Effects of a Sodium Phosphate Electrolyte Additive on Elevated Temperature Performance of Spinel Lithium Manganese Oxide Cathodes

LiMn2O4 (LMO) spinel cathode materials suffer from severe degradation at elevated temperatures because of Mn dissolution. In this research, monobasic sodium phosphate (NaH2PO4, P2) is examined as an electrolyte additive to mitigate Mn dissolution; thus, the thermal stability of the LMO cathode material is improved. The P2 additive considerably improves the cyclability and storage performances of LMO/graphite and LMO/LMO symmetric cells at 60 °C. We explain that P2 suppresses the hydrofluoric acid content in the electrolyte and forms a protective cathode electrolyte interphase layer, which mitigates the Mn dissolution behavior of the LMO cathode material. Considering its beneficial role, the P2 additive is a useful additive for spinel LMO cathodes that suffer from severe Mn dissolution.

Phosphorus requirement for juvenile jundiá (Rhamdia quelen) on a semi-purified diet

The aim of the present study was to determine the total phosphorus requirement in the diet of jundiá fry (Rhamdia quelen) in a semi-purified diet. A quantitative experimental research was carried out, using dehydrated albumin as a protein source, with the supplementation of monobasic sodium phosphate at different levels: 0.04; 0.30; 0.47 and 0.70% of total phosphorus (P). 160 fish with an average weight of 1.20 ± 0.53g were used in an experimental or completely randomized design, with four treatments and four replications. The experiment lasted 33 days. To determine the phosphorus requirements for juveniles, body chemical composition, bone mineral composition and productive performance parameters were evaluated. The body chemical composition only the levels of protein did not present significant difference (p˃0.05). The levels of phosphorus, potassium and magnesium in the bones increased linearly, with increased levels of phosphorus in the diet. Based on weight gain and total length, the requirement for phosphorus for juveniles of jundiá (Rhamdia quelen) in a semipurified diet is between 0.53 - 0 5.8% of P-total.

Nodulation, Growth and Soybean Yield in Response to Seed Coating and Split Application of Phosphorus

Phosphorus is one of the most important nutrients for soybeans, but it presents a complex dynamic in the soil and can become unavailable. The split and localized application of this nutrient can be an effective approach to increase its availability. The aim of this study was to evaluate the effect of a split phosphorus dose applied to the soil and the seed coating with monobasic sodium phosphate on nodulation, growth and yield components of soybean cultivar BRS Valiosa RR. The experiment was conducted in a greenhouse in a completely randomized design in a 2x5x3 factorial arrangement, i.e., coating or not the seeds; five doses of phosphorus applied to the soil; and three times of splitting phosphate fertilizer. Phosphorus content in the index leaf (IL), dry matter of shoots, roots and nodules, yield components, and plant height were evaluated. There was an increase in nodulation and growth of plants with increased levels of phosphorus applied to the soil. In smaller doses, the seed coating and the splitting of phosphorus fertilizer increased nodulation, growth and yield components of plants. Thus, the splitting of the phosphorus dose, combined with seed coating, is indicated for increasing the yield components of soybean plants.

Determination of propranolol in plasma by radial compression liquid chromatography with fluorometric detection.

This radial compression liquid-chromatographic assay for propranolol in plasma is rapid, reproducible, and suitable for use in routine monitoring. A 10-micron particle, 8 mm X 10 cm CN cartridge is used in conjunction with a radial compression separation system. The mobile phase is monobasic sodium phosphate (pH 3) solution/methanol/acetonitrile (760/84/156 by vol), the flow rate 6 mL/min. Propranolol was detected by use of a spectrofluorometer equipped with a 20-microL flow-through cell, at excitation and emission wavelengths of 250 and 336 nm. The retention times for propranolol and metoprolol (the internal standard) are 3.13 and 1.42 min, respectively. A one-step extraction with chloroform yields "clean" chromatograms, with greater than 90% of the drug being analytically accounted for. Under these conditions, results are precise and accurate. Currently we are using this method to monitor propranolol in hypertensive neonates. Data on changes in the concentrations of propranolol in plasma with time are presented for one such patient.

Taste responses of calves to various concentrations of different salts

SUMMARYExperiments were conducted to observe the taste responses of male and female calves to various levels of sodium salts, chloride solutions, and trace minerals. Animals were penned individually and given a completely pelleted ration ad libitum. Trace mineralized salt was freely available.Using water as a basis for determination, a non-discrimination zone was established. This zone represented an intake ranging from 63 to 37%. Preference threshold was set at 80% of intake, while the rejection threshold was set at 20% of intake. Responses were determined by expressing the intake of the test solution as a percentage of the total intake during the test period. Responses at a given chemical concentration were measured during two 8-hr periods.Taste response observations were made on the following: 0·02, 0·08, 0·32 or 1·25% sodium chloride (NaCl), sodium sulphate (Na2SO4), sodium bicarbonate (NaHCO3), sodium carbonate, monobasic sodium phosphate (NaH2PO4), dibasic sodium phosphate (Na2HPO4), ammonium chloride, potassium chloride, calcium chloride, magnesium chloride, and manganese chloride. In addition, observations were made when 0·02, 0·08, 0·32 or 1·25% NaHCO3, Na2SO4, or Na2HPO4 were offered in opposition to equal concentrations of NaCl. The responses to 5, 10, 20, 40 and 60 p.p.m. concentrations of cupric chloride, zinc chloride, molybdenum trioxide and cobaltous chloride were observed also.