Chapter 12Electrochemically Driven Supramolecular Devices

2015 ◽  
pp. 453-500
Keyword(s):  
Supramolecular Devices

Functional Supramolecular Devices: [M4IIL4]8+ [2×2]-Grid-Type Complexes as Multilevel Molecular Electronic Species

2003 ◽  
Vol 9 (1) ◽  
pp. 291-299 ◽  
Author(s):  
Mario Ruben ◽  
Esther Breuning ◽  
Mihail Barboiu ◽  
Jean-Paul Gisselbrecht ◽  
Jean-Marie Lehn
Keyword(s):  
Molecular Electronic ◽  
Supramolecular Devices

scholarly journals Towards Building Blocks for Supramolecular Architectures Based on Azacryptates

Molecules ◽  
2020 ◽  
Vol 25 (7) ◽  
pp. 1733 ◽  
Author(s):  
Ana Miljkovic ◽  
Sonia La Cognata ◽  
Greta Bergamaschi ◽  
Mauro Freccero ◽  
Antonio Poggi ◽  
...  
Keyword(s):  
Conformational Changes ◽  
Self Assembly ◽  
Hydrophobic Interactions ◽  
Building Blocks ◽  
Water Mixture ◽  
Molecular Systems ◽  
Supramolecular Architectures ◽  
Starting Point ◽  
The Difference ◽  
Supramolecular Devices

In this work, we report the synthesis of a new bis(tris(2-aminoethyl)amine) azacryptand L with triphenyl spacers. The binding properties of its dicopper complex for aromatic dicarboxylate anions (as TBA salts) were investigated, with the aim to obtain potential building blocks for supramolecular structures like rotaxanes and pseudo-rotaxanes. As expected, UV-Vis and emission studies of [Cu2L]4+ in water/acetonitrile mixture (pH = 7) showed a high affinity for biphenyl-4,4′-dicarboxylate (dfc2−), with a binding constant of 5.46 log units, due to the best match of the anion bite with the Cu(II)-Cu(II) distance in the cage’s cavity. Compared to other similar bistren cages, the difference of the affinity of [Cu2L]4+ for the tested anions was not so pronounced: conformational changes of L seem to promote a good interaction with both long (e.g., dfc2−) and short anions (e.g., terephthalate). The good affinity of [Cu2L]4+ for these dicarboxylates, together with hydrophobic interactions within the cage’s cavity, may promote the self-assembly of a stable 1:1 complex in water mixture. These results represent a good starting point for the application of these molecular systems as building units for the design of new supramolecular architectures based on non-covalent interactions, which could be of interest in all fields related to supramolecular devices.

Guanosine and isoguanosine derivatives for supramolecular devices

2014 ◽  
Vol 38 (11) ◽  
pp. 5122-5128 ◽  
Author(s):  
Valentina Abet ◽  
Raphaël Rodriguez
Keyword(s):  
Supramolecular Devices

Guanosine (G) and isoguanosine (isoG) derivatives can self-assemble, yielding supramolecules that have found broad applications in diverse fields.

scholarly journals Enantioselective supramolecular devices in the gas phase. Resorcin[4]arene as a model system

2012 ◽  
Vol 8 ◽  
pp. 539-550 ◽  
Author(s):  
Caterina Fraschetti ◽  
Matthias C Letzel ◽  
Antonello Filippi ◽  
Maurizio Speranza ◽  
Jochen Mattay
Keyword(s):  
Gas Phase ◽  
Chiral Recognition ◽  
Experimental Approach ◽  
Biologically Active ◽  
Computational Techniques ◽  
Ligand Displacement ◽  
Artificial Receptor ◽  
Ion Molecule Complexes ◽  
Supramolecular Devices ◽  
Diastereomeric Complexes

This review describes the state-of-art in the field of the gas-phase reactivity of diastereomeric complexes formed between a chiral artificial receptor and a biologically active molecule. The presented experimental approach is a ligand-displacement reaction carried out in a nano ESI-FT-ICR instrument, supported by a thermodynamic MS-study and molecular-mechanics and molecular-dynamics (MM/MD) computational techniques. The noncovalent ion–molecule complexes are ideal for the study of chiral recognition in the absence of complicating solvent and counterion effects.

Multicomponent Supramolecular Devices: Synthesis, Optical, and Electronic Properties of Bridged Bis-dirhodium and -diruthenium Complexes

2006 ◽  
Vol 2006 (19) ◽  
pp. 3878-3892 ◽  
Author(s):  
Anne Petitjean ◽  
Fausto Puntoriero ◽  
Sebastiano Campagna ◽  
Alberto Juris ◽  
Jean-Marie Lehn
Keyword(s):  
Electronic Properties ◽  
Optical And Electronic Properties ◽  
Supramolecular Devices

scholarly journals Frontispiece: From Hierarchical Helicates to Functional Supramolecular Devices

2019 ◽  
Vol 25 (17) ◽  
Author(s):  
Markus Albrecht ◽  
Xiaofei Chen ◽  
David Van Craen
Keyword(s):  
Supramolecular Devices
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