The Effect of Solvents on the Stress-Strain Curve of Vulcanized Rubber

1930 ◽  
Vol 3 (1) ◽  
pp. 19-21 ◽  
Author(s):  
H. A. Tiltman ◽  
B. D. Porritt
Keyword(s):  
Tensile Strength ◽  
Marked Effect ◽  
Strain Curve ◽  
Theoretical Interest ◽  
Stress Strain Curve ◽  
Stress Strain ◽  
Cohesive Forces ◽  
Effect Of Solvents ◽  
Vulcanized Rubber ◽  
Permanent Effect

Abstract (1) The results indicate that the rigidity of a piece of vulcanized rubber is considerably reduced by the absorption of small amounts of a solvent; thus, at a strain of 6 ( = 600 per cent elongation) the absorption of 5 per cent by weight ( = 8 per cent by volume) of benzene lowers the rigidity by 21 per cent. (2) The greatest effect is produced by the first 20 or 30 per cent (by weight) of absorbed benzene, further absorption having a less marked effect on the stress-strain curve. (3) The absorption of solvent seems to have very little effect on the breaking elongation, although the tensile strength is considerably lowered. This conclusion, however, is probably no longer true in the case of rubber swollen by immersion in liquid, where the absorption is very much greater than in the present tests. (4) Absorption of solvent followed by complete drying appears to produce a slight, but technically negligible, permanent effect on the stress-strain curve. It is evident from these results that when it is necessary to use solvents, either in the process of manufacture or the after-treatment of rubber products, these should be selected as free as possible from high-boiling constituents liable to be permanently retained by the rubber with consequent detriment to its strength. A conclusion of some theoretical interest is that since all the stresses in the present investigation were calculated on the dimensions of the original dry rubber, the low rigidity of swollen rubber cannot be ascribed simply to the “dilution” of the rubber by the absorbed liquid, but must be due to a loosening of the cohesive forces between the ultimate particles of the material.

Effects of AP and AP-ethyl on the properties of PA6

2017 ◽  
Vol 31 (12) ◽  
pp. 1609-1618
Author(s):  
Long Lijuan ◽  
He Wentao ◽  
Li Juan ◽  
Xiang Yushu ◽  
Qin Shuhao ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Fracture Surface ◽  
Thermal Degradation ◽  
Flame Retardant ◽  
Strain Curve ◽  
Stress Strain Curve ◽  
Stress Strain ◽  
Cone Calorimeter Test ◽  
Mean Size ◽  
The Mean

In this work, the effects of inorganic phosphinate flame retardant of aluminum hypophosphite (AP) and organic phosphinate flame retardant of ethyl substituted phosphinates (AP-ethyl) on the thermal degradation, flame performance, and mechanical properties of polyamide 6 (PA6) were investigated. Scanning electron micrograph showed AP with the shape of bulk and the mean size of 8 μm while AP-ethyl with irregular shape and the mean size of 30 μm. Thermal analysis indicated that the thermal degradation behavior of flame-retardant PA6 was different from pure PA6. Moreover, the cone calorimeter test results revealed that peak heat release rate (PHRR) of PA6/AP (85/15) and PA6/AP-ethyl (85/15) decreased by 51% and 64%, respectively, compared with pure PA6. Furthermore, pure PA6 showed ductile stress–strain curve with the tensile strength of 54.8 MPa. However, PA6/AP and PA6/AP-ethyl displayed brittle stress–strain curve and their tensile strength decreased to 52.3 and 47.1 MPa, respectively. In addition, pure PA6 showed a glossy and tough fracture surface morphology. The rough fracture surface morphologies for PA6/AP and PA6/AP-ethyl were observed, and the interface of PA6/AP was more obscure than that of PA6/AP-ethyl. Consequently, the small particle size of AP had a more uniform dispersion in PA6 matrix.

The Behavior of Raw Rubber When Stretched Isothermally

1938 ◽  
Vol 11 (4) ◽  
pp. 647-652 ◽  
Author(s):  
H. Hintenberger ◽  
W. Neumann
Keyword(s):  
Room Temperature ◽  
Strain Curve ◽  
Stress Strain Curve ◽  
Stress Strain ◽  
Steep Ascent ◽  
Flow Effect ◽  
Vulcanized Rubber ◽  
Flow Phenomena ◽  
Entropy Effect ◽  
The Subject

Abstract The S-shaped form of the stress-strain curve of rubber is today explained in a quite satisfactory way. In the first part of the curve, i. e., the gradual ascent, work must be expended because of the van der Waals forces of attraction of the molecules; in the second part, i. e., the steep ascent, the elasticity is chiefly an entropy effect, which is finally exceeded by crystallization phenomena. The phenomenon of crystallization itself has been the subject of extensive investigations, but in most cases vulcanized rubber has been employed, and because of the various accelerators and fillers which the rubber has contained, the products have been rather ill-defined. It is evident that the phenomena involved in crystallization would be much more clearly defined if the substance under investigation were to be in a higher state of purity. If experiments are carried out with raw rubber, a flow effect is added to the various other phenomena. As a result of this flow effect, Rosbaud and Schmidt, and Hauser and Rosbaud as well, found that the stress-strain curve depends on the rate of elongation at very low extensions, with a greater stiffness at high rates of elongation. As found recently by Kirsch, there is no evidence of any flow phenomena in vulcanized rubber at room temperature. Most investigations have been so carried out that the stress has been measured at a definite elongation. It was therefore of interest to determine the elongation at constant stress, and the changes in this relation with time and with temperature, of various types of raw rubber.

The Effect of Softeners in Rubber

1953 ◽  
Vol 26 (1) ◽  
pp. 152-155
Author(s):  
Ira Williams
Keyword(s):  
Tensile Strength ◽  
Natural Rubber ◽  
High Modulus ◽  
Mineral Oils ◽  
Cohesive Forces ◽  
Commercial Use ◽  
Effect Of Solvents ◽  
Vulcanized Rubber ◽  
Unfavorable Effect ◽  
The Cost

Abstract The use of oils and liquid softeners to assist in the mastication and processing of rubber or to produce softer vulcanized stocks has been standard practice since the early commercial use of rubber. More recently certain synthetic rubbers, polymerized under special conditions, have been treated with rather large amounts of mineral oils, with a resulting decrease in the cost of the rubber and apparently with no unfavorable effect on the rubber in most instances. A number of investigators have reported the effect of swelling agents on the properties of vulcanized rubber. Busse discusses the effect of solvents in a general way. Tiltman and Porritt conclude that the decrease in modulus caused by swelling in benzene is caused by a “loosening of cohesive forces.” Tire treads of natural rubber containing such softeners as pine tar and mineral rubber decrease in wear resistance in proportion to the softener content. Well vulcanized rubber of high modulus is most resistant to swelling in oils. Naunton, Jones, and Smith find that unaccelerated stocks lose the most tensile strength after being swollen, that milling of the raw rubber increases swelling, and that the presence of softeners in the rubber during vulcanization reduces the oil resistance. A limited amount of swelling has been reported to have little effect on the tensile strength of vulcanized natural rubber. Bourbon points out that separating the rubber molecules with solvent decreases the rate of vulcanization.

Reinforcement of Butyl with Carbon Black. II. Thermally vs. Chemically Oxidized Blacks

1964 ◽  
Vol 37 (4) ◽  
pp. 1034-1048 ◽  
Author(s):  
A. M. Gessler
Keyword(s):  
Carbon Black ◽  
Chemical Reactivity ◽  
Preceding Paper ◽  
Strain Curve ◽  
Convincing Evidence ◽  
Stress Strain Curve ◽  
Stress Strain ◽  
Carbon Particles ◽  
Vulcanized Rubber ◽  
Oxygen Functionality

Abstract The effect of oxidized blacks on the stress-strain properties and bound-rubber content of butyl and SBR was discussed in the preceding paper. Oxidized blacks, when compared with similar untreated blacks, were shown to have a greatly increased reinforcing capacity in butyl. Oxygen functionality on carbon black, it was therefore concluded, is essential in butyl to produce the chemical reactivity which is required between polymer and black if high-order reinforcement is to be obtained. Oxygen functionality on carbon black, it was also demonstrated, is not only not required for enhanced reinforcement in SBR, but it is in fact a deterrent, because it exerts severe restraining effects on the cure of the resulting vulcanizates as well. These interesting results were proposed to provide qualitative but convincing evidence that carbon-polymer bonding, which we believe is requisite to reinforcement, is achieved by different mechanisms in butyl and SBR. In butyl, the unique sensitivity of the stress-strain curve to reinforcing effects was used to speculate on the disposition of carbon blacks in “filled” and reinforced vulcanizates, respectively. With oxidized blacks, reinforcement effects were pictured as stiffening effects which, starting with the gum vulcanizates, caused the stress-strain curve to be shifted without intrinsic changes in its shape. The resulting “reinforced gum,” it was suggested, derived its physical characteristics from the fact that carbon black was included in the vulcanized rubber network. With untreated blacks, in “filled” systems, carbon black was pictured as being enmeshed or entangled in an independently formed vulcanized rubber network. The stiffening effects in this case were attributed to viscous contributions arising from steric restrictions which the occluded carbon particles were thought to impose on both initial movements and the subsequent orientation of network chains when the sample was extended.

Thermodynamics of Crystallization in High Polymers. VI. Incipient Crystallization in Stretched Vulcanized Rubber

1950 ◽  
Vol 23 (3) ◽  
pp. 576-580 ◽  
Author(s):  
Thomas G. Fox ◽  
Paul J. Flory ◽  
Robert E. Marshall
Keyword(s):  
Theoretical Prediction ◽  
Experimental Determination ◽  
Strain Curve ◽  
Steep Slope ◽  
Stress Strain Curve ◽  
Stress Strain ◽  
Hydrostatic Method ◽  
Vulcanized Rubber ◽  
High Polymers

Abstract Experimental determination of the elongation at which crystallization commences in vulcanized rubber has been attempted through measurement of density changes by a hydrostatic method. The critical elongation for incipient crystallization appears to depend on the temperature, in approximate accordance with theoretical prediction. Crystallization sets in at an elongation well below that at which the stress-strain curve assumes a steep slope.

A Mathematical Treatment of a Theory of Rubber Structure

1935 ◽  
Vol 8 (1) ◽  
pp. 23-38
Author(s):  
T. R. Griffith
Keyword(s):  
Elastic Modulus ◽  
Plastic Flow ◽  
Strain Curve ◽  
The Other ◽  
Stress Axis ◽  
Mathematical Treatment ◽  
Stress Strain Curve ◽  
Stress Strain ◽  
Joule Effect ◽  
Vulcanized Rubber

Abstract A brief consideration of the work that has been done on the structure of rubber convinces, one that the elasticity is wholly or at least mainly explained by a consideration of the kinetics involved. The fact that when a strip of stretched rubber, one end of which is free, contracts when it is warmed, contrary to the behavior of most bodies, and that it becomes warmed on stretching, commonly known as the Gough-Joule effect, pp. 453–461, would lead one to suspect .that there is a connection between the kinetic energy of the rubber molecule and its elasticity. Lundal, Bouasse, Hyde, Somerville and Cope, Partenheimer and Whitby and Katz have reported observations, principally stress-strain curves, which show that vulcanized rubber has a lower modulus of elasticity at higher temperatures, i. e., it becomes easier to stretch as the temperature is raised. On the other hand, Schmulewitsch, Stevens, and Williams found that the elastic modulus increases with the temperature. Williams shows that the softening of vulcanized rubber with rise of temperature is due to an increase of plasticity. In order to get rid of plastic flow, he first stretches the specimen several times to within about 50 per cent of its breaking elongation, and then obtains an autographic stress-strain curve of the rubber stretched very quickly. He finds that in this case the rubber actually becomes stiffer with rise of temperature, increasing temperatures causing the stress-strain curves to lean progressively more and more toward the stress axis. He concludes that rise of temperature has two effects, one a softening due to increase of plasticity, rendering plastic flow more easy, the other an actual stiffening of the rubber due to rise of temperature. It is not easy to explain the latter effect on any theory which does not take kinetics into account.

The Stress-Strain Relationship in Ebonite

1934 ◽  
Vol 7 (1) ◽  
pp. 197-211
Author(s):  
B. L. Davies
Keyword(s):  
Tensile Strength ◽  
Plastic Flow ◽  
Testing Machine ◽  
Strain Curve ◽  
Stress Strain Curve ◽  
Stress Strain ◽  
Tensile Testing Machine ◽  
Hooke’S Law ◽  
Hooke's Law ◽  
Soft Rubber

Abstract 1. A simple “extensometer” has been devised for the more accurate measurement of small elongations in hard rubber samples, thus enabling stress-strain curves to be obtained on a standard tensile testing machine. 2. The form of the curve has been described more fully than heretofore. It shows that hard rubber does not deform exactly in accordance with Hooke's Law, but exhibits plastic flow. 3. Deviations from Hooke's Law shown by the experimental curves depend upon the speed of stretching. Increased speed of elongation has been found to give higher readings of tensile strength. 4. Prolonged mastication of the rubber gives a weaker product, similar effects being obtainable by the use of a neutral softener. 5. The effects of increasing time of vulcanization have been described. The range of curves showing transition from over-cured soft rubber to ebonite indicates that the hard rubber curve is possibly related to the initial portion of the soft rubber curve. The plasticity of the overvulcanized rubber, as indicated by the deviation from Hooke's Law, increased with time of vulcanization until the “semi-ebonite” stage was reached. 6. The leather-like “semi-ebonites” differed from soft and hard rubber inasmuch as they were extremely sensitive to small changes in time of vulcanization, and inasmuch as their plasticity was such that the velocity of plastic flow was comparable with the rate of pulling (1 in. per minute), at a particular point in the test they experienced a large elongation at constant load, i. e., the velocity of flow was equal to the speed of pulling. Their plasticity decreased with further vulcanization. 7. The longest cures in the above-mentioned group gave products which were rigid at room temperature. Since these must be more resistant to shock than vulcanizates in a higher state of cure, it seems that the best technical cure of ebonite for mechanical purposes is that which gives maximum tensile strength combined with the property of undergoing considerable plastic flow (of the order of 5 per cent) at the constant maximum load, and at an arbitrarily fixed rate of stretching, the temperature being commensurate with the thermal conditions of service. Such a cure is clearly indicated by the stress-strain curve. 8. Accelerated ebonite mixings are more sensitive to time of cure than rubber-sulfur stocks without accelerators. An accelerator may produce very little effect on the tensile strength and breaking elongation, but may yield a stock which “scorches” readily. This prevulcanization was detrimental to the mechanical properties of the vulcanizate, even though it was so slight that its presence was not detected during normal processing. 9. Mineral rubber in ebonite stocks has been shown to accelerate the cure as indicated by the stress-strain curve. 10. Stocks containing high loadings of gas black gave vulcanizates which were weak and brittle. The effect of the black on the stiffness was similar to that produced by further cure. 11. The stress-strain curve provides a reliable means whereby stocks containing different accelerators and other compounding ingredients may be compared at equivalent states of vulcanization.

Uncertainty Quantification of Nondestructive Techniques to Verify Pipeline Material Strength

2018 ◽  
Author(s):  
Jeffrey A. Kornuta ◽  
Nicoli M. Ames ◽  
Mary W. Louie ◽  
Peter Veloo ◽  
Troy Rovella
Keyword(s):  
Tensile Strength ◽  
Material Properties ◽  
Strain Curve ◽  
Material Strength ◽  
Stress Strain Curve ◽  
Stress Strain ◽  
Empirical Constant ◽  
Modeling Uncertainties ◽  
Force Displacement ◽  
Indentation Response

The Pipeline and Hazardous Materials Safety Administration (PHMSA) Notice of Proposed Rulemaking (NPRM), with Docket No. PHMSA-2011-0023, substantially revises 49 CFR Part 191 and 192. Notable among these changes was the addition of §192.607, verification of pipeline material. This section calls for the verification of material properties of pipe and fittings located in either high consequence areas, class 3, or class 4 locations where traceable, verifiable, and complete records do not exist. Material properties include grade (yield strength, YS, and ultimate tensile strength, UTS) and chemical composition. The proposed regulations include an independent third-party validation for non-destructive testing (NDT) methods to determine material strength and require an accuracy of within ±10% of an actual strength value. Among the NDT technologies currently available to pipeline operators to estimate material strength is instrumented indentation testing (IIT). IIT is based on the principal that there exists a relationship between the indentation response of a material and its stress-strain curve. The indentation response is measured during the IIT process whereby an indenter is sequentially forced into the material during testing. The link between the indentation response and the material stress-strain curve is established often through the use of iterative Finite Element Analysis (FEA). The IIT vendor’s proprietary software performs this calculation, converting force-displacement measurements into an estimate of YS and UTS. In this study we extracted force-displacement data from IIT performed using FEA on an idealized steel. This data was then coupled with literature algorithms developed at Seoul National University (Kwon et al.). Parametric sensitivity analysis was then performed on estimated YS with respect to the algorithm parameters. Preliminary results indicate that while variations in the indenter constant, ω, used to estimate surface deformation do not significantly alter the predicted UTS or YS, the sensitivity to deviations in the empirical constant, Ψ, relating normal load to representative stress was more pronounced due to an effect on the calculated power-law constant, K. PHMSA’s NPRM accuracy requirements for NDT to establish yield and tensile strength should be driven by a rigorous understanding of material inhomogeneities, uncertainties in actual tensile strength determination, experimental uncertainty, and modeling uncertainties. The analysis performed in this paper provides part of this rigorous framework to establish realistic accuracy requirements for NDT that must drive federal rulemaking. In addition, this research highlights the need for pipeline operators to establish controls on the algorithms adopted by commercial NDT vendors.

A Contribution to the Characterization of the Plastic-Elastic State

1939 ◽  
Vol 12 (4) ◽  
pp. 799-804 ◽  
Author(s):  
E. Rohde
Keyword(s):  
Characteristic Property ◽  
Strain Curve ◽  
The Other ◽  
Elastic State ◽  
Stress Strain Curve ◽  
Stress Strain ◽  
Vulcanized Rubber ◽  
Other Hand ◽  
Puzzling Problem

Abstract The manner in which vulcanized rubber can be deformed and yet return almost completely to its original dimensions after the stress is released is a unique and characteristic property. Technically the problem in testing rubber is to evaluate this property and to define it in terms of the factors which are concerned. To define completely this property of rubber whereby it is susceptible to deformation, it is necessary to know the stress, the elongation, the energy expended, the energy lost, the time and the temperature. The stress, elongation and energy expended are closely related and are characterized by the stress-strain curve, which in turn depends on the time and temperature. In addition, it must be borne in mind that rubber can be deformed either by tension or by pressure, but this will not be discussed further here. On the other hand a rather puzzling problem will be considered, the solution of which brings out the fact that the three variables involved in any deformation, viz.: (1) The time or frequency. (2) The temperature. (3) The interrelated factors: stress, elongation and energy expended, must be varied considerably in order to characterize the phenomena of deformation and that when this is done, unexpected results are obtained.

Ultra-Speed Tensile of Rubber and Synthetic Elastomers

1951 ◽  
Vol 24 (1) ◽  
pp. 144-160
Author(s):  
D. S. Villars
Keyword(s):  
Tensile Strength ◽  
High Speed ◽  
Relaxation Times ◽  
Strain Curve ◽  
Stress Strain Curve ◽  
Stress Strain ◽  
Elongation At Break ◽  
Different Types ◽  
Speed Up ◽  
Pass Through

Abstract A high speed stress-strain machine has been developed which is capable of recording the stress-strain curve of elastomers at elongation rates up to 270 per cent/msec. Data are reported on two series of gum and tread stocks of Hevea and of the synthetic elastomers, GR-S, Hycar-OR, Butyl, Perbunan, and Neoprene-GN. The second (elastomer) series was also run at 150° C. In general, stress-strain curves fall into two classes. Stocks of elastomers which are known to crystallize on stretching tend to show tensile strengths which decrease with increasing speed up to about 10 per cent/msec, pass through a minimum, and rise more or less drastically to values 100 per cent (or more) greater than the Scott tensile strength. Elastomers which do not crystallize on stretching tend to show a steady rise in tensile strength with increasing speed. Elongation at break curves show a maximum with crystallizing stocks and no maximum with noncrystallizing stocks. The shape of the modulus vs. speed curves is accounted for on the hypothesis of different types of slipping bonds with different characteristic relaxation times. The shift of curves for tread stocks with temperature allows the estimation of a heat of activation of slippage. This comes out to be of the order of 3 kg.-cal.

Sign in / Sign up

Export Citation Format

Share Document