A Literature Review on Supramolecular Devices

Supramolecular device includes hydrogel and polymer manufactured by gelation or polymerization. Hydrogels are produced via chemical and physical gelation. Polymers are synthesized through photopolymerization, step-growth, and chain-growth polymerization. The supramolecular device possesses as the host to entrap the guest molecules via chemical, physical and physical-chemical microencapsulation. The present review article discusses the microencapsulation techniques, mechanism of gelation or polymerization, and different gelation or polymerization methods with given examples, such as gelatin, chitosan, and polyvinyl alcohol (PVA), and polyamide to act as the hosts for encapsulation.

Towards Building Blocks for Supramolecular Architectures Based on Azacryptates

In this work, we report the synthesis of a new bis(tris(2-aminoethyl)amine) azacryptand L with triphenyl spacers. The binding properties of its dicopper complex for aromatic dicarboxylate anions (as TBA salts) were investigated, with the aim to obtain potential building blocks for supramolecular structures like rotaxanes and pseudo-rotaxanes. As expected, UV-Vis and emission studies of [Cu2L]4+ in water/acetonitrile mixture (pH = 7) showed a high affinity for biphenyl-4,4′-dicarboxylate (dfc2−), with a binding constant of 5.46 log units, due to the best match of the anion bite with the Cu(II)-Cu(II) distance in the cage’s cavity. Compared to other similar bistren cages, the difference of the affinity of [Cu2L]4+ for the tested anions was not so pronounced: conformational changes of L seem to promote a good interaction with both long (e.g., dfc2−) and short anions (e.g., terephthalate). The good affinity of [Cu2L]4+ for these dicarboxylates, together with hydrophobic interactions within the cage’s cavity, may promote the self-assembly of a stable 1:1 complex in water mixture. These results represent a good starting point for the application of these molecular systems as building units for the design of new supramolecular architectures based on non-covalent interactions, which could be of interest in all fields related to supramolecular devices.

The eternal youth of azobenzene: new photoactive molecular and supramolecular devices

The development of multicomponent chemical systems that can perform predetermined functions under external control – i.e., molecular devices – is a challenging task in chemistry and a fascinating objective in the frame of a bottom-up approach to nanostructures. Photochromic units undergo profound changes in their chemical and/or electronic structure upon light excitation, and are highly interesting for the construction of photocontrollable molecular devices, machines and materials. The E–Z photoisomerization of azobenzene – owing to its high efficiency, excellent reversibility and significant physico-chemical differences between the two forms – is a highly useful reaction in this regard. Azobenzene photoisomerization has been known for almost 80 years and has been exploited to implement light-induced functionalities with a large variety of compounds, biomolecules, nanosystems and materials. Here we present some of our recent investigations highlighting how this outstanding photochrome can be utilized to develop (supra)molecular systems with valuable light-induced functionalities.