Ultra-Speed Tensile of Rubber and Synthetic Elastomers

1951 ◽  
Vol 24 (1) ◽  
pp. 144-160
Author(s):  
D. S. Villars

Abstract A high speed stress-strain machine has been developed which is capable of recording the stress-strain curve of elastomers at elongation rates up to 270 per cent/msec. Data are reported on two series of gum and tread stocks of Hevea and of the synthetic elastomers, GR-S, Hycar-OR, Butyl, Perbunan, and Neoprene-GN. The second (elastomer) series was also run at 150° C. In general, stress-strain curves fall into two classes. Stocks of elastomers which are known to crystallize on stretching tend to show tensile strengths which decrease with increasing speed up to about 10 per cent/msec, pass through a minimum, and rise more or less drastically to values 100 per cent (or more) greater than the Scott tensile strength. Elastomers which do not crystallize on stretching tend to show a steady rise in tensile strength with increasing speed. Elongation at break curves show a maximum with crystallizing stocks and no maximum with noncrystallizing stocks. The shape of the modulus vs. speed curves is accounted for on the hypothesis of different types of slipping bonds with different characteristic relaxation times. The shift of curves for tread stocks with temperature allows the estimation of a heat of activation of slippage. This comes out to be of the order of 3 kg.-cal.

2017 ◽  
Vol 31 (12) ◽  
pp. 1609-1618
Author(s):  
Long Lijuan ◽  
He Wentao ◽  
Li Juan ◽  
Xiang Yushu ◽  
Qin Shuhao ◽  
...  

In this work, the effects of inorganic phosphinate flame retardant of aluminum hypophosphite (AP) and organic phosphinate flame retardant of ethyl substituted phosphinates (AP-ethyl) on the thermal degradation, flame performance, and mechanical properties of polyamide 6 (PA6) were investigated. Scanning electron micrograph showed AP with the shape of bulk and the mean size of 8 μm while AP-ethyl with irregular shape and the mean size of 30 μm. Thermal analysis indicated that the thermal degradation behavior of flame-retardant PA6 was different from pure PA6. Moreover, the cone calorimeter test results revealed that peak heat release rate (PHRR) of PA6/AP (85/15) and PA6/AP-ethyl (85/15) decreased by 51% and 64%, respectively, compared with pure PA6. Furthermore, pure PA6 showed ductile stress–strain curve with the tensile strength of 54.8 MPa. However, PA6/AP and PA6/AP-ethyl displayed brittle stress–strain curve and their tensile strength decreased to 52.3 and 47.1 MPa, respectively. In addition, pure PA6 showed a glossy and tough fracture surface morphology. The rough fracture surface morphologies for PA6/AP and PA6/AP-ethyl were observed, and the interface of PA6/AP was more obscure than that of PA6/AP-ethyl. Consequently, the small particle size of AP had a more uniform dispersion in PA6 matrix.


1937 ◽  
Vol 135 (1) ◽  
pp. 467-483
Author(s):  
R. J. Lean ◽  
H. Quinney

The paper contains an account of a research into the effect on metals of different speeds of fracture, using a specially designed high-speed testing machine which is described in detail. The experiments were conducted both in this machine and in a 5-ton variable-speed autographic tensile machine, on five steels, the rate of loading being varied for each. With the high-speed machine toughness, ductility, time to produce fracture, and the stress-strain curve were obtained. The results of these combined tests, given in tables and graphs, show that there is a marked increase in stress due to higher speed of testing; and also that the work required to cause fracture increases with the speed. For mild steel the stress at the initial yield point was found to be in excess of that at the maximum point, when the speed of testing was increased the ductility did not appear to suffer.


Metals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1214
Author(s):  
Song Zhang ◽  
Xuedao Shu ◽  
Jitai Wang ◽  
Yingxiang Xia

It is necessary to establish a constitutive model of 30CrMoA steel to optimize the forming shape and mechanical properties of high-speed train axles. The experimental stress–strain curve of 30CrMoA steel was obtained by an isothermal compression test on a Gleeble-3500 thermal simulation test machine under temperature of 1273~1423 K and strain rate of 0.01~10 s−1. Considering the effect of strain on the material constant, an empirical constitutive model was proposed with strain correction for 30CrMoA steel. In addition, the material constant in the constitutive model is determined by linear regression analysis of the experimental stress–strain curve. Comparing the theoretical value and experimental value of flow stress, the correlation R is 0.9828 and the average relative error (ARRE) is 4.652%. The constitutive model of 30CrMoA steel with strain correction can reasonably predict the flow stress under various conditions. The results provide an effective numerical tool for further study on accurate near-net forming of high-speed train axles.


1934 ◽  
Vol 7 (1) ◽  
pp. 197-211
Author(s):  
B. L. Davies

Abstract 1. A simple “extensometer” has been devised for the more accurate measurement of small elongations in hard rubber samples, thus enabling stress-strain curves to be obtained on a standard tensile testing machine. 2. The form of the curve has been described more fully than heretofore. It shows that hard rubber does not deform exactly in accordance with Hooke's Law, but exhibits plastic flow. 3. Deviations from Hooke's Law shown by the experimental curves depend upon the speed of stretching. Increased speed of elongation has been found to give higher readings of tensile strength. 4. Prolonged mastication of the rubber gives a weaker product, similar effects being obtainable by the use of a neutral softener. 5. The effects of increasing time of vulcanization have been described. The range of curves showing transition from over-cured soft rubber to ebonite indicates that the hard rubber curve is possibly related to the initial portion of the soft rubber curve. The plasticity of the overvulcanized rubber, as indicated by the deviation from Hooke's Law, increased with time of vulcanization until the “semi-ebonite” stage was reached. 6. The leather-like “semi-ebonites” differed from soft and hard rubber inasmuch as they were extremely sensitive to small changes in time of vulcanization, and inasmuch as their plasticity was such that the velocity of plastic flow was comparable with the rate of pulling (1 in. per minute), at a particular point in the test they experienced a large elongation at constant load, i. e., the velocity of flow was equal to the speed of pulling. Their plasticity decreased with further vulcanization. 7. The longest cures in the above-mentioned group gave products which were rigid at room temperature. Since these must be more resistant to shock than vulcanizates in a higher state of cure, it seems that the best technical cure of ebonite for mechanical purposes is that which gives maximum tensile strength combined with the property of undergoing considerable plastic flow (of the order of 5 per cent) at the constant maximum load, and at an arbitrarily fixed rate of stretching, the temperature being commensurate with the thermal conditions of service. Such a cure is clearly indicated by the stress-strain curve. 8. Accelerated ebonite mixings are more sensitive to time of cure than rubber-sulfur stocks without accelerators. An accelerator may produce very little effect on the tensile strength and breaking elongation, but may yield a stock which “scorches” readily. This prevulcanization was detrimental to the mechanical properties of the vulcanizate, even though it was so slight that its presence was not detected during normal processing. 9. Mineral rubber in ebonite stocks has been shown to accelerate the cure as indicated by the stress-strain curve. 10. Stocks containing high loadings of gas black gave vulcanizates which were weak and brittle. The effect of the black on the stiffness was similar to that produced by further cure. 11. The stress-strain curve provides a reliable means whereby stocks containing different accelerators and other compounding ingredients may be compared at equivalent states of vulcanization.


Author(s):  
Jeffrey A. Kornuta ◽  
Nicoli M. Ames ◽  
Mary W. Louie ◽  
Peter Veloo ◽  
Troy Rovella

The Pipeline and Hazardous Materials Safety Administration (PHMSA) Notice of Proposed Rulemaking (NPRM), with Docket No. PHMSA-2011-0023, substantially revises 49 CFR Part 191 and 192. Notable among these changes was the addition of §192.607, verification of pipeline material. This section calls for the verification of material properties of pipe and fittings located in either high consequence areas, class 3, or class 4 locations where traceable, verifiable, and complete records do not exist. Material properties include grade (yield strength, YS, and ultimate tensile strength, UTS) and chemical composition. The proposed regulations include an independent third-party validation for non-destructive testing (NDT) methods to determine material strength and require an accuracy of within ±10% of an actual strength value. Among the NDT technologies currently available to pipeline operators to estimate material strength is instrumented indentation testing (IIT). IIT is based on the principal that there exists a relationship between the indentation response of a material and its stress-strain curve. The indentation response is measured during the IIT process whereby an indenter is sequentially forced into the material during testing. The link between the indentation response and the material stress-strain curve is established often through the use of iterative Finite Element Analysis (FEA). The IIT vendor’s proprietary software performs this calculation, converting force-displacement measurements into an estimate of YS and UTS. In this study we extracted force-displacement data from IIT performed using FEA on an idealized steel. This data was then coupled with literature algorithms developed at Seoul National University (Kwon et al.). Parametric sensitivity analysis was then performed on estimated YS with respect to the algorithm parameters. Preliminary results indicate that while variations in the indenter constant, ω, used to estimate surface deformation do not significantly alter the predicted UTS or YS, the sensitivity to deviations in the empirical constant, Ψ, relating normal load to representative stress was more pronounced due to an effect on the calculated power-law constant, K. PHMSA’s NPRM accuracy requirements for NDT to establish yield and tensile strength should be driven by a rigorous understanding of material inhomogeneities, uncertainties in actual tensile strength determination, experimental uncertainty, and modeling uncertainties. The analysis performed in this paper provides part of this rigorous framework to establish realistic accuracy requirements for NDT that must drive federal rulemaking. In addition, this research highlights the need for pipeline operators to establish controls on the algorithms adopted by commercial NDT vendors.


1965 ◽  
Vol 87 (2) ◽  
pp. 319-324 ◽  
Author(s):  
D. K. Felbeck ◽  
W. G. Gibbons ◽  
W. G. Ovens

Room-temperature tensile straining of mild steel followed by aging at 350 F causes return of the upper yield and a raising of the stress-strain curve. Tensile tests on a special rimmed steel of low Mn/C ratio show not only the expected raising of the stress-strain curve, but raising by an additional amount when several small increments of strain are each followed by aging at moderate temperatures. Longitudinal tensile prestrain by rolling gives substantially the same results. Tests of specimens prestrained in a limited region by impact or in slow tension and aged indicate that embrittlement of the whole specimen may result. The combined theories of Griffith and Orowan, plus an extension of the Ludwik triaxiality concept, can provide a consistent description of the local stress and average stress (energy) criteria that are necessary and sufficient for high-speed low-energy fracture to occur.


1930 ◽  
Vol 3 (1) ◽  
pp. 19-21 ◽  
Author(s):  
H. A. Tiltman ◽  
B. D. Porritt

Abstract (1) The results indicate that the rigidity of a piece of vulcanized rubber is considerably reduced by the absorption of small amounts of a solvent; thus, at a strain of 6 ( = 600 per cent elongation) the absorption of 5 per cent by weight ( = 8 per cent by volume) of benzene lowers the rigidity by 21 per cent. (2) The greatest effect is produced by the first 20 or 30 per cent (by weight) of absorbed benzene, further absorption having a less marked effect on the stress-strain curve. (3) The absorption of solvent seems to have very little effect on the breaking elongation, although the tensile strength is considerably lowered. This conclusion, however, is probably no longer true in the case of rubber swollen by immersion in liquid, where the absorption is very much greater than in the present tests. (4) Absorption of solvent followed by complete drying appears to produce a slight, but technically negligible, permanent effect on the stress-strain curve. It is evident from these results that when it is necessary to use solvents, either in the process of manufacture or the after-treatment of rubber products, these should be selected as free as possible from high-boiling constituents liable to be permanently retained by the rubber with consequent detriment to its strength. A conclusion of some theoretical interest is that since all the stresses in the present investigation were calculated on the dimensions of the original dry rubber, the low rigidity of swollen rubber cannot be ascribed simply to the “dilution” of the rubber by the absorbed liquid, but must be due to a loosening of the cohesive forces between the ultimate particles of the material.


Author(s):  
Shanu Sharma

Abstract: As everyone is aware of the fact that Natural Coarse Aggregate (NCA) is the main constituent of traditional concrete mixes. Whenever an existing concrete structure is demolished, it produces smashed concrete waste in the large amount. Concrete waste give rise to negative effects on the environment. To evade the environmental pollution and mark effective reuse of the concrete waste as Recycled Aggregates in the place of NCA. This operative initiative provides an opportunity to reduce air pollution and soil exploitation to some extent. Such concrete is sustainable in nature and also eco-friendly to the environment. Also, such waste material will lower the usage of naturally occurring stone to produce NCA and thus various natural energy resources will be safeguarded. This study covers the suitability norms for a material to be used for Recycled Aggregate. In this study the natural aggregate is replaced with recycled aggregate in the different percentages (0%, 25%, 50%). When percentage of recycled aggregate mixed in the fixed proportion as percentage replacement to natural aggregates, it imparts improvement in the property of fresh as well as hardened concrete like, compressive strength & split tensile strength. Laboratory results of this research indicates that the value of compressive strength, tensile strength stress-strain curve & NDT of these mixes drives on decreasing, but at the 25% replacement level, it achieves target mean strength. Hence, for the fundamental concrete mix Natural Coarse Aggregate can be efficiently replaced by the Recycled Aggregate to the range of 25%. Keywords: Concrete, Recycled aggregate, Natural Coarse Aggregate (NCA), Compressive Strength, Tensile strength, , NDT, Stress-Strain Curve


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