Study on Ablation Characteristics of Femyosecond Laser Nanoscale Processing for Aluminum Nitride and LeadZirconate Titanate Ceramics

This paper analytically investigates an ultrashort pulsed laser nanoscale processing for aluminum nitride (AIN) and lead zirconate titanate (PZT) ceramics. Processing characteristics of an ultra-short pulsed laser is different from that of long-pulsed laser due to ultrahigh intensity, ultrahigh power, and ultrashort time. The ultrasmall processing for materials can achieved by an ultra-short pulsed laser. This study proposes a model to analyze an ultrashort pulsed laser nanoscale processing for aluminum nitride (AIN) and lead zirconate titanate (PZT) ceramics. The effects of optical penetration absorption and thermal diffusion on temperature are also discussed. The results reveal that the variation of ablation rate with laser fluences predicted by this work agrees with the available measured data for an ultrashort pulsed laser processing for AIN and PZT. For femtosecond lasers, the optical absorption and thermal diffusion, respectively, governs the ablated depth per pulse at the low and high laser fluences. The thermal diffusion length is small relative to the optical penetration depth for femtosecond laser. The optical penetration absorption governs the temperature in the workpiece. On the other hand, for the picosecond laser, the thermal diffusion length is large compared to the optical penetration depth. The thermal diffusion determines the temperature in the workpiece.

Photoinduced multistage phase transitions in Ta2NiSe5

Ultrafast control of material physical properties represents a rapidly developing field in condensed matter physics. Yet, accessing the long-lived photoinduced electronic states is still in its early stages, especially with respect to an insulator to metal phase transition. Here, by combining transport measurement with ultrashort photoexcitation and coherent phonon spectroscopy, we report on photoinduced multistage phase transitions in Ta2NiSe5. Upon excitation by weak pulse intensity, the system is triggered to a short-lived state accompanied by a structural change. Further increasing the excitation intensity beyond a threshold, a photoinduced steady new state is achieved where the resistivity drops by more than four orders at temperature 50 K. This new state is thermally stable up to at least 350 K and exhibits a lattice structure different from any of the thermally accessible equilibrium states. Transmission electron microscopy reveals an in-chain Ta atom displacement in the photoinduced new structure phase. We also found that nano-sheet samples with the thickness less than the optical penetration depth are required for attaining a complete transition.

Comparison of Volumetric to Surface Heating for Filament-Fed Laser Heated Additive Manufacturing of Glass

This paper presents work using a laser-heated fiber-fed technique to deposit fully dense glass. A stationary laser beam is focused on the intersection of a quartz filament with the workpiece. The workpiece is articulated on a precision 4-axis stage. The laser beam continuously melts the glass filament so that its viscosity is low enough to wet and fuse the workpiece. The focus of this paper is to compare volumetric heating of the glass as opposed to surface heat flux. CO2 laser radiation (λ = 10.6 µm) strongly couples to the silica phonon mode (optical penetration depth < 5 µm). This requires printing at very slow rates in order to allow the heat to diffuse from the surface of the glass to the interface of the filament and the workpiece. CO laser radiation (λ = 5.3 µm) provides volumetric absorption because of weaker coupling (optical penetration depth of ∼500 µm for fused quartz). This produces a more uniform temperature profile in the glass filament and supports deposition at greater speeds. The maximum deposition rates for 0.5 and 1.0 mm diameter fused quartz filaments are determined by extrapolating the power required to achieve wetting using both CO2 and CO lasers. The results show that volumetric heating (CO laser) produces surface wetting with significantly lower power. The results are compared to a 1D conduction model which suggests that still greater deposition speeds are possible as the optical penetration depth approaches the filament diameter.

Rational design of a junction structure to realize an NIR-selective narrowband organic thin-film photodiode

By systematically controlling the correlation between the optical penetration depth and junction depletion width, high-performance NIR-selective OPDs are demonstrated.