Rheological Properties of Rubber-Carbon Black and Carbon Black-Oil Compounds Including Measurements at Very Low Shear Stresses

1995 ◽  
Vol 68 (1) ◽  
pp. 50-58 ◽  
Author(s):  
Gabriel J. Osanaiye ◽  
Arkadii I. Leonov ◽  
James L. White
Keyword(s):  
Carbon Black ◽  
Rheological Properties ◽  
Yield Stress ◽  
Rubber Matrix ◽  
Shear Stresses ◽  
Shear Rates ◽  
Ternary Compounds ◽  
Black Oil ◽  
Critical Yield ◽  
Capillary Extrusion

Abstract The rheological properties of binary rubber-carbon black compounds at compositions 5, 20, 30, 40 and 50 volume percent carbon black have been investigated as well as ternary compounds with rubber/carbon black/oil compositions of 70/20/10, 60/20/20 and 50/20/30, respectively. The compounds were investigated using (1) a constant stress creep instrument at very low rates of deformation, (2) a rotational rheometer at intermediate shear rates and (3) a capillary extrusion instrument at higher shear rates. In experiment (1), it was found that below a critical yield stress, the strain becomes saturated and finite. Above this stress the strain becomes unbounded and the compound maintained a steady shear flow. This observation was made for all compounds investigated. The values of the yield stresses obtained using the creep instrument were found to be significantly lower than those obtained from common extrapolations from rotational and capillary rheometers. In the ternary compounds it was also observed that as the oil content increases, not only the viscosity but the yield stress is reduced significantly. This observation is important because it can throw light on the type of interactions between carbon black and the rubber matrix.

MR Fluid Behavior Under Constant Shear Rates and High Magnetic Fields Over Long Time Periods

Aerospace ◽  
2004 ◽  
Author(s):  
Constantin Ciocanel ◽  
Kevin Molyet ◽  
Hideki Yamamoto ◽  
Sheila L. Vieira ◽  
Nagi G. Naganathan
Keyword(s):  
Magnetic Field ◽  
Shear Rate ◽  
Shear Strain ◽  
Rheological Properties ◽  
Smart Materials ◽  
Shear Stresses ◽  
Mr Fluid ◽  
Shear Rates ◽  
Constant Shear ◽  
Mechanical Devices

MR fluids are smart materials that reversibly change their rheological properties in the presence of a magnetic field. Their capability to support a high range of shear stresses makes them an ideal component of many mechanical devices. However, to be suitable for applications requiring a large number of cycles, e.g. a clutch, the long term behavior of these fluids needs to be thoroughly investigated and well understood. The paper presents a new MR cell design along with a study of the shear rate, shear strain, magnetic field and time influences on the properties and behavior of a MR fluid tested for long periods of time. The MR cell is required to adapt a commercially available rheometer to measure the rheological properties of the fluid. Overall characteristics of the designed MR cell output capability are provided. Constant shear rate tests, two hours in duration, have been performed at shear rates between 0.1 and 200 l/s under magnetic field intensities up to 0.4 T. The rheological measurements indicated that the time, the shear strain and the shear rate influence the fluid’s shear stress magnitude.

Rheological Properties of Two Unvulcanized Rubber Compounds as Determined on an Extrusion and a Rotational Viscometer

1964 ◽  
Vol 37 (2) ◽  
pp. 491-502
Author(s):  
F. E. Devine ◽  
J. A. Ross
Keyword(s):  
Shear Stress ◽  
Rheological Properties ◽  
Extrusion Pressure ◽  
Rheological Parameters ◽  
Shear Stresses ◽  
Extrude Material ◽  
Rotational Viscometer ◽  
Shear Rates ◽  
Rubber Compounds

Abstract The viscometer manufactured by A. Macklow-Smith Ltd., which operates at constant rate of extrusion, is a capillary instrument designed for the determination of flow properties of plastics. The instrument has been used for examining the rheological characteristics of rubber compounds and it has been possible to derive the shear stresses required to extrude material at various shear rates between 2 and 1050 sec−1. The general method of operation of the instrument for this purpose is discussed including the determination of preheat time before extrusion and the aspect of incipient vulcanization in the viscometer during extrusion. The effects of various lengths and diameters of dies on rheological parameters and entrance effects are discussed. An important aspect of the work is the observation of a piston height effect in the extruder barrel. Two different compounded polymers have been examined and in one case, the extrusion pressure was found to decrease with piston height whilst in the other highly elastic material, it was found that as the piston descended, the extrusion pressure increased to an equilibrium value. The importance of this effect in obtaining consistent shear stress data is discussed. Results of the work have been expressed in terms of apparent viscosity and also in terms of the parameters which describe a power law relating shear stress and shear rate within the capillary die. Rheological data have been obtained at various temperatures within the range of processing temperatures of the compounds. The effects on rheological properties of mastication and relaxation time after mastication have been examined. Results have been compared with figures obtained on conventional laboratory viscometers such as the Mooney Plastometer and the Wallace Rapid Plastimeter. A biconical, rotational viscometer has also been used at the lower range of shear rates and the results are compared with those obtained from the extrusion viscometer.

RHEOLOGICAL PROPERTIES OF NOVEL MAGNETORHEOLOGICAL FLUIDS

2007 ◽  
Vol 21 (28n29) ◽  
pp. 4849-4857 ◽  
Author(s):  
S. MANTRIPRAGADA ◽  
X. WANG ◽  
F. GORDANINEJAD ◽  
B. HU ◽  
A. FUCHS
Keyword(s):  
Magnetic Field ◽  
Rheological Properties ◽  
Yield Stress ◽  
Parallel Plate ◽  
Magnetorheological Fluids ◽  
High Yield ◽  
Iron Particles ◽  
Shear Rates ◽  
Low Viscosity ◽  
Mr Fluids

The rheological properties of novel MR fluids are characterized using a parallel plate MR shear rheometer. In these MR fluids the surface of iron particles is coated with a polymer. The rheological properties are measured and compared at various magnetic field strengths, shear rates and strain amplitudes. It has been shown that these MR fluids exhibit stable and desirable rheological properties such as, low viscosity and high yield stress.

scholarly journals Enhancement of Chloroprene/Natural/Butadiene Rubber Nanocomposite Properties Using Organoclays and Their Combination with Carbon Black as Fillers

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1085
Author(s):  
Patricia Castaño-Rivera ◽  
Isabel Calle-Holguín ◽  
Johanna Castaño ◽  
Gustavo Cabrera-Barjas ◽  
Karen Galvez-Garrido ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Carbon Black ◽  
High Performance ◽  
Rubber Matrix ◽  
Butadiene Rubber ◽  
X Ray Diffraction ◽  
X Ray ◽  
Rubber Blends ◽  
Ft Ir ◽  
Chloroprene Rubber

Organoclay nanoparticles (Cloisite® C10A, Cloisite® C15) and their combination with carbon black (N330) were studied as fillers in chloroprene/natural/butadiene rubber blends to prepare nanocomposites. The effect of filler type and load on the physical mechanical properties of nanocomposites was determined and correlated with its structure, compatibility and cure properties using Fourier Transformed Infrared (FT-IR), X-ray Diffraction (XRD), Thermogravimetric Analysis (TGA) and rheometric analysis. Physical mechanical properties were improved by organoclays at 5–7 phr. Nanocomposites with organoclays exhibited a remarkable increase up to 46% in abrasion resistance. The improvement in properties was attributed to good organoclay dispersion in the rubber matrix and to the compatibility between them and the chloroprene rubber. Carbon black at a 40 phr load was not the optimal concentration to interact with organoclays. The present study confirmed that organoclays can be a reinforcing filler for high performance applications in rubber nanocomposites.

Electrical conductivity and rheological properties of carbon black based conductive polymer composites prior to and after annealing

2021 ◽  
pp. 096739112110012
Author(s):  
Qingsen Gao ◽  
Jingguang Liu ◽  
Xianhu Liu
Keyword(s):  
Electrical Conductivity ◽  
Carbon Black ◽  
Percolation Threshold ◽  
Rheological Properties ◽  
Network Formation ◽  
Loss Modulus ◽  
Conductive Polymer ◽  
Complex Viscosity ◽  
Electrical Percolation ◽  
Electrical Percolation Threshold

The effect of annealing on the electrical and rheological properties of polymer (poly (methyl methacrylate) (PMMA) and polystyrene (PS)) composites filled with carbon black (CB) was investigated. For a composite with CB content near the electrical percolation threshold, the formation of conductive pathways during annealing has a significant impact on electrical conductivity, complex viscosity, storage modulus and loss modulus. For the annealed samples, a reduction in the electrical and rheological percolation threshold was observed. Moreover, a simple model is proposed to explain these behaviors. This finding emphasizes the differences in network formation with respect to electrical or rheological properties as both properties belong to different physical origins.

Wet compounding with pyrolytic carbon black from waste tyre for manufacture of new tyre – A mini review

2021 ◽  
pp. 0734242X2110047
Author(s):  
Junqing Xu ◽  
Jiaxue Yu ◽  
Wenzhi He ◽  
Juwen Huang ◽  
Junshi Xu ◽  
...  
Keyword(s):  
Carbon Black ◽  
Pyrolytic Carbon ◽  
Research Progress ◽  
Rubber Matrix ◽  
Innovative Technology ◽  
Nano Materials ◽  
Natural Rubber Composites ◽  
Waste Tyres ◽  
Dry Mixing ◽  
Waste Tyre

Pyrolysis offers a more focused alternative to waste tyres treatment. Pyrolytic carbon black (CBp), the main product of waste tyre pyrolysis, and its modified species can be applied to tyre manufacturing realizing its high-value utilization. Modified pyrolytic carbon black/natural rubber composites prepared by a wet compounding (WC) and latex mixing process have become an innovative technology route for waste tyre remanufacturing. The main properties and applications of CBp reported in recent years are reviewed, and the main difficulties affecting its participation in tyre recycling are pointed out. The research progress of using WC technology to replace dry mixing manufacturing of new tyres is summarized. Through literature data and comparative studies, this paper points out that the characteristic of high ash content can be well utilized if CBp is applied to tyre manufacturing. This mini-review proposes a new method for high-value utilization of CBp. The composite mixing of CBp and carbon nano-materials under wet conditions is conducive to the realization of their good dispersion in the rubber matrix. This provides a new idea for customer resource integration and connection of industry development between the tyre production industry and waste tyre disposal management.

scholarly journals Comparison of the Effects of Conching Parameters on the Contents of Three Dominant Flavan3-ols, Rheological Properties and Sensory Quality in Chocolate Milk Mass Based on Liquor from Unroasted Cocoa Beans

Molecules ◽  
2021 ◽  
Vol 26 (9) ◽  
pp. 2502
Author(s):  
Bogumiła Urbańska ◽  
Hanna Kowalska ◽  
Karolina Szulc ◽  
Małgorzata Ziarno ◽  
Irina Pochitskaya ◽  
...  
Keyword(s):  
Rheological Properties ◽  
Yield Stress ◽  
Sensory Quality ◽  
Raw Material ◽  
Antioxidant Compounds ◽  
Chocolate Milk ◽  
Cocoa Beans ◽  
Variable Parameters ◽  
The Relationship ◽  
Manufacturing Parameters

The content of polyphenols in chocolate depends on many factors related to the properties of raw material and manufacturing parameters. The trend toward developing chocolates made from unroasted cocoa beans encourages research in this area. In addition, modern customers attach great importance to how the food they consume benefits their bodies. One such benefit that consumers value is the preservation of natural antioxidant compounds in food products (e.g., polyphenols). Therefore, in our study we attempted to determine the relationship between variable parameters at the conching stage (i.e., temperature and time of) and the content of dominant polyphenols (i.e.,catechins, epicatechins, and procyanidin B2) in chocolate milk mass (CMM) obtained from unroasted cocoa beans. Increasing the conching temperature from 50 to 60 °C decreased the content of three basic flavan-3-ols. The highest number of these compounds was determined when the process was carried out at 50 °C. However, the time that caused the least degradation of these compounds differed. For catechin, it was 2 h; for epicatechin it was 1 h; and for procyanidin it was 3 h. The influence of both the temperature and conching time on the rheological properties of chocolate milk mass was demonstrated. At 50 °C, the viscosity and the yield stress of the conched mass showed its highest value.

scholarly journals Electromagnetic Interference Shielding and Physical-Mechanical Characteristics of Rubber Composites Filled with Manganese-Zinc Ferrite and Carbon Black

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 616
Author(s):  
Ján Kruželák ◽  
Andrea Kvasničáková ◽  
Klaudia Hložeková ◽  
Rastislav Dosoudil ◽  
Marek Gořalík ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Carbon Black ◽  
Zinc Ferrite ◽  
Mechanical Characteristics ◽  
Hybrid Composites ◽  
Rubber Matrix ◽  
Butadiene Rubber ◽  
Frequency Range ◽  
Manganese Zinc ◽  
Manganese Zinc Ferrite

In the present work, composite materials were prepared by incorporation of manganese-zinc ferrite, carbon black and combination of ferrite and carbon black into acrylonitrile-butadiene rubber (NBR). For cross-linking of composites, standard sulfur-based curing system was applied. The main goal was to investigate the influence of the fillers on the physical-mechanical properties of composites. Then, the electromagnetic absorption shielding ability was investigated in the frequency range 1 MHz–3 GHz. The results revealed that composites filled with ferrite provide sufficient absorption shielding performance in the tested frequency range. On the other hand, ferrite behaves as an inactive filler and deteriorates the physical-mechanical characteristics of composites. Carbon black reinforces the rubber matrix and contributes to the improvement of physical-mechanical properties. However, composites filled with carbon black are not able to absorb electromagnetic radiation in the given frequency range. Finally, the combination of carbon black and ferrite resulted in the modification of both physical-mechanical characteristics and absorption shielding ability of hybrid composites.

scholarly journals Rheological Properties of Wood–Plastic Composites by 3D Numerical Simulations: Different Components

Forests ◽  
2021 ◽  
Vol 12 (4) ◽  
pp. 417
Author(s):  
Xingcong Lv ◽  
Xiaolong Hao ◽  
Rongxian Ou ◽  
Tao Liu ◽  
Chuigen Guo ◽  
...  
Keyword(s):  
Flow Field ◽  
Rheological Properties ◽  
Wood Fiber ◽  
Velocity Shear ◽  
Wood Plastic Composites ◽  
Shear Rates ◽  
Plastic Composites ◽  
Power Law Fluids ◽  
Field Information ◽  
Computational Fluid Dynamics Cfd

The rheological properties of wood–plastic composites (WPCs) with different wood fiber contents were investigated using a rotational rheometer under low shear rates. The flow field information was analyzed and simulated by Ansys Polyflow software. The results showed that the WPCs with different wood fiber contents behaved as typical power-law fluids. A higher wood fiber content increased the shear thinning ability and pseudoplasticity of the WPCs. The pressure, velocity, shear rate, and viscosity distributions of the WPC during extrusion could be predicted by computational fluid dynamics (CFD) Ansys Polyflow software to explore the effects of different components on the flow field of WPCs.

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