Realizing 6.7 wt% reversible storage of hydrogen at ambient temperature with non-confined ultrafine magnesium hydrides

Non-confined MgH2 nanoparticles of 4–5 nm diameter enable reversible storage of hydrogen up to 6.7 wt% at 30 °C.

A high throughput dynamic method for characterizing thermodynamic properties of catalyzed magnesium hydrides by thermogravimetric analysis

An effective dynamic method using TGA to determine the reaction enthalpies of catalyzed MgH2.

Magnesium hydrides bearing sterically demanding amidinate ligands: synthesis, reactivity and catalytic application

The synthesis, characterisation and reactivity of a series of magnesium complexes bearing sterically demanding amidinate ligands is reported; this includes magneisum amides, hydrides and alkyl complexes.

Stereo-controlled anti-hydromagnesiation of aryl alkynes by magnesium hydrides

Anti-hydromagnesiation of aryl alkynes was facilitated solely by magnesium hydride. The resulting alkenylmagnesium intermediates were functionalized with various electrophiles to afford stereochemically defined tri-substituted alkenes.