Particulate Reinforcement of Polyacrylate Elastomers. III. Swelling Measurements
Abstract This paper presents and discusses results which have been obtained for the swelling in chlorobenzene of crosslinked poly (ethyl acrylates) containing various amounts of microscopic glass beads. The adhesion between the glass beads and the elastomer matrix was varied by subjecting the beads to different surface treatments. The swelling behavior has been found to correlate very closely with the extent of adhesion as judged by peel force measurements and tensile stress-strain properties reported previously. In the case of beads showing pronounced adhesion to the matrix, restrictions on swelling have been interpreted in terms of an apparent enhancement of crosslink density by the reactive beads.