Prediction of Reformed Gas Composition for Diesel Engines with a Reformed EGR System Using an Artificial Neural Network

Facing the reinforced emission regulations and moving toward a clean powertrain, hydrogen has become one of the alternative fuels for the internal combustion engine. In this study, the prediction methodology of hydrogen yield by on-board fuel reforming under a diesel engine is introduced. An engine dynamometer test was performed, resulting in reduced particulate matter (PM) and NOx emission with an on-board reformer. Based on test results, the reformed gas production rate from the on-board reformer was trained and predicted using an artificial neural network with a backpropagation process at various operating conditions. Additional test points were used to verify predicted results, and sensitivity analysis was performed to obtain dominant parameters. As a result, the temperature at the reformer outlet and oxygen concentration is the most dominant parameters to predict reformed gas owing to auto-thermal reforming driven by partial oxidation reforming process, dominantly.

Hydrogen Production by Partial Oxidation Reforming of Methane over Ni Catalysts Supported on High and Low Surface Area Alumina and Zirconia

The catalytic activity of the partial oxidation reforming reaction for hydrogen production over 10% Ni supported on high and low surface area alumina and zirconia was investigated. The reforming reactions, under atmospheric pressure, were performed with a feed molar ratio of CH4/O2 = 2.0. The reaction temperature was set to 450–650 °C. The catalytic activity, stability, and carbon formation were determined via TGA, TPO, Raman, and H2 yield. The catalysts were calcined at 600 and 800 °C. The catalysts were prepared via the wet-impregnation method. Various characterizations were conducted using BET, XRD, TPR, TGA, TPD, TPO, and Raman. The highest methane conversion (90%) and hydrogen yield (72%) were obtained at a 650 °C reaction temperature using Ni-Al-H-600, which also showed the highest stability for the ranges of the reaction temperatures investigated. Indeed, the time-on-stream for 7 h of the Ni-Al-H-600 catalyst displayed high activity and a stable profile when the reaction temperature was set to 650 °C.

Solid oxide fuel cells power unit reformer/burner/heat-exchanger module experimental study

The article contains the installation description, experimental procedure, and results for the catalytic partial oxidation reformer/catalyst burner/heat-exchanger module. Mathematical modeling for all major blocks temperatures dependence on the reformer air supply ratio was carried out. In the air supply ratio range under study the model was verified using experimental data. The model was further practically used for the solid oxide fuel cells power unit automatic control modes development. The partial oxidation reforming solid oxide fuel cells power unit characteristics were evaluated.