Specific Solvent Effects in Swollen Polymer Networks

1974 ◽  
Vol 47 (5) ◽  
pp. 1151-1159 ◽  
Author(s):  
C. U. Yu ◽  
J. E. Mark
Keyword(s):  
Solvent Effects ◽  
Volume Fraction ◽  
Polymer Networks ◽  
Low Molecular Weight ◽  
Constant Composition ◽  
Stress Strain ◽  
Unperturbed Dimensions ◽  
Cohesive Energy Density ◽  
Octyl Acetate ◽  
Good Agreement

Abstract Stress—strain isotherms at 25° have been determined for uniaxially elongated poly(dimethylsiloxane) networks in the unswollen state and swollen consecutively with each of the following very dissimilar diluents : low molecular weight dimethylsiloxane fluid, n-hexadecane, 2,4-dichlorotoluene, and n-octyl acetate Five constant composition experiments were carried out, at values of the volume fraction ν2 of polymer of 1.00, 0.80, 0.60, 0.50, and 0.35. At ν2=0.80, the stress—strain isotherms were found to be independent of the nature of the diluent; at lower values of ν2, however, these isotherms were significantly different, thus demonstrating the existence of a “specific solvent effect” in swollen polymer networks. Interpretation of these data in terms of the statistical theory of rubberlike elasticity gave results in good agreement with previously reported specific solvent effects on the unperturbed dimensions of uncrosslinked poly (dimethylsiloxane) chains in solution. In neither case, however, do these effects correlate well with the cohesive energy density or dielectric of the diluent or solvent medium.

Stress-Strain Isotherms and Stress-Temperature Coefficients of Poly(Dimethylsiloxane) Networks in Compression

1975 ◽  
Vol 48 (2) ◽  
pp. 176-185 ◽  
Author(s):  
R. Y. S. Chen ◽  
C. U. Yu ◽  
J. E. Mark
Keyword(s):  
Statistical Theory ◽  
Temperature Coefficient ◽  
Polymer Networks ◽  
Temperature Measurements ◽  
Stress Strain ◽  
Unperturbed Dimensions ◽  
Temperature Coefficients ◽  
A Value ◽  
Good Agreement

Abstract Stress-strain isotherms at 30, 45, 60, 75, and 90°C have been determined for compressed, unswollen poly(dimethylsiloxane) networks which had been prepared either in the undiluted state or in solution. For these networks in compression, deviations of the dependence of stress on strain from that predicted by the statistical theory of rubberlike elasticity are much less than is the case for polymer networks in elongation. The present data nonetheless give a value for the temperature coefficient of the unperturbed dimensions of the network chains which is in good agreement with published results on networks of poly(dimethylsiloxane) in elongation. This agreement thus seems to validate the intentional disregard of such deviations in analyses of stress-temperature measurements.

scholarly journals Heat Treatment Evaluation for the Camshafts Production of ADI Low Alloyed with Vanadium

Metals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1036
Author(s):  
Eduardo Colin García ◽  
Alejandro Cruz Ramírez ◽  
Guillermo Reyes Castellanos ◽  
José Federico Chávez Alcalá ◽  
Jaime Téllez Ramírez ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Heat Treatment ◽  
Tensile Strength ◽  
Ductile Iron ◽  
Volume Fraction ◽  
Energy Impact ◽  
Treatment Conditions ◽  
Mold Casting ◽  
Grade 3 ◽  
Good Agreement

Ductile iron camshafts low alloyed with 0.2 and 0.3 wt % vanadium were produced by one of the largest manufacturers of the ductile iron camshafts in México “ARBOMEX S.A de C.V” by a phenolic urethane no-bake sand mold casting method. During functioning, camshafts are subject to bending and torsional stresses, and the lobe surfaces are highly loaded. Thus, high toughness and wear resistance are essential for this component. In this work, two austempering ductile iron heat treatments were evaluated to increase the mechanical properties of tensile strength, hardness, and toughness of the ductile iron camshaft low alloyed with vanadium. The austempering process was held at 265 and 305 °C and austempering times of 30, 60, 90, and 120 min. The volume fraction of high-carbon austenite was determined for the heat treatment conditions by XRD measurements. The ausferritic matrix was determined in 90 min for both austempering temperatures, having a good agreement with the microstructural and hardness evolution as the austempering time increased. The mechanical properties of tensile strength, hardness, and toughness were evaluated from samples obtained from the camshaft and the standard Keel block. The highest mechanical properties were obtained for the austempering heat treatment of 265 °C for 90 min for the ADI containing 0.3 wt % V. The tensile and yield strength were 1200 and 1051 MPa, respectively, while the hardness and the energy impact values were of 47 HRC and 26 J; these values are in the range expected for an ADI grade 3.

scholarly journals Predictive Computational Model for Damage Behavior of Metal-Matrix Composites Emphasizing the Effect of Particle Size and Volume Fraction

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2143
Author(s):  
Shaimaa I. Gad ◽  
Mohamed A. Attia ◽  
Mohamed A. Hassan ◽  
Ahmed G. El-Shafei
Keyword(s):  
Finite Element ◽  
Metal Matrix Composites ◽  
Metal Matrix ◽  
Volume Fraction ◽  
Particulate Composites ◽  
Aluminum Matrix Composites ◽  
Matrix Composites ◽  
Zone Method ◽  
Stress Strain ◽  
The Matrix

In this paper, an integrated numerical model is proposed to investigate the effects of particulate size and volume fraction on the deformation, damage, and failure behaviors of particulate-reinforced metal matrix composites (PRMMCs). In the framework of a random microstructure-based finite element modelling, the plastic deformation and ductile cracking of the matrix are, respectively, modelled using Johnson–Cook constitutive relation and Johnson–Cook ductile fracture model. The matrix-particle interface decohesion is simulated by employing the surface-based-cohesive zone method, while the particulate fracture is manipulated by the elastic–brittle cracking model, in which the damage evolution criterion depends on the fracture energy cracking criterion. A 2D nonlinear finite element model was developed using ABAQUS/Explicit commercial program for modelling and analyzing damage mechanisms of silicon carbide reinforced aluminum matrix composites. The predicted results have shown a good agreement with the experimental data in the forms of true stress–strain curves and failure shape. Unlike the existing models, the influence of the volume fraction and size of SiC particles on the deformation, damage mechanism, failure consequences, and stress–strain curve of A359/SiC particulate composites is investigated accounting for the different possible modes of failure simultaneously.

A New Look at Measurements of Network Density

1986 ◽  
Vol 59 (1) ◽  
pp. 138-141 ◽  
Author(s):  
Robert A. Hayes
Keyword(s):  
Hysteresis Loop ◽  
Interaction Parameters ◽  
Network Density ◽  
Stress Strain ◽  
Solvent Interaction ◽  
Solvent Method ◽  
Strain Data ◽  
Good Agreement ◽  
Polymer Solvent ◽  
New Look

Abstract A two-solvent method for determining the polymer-solvent interaction parameters independently of stress-strain data is described. The values obtained are much lower than those reported previously. Network densities calculated from swelling data and these interaction parameters are in good agreement with those calculated from the return portion of a hysteresis loop at high elongations.

Estimation of Interlayer Thickness in Inorganic Particulate-Filled Polymer Composites

2011 ◽  
Vol 24 (6) ◽  
pp. 777-788 ◽  
Author(s):  
J.Z. Liang
Keyword(s):  
Polymer Composites ◽  
Volume Fraction ◽  
Particle Diameter ◽  
Interfacial Structure ◽  
Interlayer Thickness ◽  
Filled Polymer ◽  
Mechanical And Physical Properties ◽  
The Relationship ◽  
Good Agreement

The structure of the interlayer between matrix and inclusions affect directly the mechanical and physical properties of inorganic particulate-filled polymer composites. The interlayer thickness is an important parameter for characterization of the interfacial structure. The effects of the interlayer between the filler particles and matrix on the mechanical properties of polymer composites were analyzed in this article. On the basis of a simplified model of interlayer, an expression for estimating the interlayer thickness ([Formula: see text]) was proposed. In addition, the relationship between the [Formula: see text] and the particle size and its concentration was discussed. The results showed that the calculations of the [Formula: see text] and thickness/particle diameter ratio ([Formula: see text]) increased nonlinearly with an increase of the volume fraction of the inclusions. Moreover, the predictions of [Formula: see text] and the relevant data reported in literature were compared, and good agreement was found between them.

Study on Dynamic Recrystallization Behavior in Deformed Austenite of 52100 Steel by Using JMAK-Model

2013 ◽  
Vol 275-277 ◽  
pp. 1833-1837
Author(s):  
Ke Lu Wang ◽  
Shi Qiang Lu ◽  
Xin Li ◽  
Xian Juan Dong
Keyword(s):  
Grain Size ◽  
Dynamic Recrystallization ◽  
Hot Deformation ◽  
Volume Fraction ◽  
True Strain ◽  
Strain And Strain Rate ◽  
Average Grain Size ◽  
Dynamic Recrystallization Behavior ◽  
Simulation And Experiment ◽  
Good Agreement

A Johnson-Mehl-Avrami-Kolmogorov (JMAK)-model was established for dynamic recrystallization in hot deformation process of 52100 steel. The effects of hot deformation temperature, true strain and strain rate on the microstructural evolution of the steel were physically studied by using Gleeble-1500 thermo-mechanical simulator and the experimental results were used for validation of the JMAK-model. Through simulation and experiment, it is found that the predicted results of DRX volume fraction, DRX grain size and average grain size are in good agreement with the experimental ones.

The Estimation of Thermal Conductivity for Alumina-Epoxy Composite Material with High Filling Volume Fraction

2014 ◽  
Vol 918 ◽  
pp. 21-26
Author(s):  
Chen Kang Huang ◽  
Yun Ching Leong
Keyword(s):  
Thermal Conductivity ◽  
Composite Material ◽  
Composite Materials ◽  
Physical Model ◽  
Electron Scattering ◽  
Volume Fraction ◽  
Epoxy Composite ◽  
The Matrix ◽  
Transport Theorem ◽  
Good Agreement

In this study, the transport theorem of phonons and electrons is utilized to create a model to predict the thermal conductivity of composite materials. By observing or assuming the dopant displacement in the matrix, a physical model between dopant and matrix can be built, and the composite material can be divided into several regions. In each region, the phonon or electron scattering caused by boundaries, impurities, or U-processes was taken into account to calculate the thermal conductivity. The model is then used to predict the composite thermal conductivity for several composite materials. It shows a pretty good agreement with previous studies in literatures. Based on the model, some discussions about dopant size and volume fraction are also made.

scholarly journals CuO–Water Nanofluid Magnetohydrodynamic Natural Convection inside a Sinusoidal Annulus in Presence of Melting Heat Transfer

2017 ◽  
Vol 2017 ◽  
pp. 1-9 ◽  
Author(s):  
M. Sheikholeslami ◽  
R. Ellahi ◽  
C. Fetecau
Keyword(s):  
Magnetic Field ◽  
Heat Transfer ◽  
Natural Convection ◽  
Hartmann Number ◽  
Volume Fraction ◽  
Melting Heat ◽  
Melting Heat Transfer ◽  
Limiting Case ◽  
Good Agreement ◽  
Melting Parameter

Impact of nanofluid natural convection due to magnetic field in existence of melting heat transfer is simulated using CVFEM in this research. KKL model is taken into account to obtain properties of CuO–H2O nanofluid. Roles of melting parameter (δ), CuO–H2O volume fraction (ϕ), Hartmann number (Ha), and Rayleigh (Ra) number are depicted in outputs. Results depict that temperature gradient improves with rise of Rayleigh number and melting parameter. Nusselt number detracts with rise of Ha. At the end, a comparison as a limiting case of the considered problem with the existing studies is made and found in good agreement.

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