A high throughput dynamic method for characterizing thermodynamic properties of catalyzed magnesium hydrides by thermogravimetric analysis

Author(s):  
Chengshang Zhou ◽  
Yunhe Gao ◽  
Robert C. Bowman ◽  
Jingxi Zhang ◽  
Huang Liu ◽  
...  

An effective dynamic method using TGA to determine the reaction enthalpies of catalyzed MgH2.

2011 ◽  
Vol 4 ◽  
pp. 15-22 ◽  
Author(s):  
Fabien Porcheron ◽  
Alexandre Gibert ◽  
Marc Jacquin ◽  
Pascal Mougin ◽  
Abdelaziz Faraj ◽  
...  

Polymers ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 1009 ◽  
Author(s):  
Jianxiao Lu ◽  
Chuanyue Sun ◽  
Kexin Yang ◽  
Kaili Wang ◽  
Yingyi Jiang ◽  
...  

Polylactic acid (PLA) is one of the most promising bio-based materials, but its inherent hydrophobicity limits its application. Although nanocellulose (NCC) is a desirable reinforcement for PLA, the poor interface compatibility between the two has been a challenge. In this work, hydroxyapatite (HAP) modified NCC was prepared, and the obtained NCC/HAP reinforcement was used to prepare PLA/NCC-HAP composites. Different ratios of NCC to HAP were studied to explore their effects on the mechanical and thermodynamic properties of the composites. When the ratio of NCC to HAP was 30/70, the tensile strength and tensile modulus of the composite film reached 45.6 MPa and 2.34 GPa, respectively. Thermogravimetric analysis results indicate that thermal stability of the composites was significantly improved compared with pure PLA, reaching 346.6 °C. The above revelations show that NCC/HAP significantly improved the interface compatibility with PLA matrix.


2002 ◽  
Vol 80 (5) ◽  
pp. 476-482 ◽  
Author(s):  
Urszula Domanska ◽  
Juan Antonio Gonzalez

Equilibrium temperatures for solid–liquid transitions of mixtures formed by sulfolane and ethanenitrile, propanenitrile, butanenitrile, or pentanenitrile were measured by a dynamic method. The solid–liquid equilibria phase diagrams show positive deviations from Raoult's law, except for the system with ethanenitrile, which is nearly ideal. The sulfolane–nitrile and sulfolane–1-alkyne interactions have been characterized in terms of the DISQUAC group contribution model. DISQUAC properly represents a complete set of thermodynamic properties: solid–liquid equilibria, molar excess enthalpies, and natural logarithms of activity coefficients. DISQUAC predictions are valid over a wide temperature range.Key words: solid–liquid equilibria, thermodynamics, mixtures, interactions.


1994 ◽  
Vol 4 (3) ◽  
pp. 103-104 ◽  
Author(s):  
Sergey B. Savvin ◽  
Albert S. Katchanov ◽  
Vladimir V. Kuznetsov ◽  
Alla V. Mikhailova

1979 ◽  
Vol 44 ◽  
pp. 349-355
Author(s):  
R.W. Milkey

The focus of discussion in Working Group 3 was on the Thermodynamic Properties as determined spectroscopically, including the observational techniques and the theoretical modeling of physical processes responsible for the emission spectrum. Recent advances in observational techniques and theoretical concepts make this discussion particularly timely. It is wise to remember that the determination of thermodynamic parameters is not an end in itself and that these are interesting chiefly for what they can tell us about the energetics and mass transport in prominences.


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