scholarly journals An in situ method for characterizing the kinetics of the oxidation process of copper thin films via sheet resistance

2007 ◽  
Vol 56 (11) ◽  
pp. 6722
Author(s):  
Luo Yu-Feng ◽  
Zhong Cheng ◽  
Zhang Li ◽  
Yan Xue-Jian ◽  
Li Jin ◽  
...  
Keyword(s):  
Thin Films ◽  
Sheet Resistance ◽  
Oxidation Process ◽  
In Situ Method ◽  
Kinetics Of

Kinetics of Ion-Exchange Reactions in Hybrid Organic–Inorganic Perovskite Thin Films Studied by In Situ Real-Time X-ray Scattering

2018 ◽  
Vol 9 (23) ◽  
pp. 6750-6754 ◽  
Author(s):  
Alessandro Greco ◽  
Alexander Hinderhofer ◽  
M. Ibrahim Dar ◽  
Neha Arora ◽  
Jan Hagenlocher ◽  
...  
Keyword(s):  
Thin Films ◽  
Ion Exchange ◽  
Real Time ◽  
Exchange Reactions ◽  
Inorganic Perovskite ◽  
X Ray ◽  
X Ray Scattering ◽  
Kinetics Of ◽  
Kinetics Of Ion Exchange

Using diffusive gradients in thin films to probe the kinetics of metal interaction with algal exudates

2011 ◽  
Vol 8 (5) ◽  
pp. 517 ◽  
Author(s):  
Jacqueline Levy ◽  
Hao Zhang ◽  
William Davison ◽  
Rene Groben
Keyword(s):  
Thin Films ◽  
Organic Matter ◽  
Organic Carbon ◽  
Dissolved Organic Matter ◽  
Chlorella Vulgaris ◽  
Metal Speciation ◽  
The Relationship ◽  
Diffusive Gradients ◽  
Kinetics Of

Environmental context Interaction of metals with dissolved organic matter is one of the key processes defining metal bioavailability in water. The technique of diffusive gradients in thin films was used to investigate the kinetics of the interaction between metals and dissolved organic matter released by algae. For most metals the rate at which they were released from the organic matter was fast, but release of iron was kinetically limited. AbstractThe interaction of metals with organic matter is one of the key processes determining metal speciation and bioavailability in water. Fulvic acid tends to dominate dissolved organic carbon (DOC) in freshwaters, but organic carbon produced in situ, e.g. exudates released by algae and bacteria, is also significant. The technique of diffusive gradients in thin films (DGT) was used to investigate the lability of metal–exudate complexes using a kinetic signature approach. Exudates were harvested from three cultured freshwater alga (Chlorella vulgaris, Cryptomonas pyrenoidifera, Anabaena flos-aquae) and the filtered media supplemented with trace metals. DGT-labile metal concentrations and kinetic signatures were determined (24-h deployment). The relationship between Fe and DOC was a defining feature of the kinetic signatures. Iron was the most kinetically limited metal followed by Al and Cu, whereas Co, Ni and Pb were effectively completely labile. Exudates from Chlorella vulgaris produced the most DOC and the most marked kinetic limitation.

Oxidation Kinetics of Yba2Cu3OT7-x Thin Films in the Presence of Atomic Oxygen and Molecular Oxygen by In-Situ Resistivity Measurement

1991 ◽  
Vol 230 ◽  
Author(s):  
K. Yamamoto ◽  
B. M. Lairson ◽  
J. C. Bravman ◽  
T. H. Geballe
Keyword(s):  
Thin Films ◽  
Molecular Oxygen ◽  
Atomic Oxygen ◽  
Resistivity Measurement ◽  
Oxygen Stoichiometry ◽  
Ambient Conditions ◽  
Kinetics Of Oxidation ◽  
Thermally Activated ◽  
Kinetics Of

AbstractThe kinetics of oxidation in Yba2Cu3O7-x thin films in the presence of molecular and atomic oxygen ambients have been studied. The resistivity of c-axis, a-axis, and mixed a+c axis oriented films, deposited in-situ by off-axis magnetron sputtering, was measured as a function of time subsequent to a change in the ambient conditions. The oxidation process is shown to be thermally activated and can be characterized by a diffusion model with an activation energy which varies from approximately 1.2eV in the presence of molecular oxygen to 0.6eV for a flux of 2×1015 oxygen atoms/cm2sec. In both cases, diffusivity is found to be insensitive to oxygen stoichiometry, but the rate of oxidation is found to be sensitive to the microstructure and orientation of the films.

In Situ Method for Measuring the Mechanical Properties of Nafion Thin Films during Hydration Cycles

2015 ◽  
Vol 7 (32) ◽  
pp. 17874-17883 ◽  
Author(s):  
Kirt A. Page ◽  
Jae Wook Shin ◽  
Scott A. Eastman ◽  
Brandon W. Rowe ◽  
Sangcheol Kim ◽  
...  
Keyword(s):  
Thin Films ◽  
Mechanical Properties ◽  
In Situ Method

Spectra Library: An Assumption-Free In Situ Method to Access the Kinetics of Catechols Binding to Colloidal ZnO Quantum Dots

2015 ◽  
Vol 128 (3) ◽  
pp. 944-947 ◽  
Author(s):  
Wei Lin ◽  
Michael Haderlein ◽  
Johannes Walter ◽  
Wolfgang Peukert ◽  
Doris Segets
Keyword(s):  
Quantum Dots ◽  
In Situ Method ◽  
Zno Quantum Dots ◽  
Kinetics Of

An in situ method on kinetics of gas hydrates

2019 ◽  
Vol 90 (3) ◽  
pp. 035111 ◽  
Author(s):  
Ali Masoudi ◽  
Parham Jafari ◽  
Masoumeh Nazari ◽  
Varun Kashyap ◽  
Bahareh Eslami ◽  
...  
Keyword(s):  
Gas Hydrates ◽  
In Situ Method ◽  
Kinetics Of

scholarly journals In Situ Method Correlating Raman Vibrational Characteristics to Chemical Expansion via Oxygen Nonstoichiometry of Perovskite Thin Films

2019 ◽  
Vol 31 (33) ◽  
pp. 1902493 ◽  
Author(s):  
Eva Sediva ◽  
Thomas Defferriere ◽  
Nicola H. Perry ◽  
Harry L. Tuller ◽  
Jennifer L. M. Rupp
Keyword(s):  
Thin Films ◽  
Oxygen Nonstoichiometry ◽  
Chemical Expansion ◽  
In Situ Method ◽  
Vibrational Characteristics

Spectra Library: An Assumption-Free In Situ Method to Access the Kinetics of Catechols Binding to Colloidal ZnO Quantum Dots

2015 ◽  
Vol 55 (3) ◽  
pp. 932-935 ◽  
Author(s):  
Wei Lin ◽  
Michael Haderlein ◽  
Johannes Walter ◽  
Wolfgang Peukert ◽  
Doris Segets
Keyword(s):  
Quantum Dots ◽  
In Situ Method ◽  
Zno Quantum Dots ◽  
Kinetics Of
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