Impact of Emerging Agricultural Contaminants on Global Warming

There are many definitions of emerging contaminants (ECs). They are not usually new chemicals and could be substances that have stayed long in the environment with their presence and importance being recognized now. They may be chemicals or microorganisms which are not usually monitored in the environment but with known or suspected potential to cause ecological damage or adverse human effects. Some natural products and those transformed through biochemical processes from synthetic chemicals may be formed in the environment as ECs. Emerging Agricultural Contaminants are released to the environment or enter indirectly to the soil during the application of manure, fertilizers, biosolids or other solid waste materials. Once they enter the soil, they may be transported by leaching, runoff and drainage processes to water bodies. The extent of the transport is dependent on the persistence of the EC and on how it interacts with soil and air. These ECs contribute to global warming through the emissions of Greenhouse gases. The largest source of GHG emission from Agriculture is Nitrous oxide (N2O) and it accounts for 38% of the total global emission through the process of nitrification and denitrification, anthropogenic activities (use of nitrogen fertilizer, production of nitrogen-fixing crops and forages, retention of crop residues, application of managed livestock manure) which are either through direct additions and/or through indirect additions (atmospheric deposition of applied nitrogen). The natural digestive processes in ruminants otherwise known as enteric fermentation account for the key source of methane production under livestock production hence the second largest source of total agricultural emission with 34% global share and rice cultivation being the third with 11%. The three important greenhouse gases (Methane, Carbon dioxide and Nitrous oxide) are not harmful in naturally occurring quantities for their atmospheric presence helps in sustaining life on the planet when they trap heat energy near the surface of the earth. Concentration of greenhouse gases from both the natural and human factors have been increasing and contributing to Global Warming and Climate Change. Increase in greenhouse gases may cause tremendous changes to our civilization positively or negatively but the total impact is uncertain. Climate change comes as a result of a warming planet which can affect the weather adversely in many ways. So, as climate changes, extreme weather activities release severe threats on human society. Indicators of global warming include sea surface temperature, temperature over land, snow cover on hills, temperature over land and humidity. It is expected that climate change may cause more floods, storms, droughts, heatwaves and other extreme weathers activities. IPCC estimated that temp may rise from 2 to 6°C within 2021. Mitigation of greenhouse effect could be achieved through Biochemical methods on enteric fermentation, development of good environmental policies even Methanotrophs also aid in recycling the atmospheric Methane.

Recombinant Expression of Metal-Binding Proteins (Bacterioferritin, MBP, Metallothionein, and OprF) and Pesticide-Binding Proteins (LC-Cutinase and OpdA) in Escherichia coli for Detection of Agricultural Contaminants

We consume fruits and vegetables every day without knowing whether or not agricultural residues (i.e. pesticides & heavy metals) are present on them. Current methods of agricultural residue detection are not easily accessible to the public and are inconvenient for everyday use. Thus, we want to develop a convenient visualization of agricultural residues by designing metal-binding and pesticide-binding proteins along with colored proteins that can directly interact with these residues. We worked with metal-binding proteins including Bacterioferritin, MBP, Metallothionein, and OprF. We also utilized pesticide-binding proteins LC Cutinase and OpdA. In this paper, we envision a system in which our residue-binding proteins are fused with chromoproteins to allow for the visible detection of agricultural residues on produce. Our final product can be used by consumers, distributors and farmers alike.

Confirmation of aflatoxin in fish and shrimp by LC/MS-MS (ZEVO TQD)

Mycotoxins are agricultural contaminants of fungal origin occurring at all latitudes worldwide and being characterized by acute and chronic effects on human health and animal wellness, depending on the species sensitivity. Various types of crops like maize, wheat, soybeans etc are used as raw materials for preparing feed of fish and shrimp. They are particularly susceptible to infection by Aspergillus following prolonged exposure to a high humidity environment. For this reason, the fish and shrimp samples should be tested for identifying and quantifying mycotoxin. The major mycotoxins of food concern are aflatoxin (B1, B2, G1, G2) for its toxicity. This paper focus on the confirmation of aflatoxin in fish and shrimp by developing method and validated it by LC/MS-MS (ZEVO TQD) which is important for ensuring the safety of fishery product for human consumption. The monitored MRM transitions for B1, B2, G1, G2 were m/z 31357 and m/z 31371, m/z 31888 and m/z 318256, m/z 328.75242.99 and m/z 328.75199.9, m/z 330.3488 and m/z 330.34106 respectively. Limit of decision (CCα) for B1, B2, G1, G2 were 0.59 μg/kg, 0.70 μg/kg, 0.68 μg/kg, 0.83 μg/kg respectively and detection capability (CCβ) for B1, B2, G1, G2 were 1.01μg/kg, 1.19 μg/kg, 1.15 μg/kg, 1.40 μg/kg respectively. Asian Australas. J. Food Saf. Secur. 2020, 4 (1), 14-21

Remediation of Soils Contaminated by Pesticides Using Physicochemical Processes: a Brief Review

ABSTRACT: After years of pesticide application, often indiscriminately, damage has been caused to the environment, as well as to agronomic crops grown in contaminated areas. In water treatment, techniques based on physical and/or physicochemical processes are used, being formed secondary oxidizing agents responsible for the mineralization of contaminants present in the herbicides, thus causing the degradation process. However, few studies have demonstrated the effectiveness of these techniques in soils. The aim of this study was to review the existing studies, presenting the main techniques used for remediation of soils contaminated with pesticides. Emphasis was placed on electrokinetics, advanced oxidative processes, soil washing, chemical or solvent extraction, and combinations of these methods. According to the results of several studies, the combination of techniques, such as electrokinetics and soil washing processes, allows achieving a high efficiency when it is applied for the degradation of agricultural contaminants. The combination of electrolysis with other methods, such as the Fenton’s reagent, ultrasound irradiation, and UV light, also present satisfactory results in removing pesticides in soil treatment. However, Fenton technology used alone is the most promising of the assessed techniques since it can be used for the remediation of several contaminants, especially pesticides, not harming the environment and allowing soil recovery.

Impact of iron and manganese nano-metal-oxides on contaminant interaction and fortification potential in agricultural systems – a review

Environmental contextNanominerals are more reactive than bulk minerals, a property that strongly influences the fate of nutrients and contaminants in soils and plants. This review discusses applications of Fe- and Mn-nano-oxides in agricultural systems and their potential to be used as fertiliser and contaminant adsorbents, while addressing potential phytotoxicity. We discuss areas where significant advances are needed, and provide a framework for future work. AbstractRising population growth and increase global food demand have made meeting the demands of food production and security a major challenge worldwide. Nanotechnology is starting to become a viable remediation strategy of interest in farming. Ultimately, it may be used as a sustainability tool in agricultural systems. In these roles, it could be used to increase the efficiency of techniques such as food monitoring, pathogen control, water treatment and targeted delivery of agrochemicals. In addition to these uses, nanoparticles, particularly nano-metal-oxides (NMOs), have been engineered to act as contaminant scavengers and could be applied to a wide range of systems. Numerous studies have investigated the scavenging ability of NMOs, but few have investigated them in this role in the context of agricultural and food systems. Within these systems, however, research has demonstrated the potential of NMOs to increase crop health and yield but few have studied using NMOs as sources of key micronutrients, such as Fe and Mn. In this review, we address previous research that has used Fe- and Mn-NMOs in agricultural systems, particularly the worldwide crop production of the four major staple foods – rice, wheat, maize and soybeans – highlighting their application as fertilisers and sorbents. Fe- and Mn-NMOs are strong candidates for immobilisation of agricultural contaminants in soils and, because they are naturally ubiquitous, they have the potential to be a cost-effective and sustainable technology compared with other remediation strategies.