Author(s):  
Philip J. Williams

The involvement of Christians in the Nicaraguan Revolution is a clear manifestation of the profound changes taking place within the Nicaraguan Church as a whole. While a clear majority of the clergy took a stand against the injustices of the Somoza regime, a smaller group of priests and religious demonstrated a more profound commitment to radical structural transformation of society. Although their efforts to organize andconcientizar1rural and urban poor had serious political implications – in fact, many joined the guerrilla as a result of the ‘radicalization of their faith’ – to these priests and religious the political solutions available to counter growing social injustices and government abuses were few: either fight or capitulate. The bishops, on the other hand, were cautious about the pace of change and rejected the violent option, choosing instead an intermediate path. Unfortunately, such an option proved futile in the case of Nicaragua, and finally the bishops justified armed revolution as a viable alternative to systematic repression.


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