Enhanced Anti-Wear Performance Induced by Innovative Base Oil in Low Viscosity Engine Oil

Author(s):  
Nicolas Champagne ◽  
Nicolas Obrecht ◽  
Arup Gangopadhyay ◽  
Rob Zdrodowski ◽  
Z Liu
2020 ◽  
Author(s):  
Sachiko Okuda ◽  
Hiroki Saito ◽  
Seiichi Nakano ◽  
Yusuke Koike ◽  
Takumaru Sagawa ◽  
...  

2017 ◽  
Vol 10 (2) ◽  
pp. 469-477 ◽  
Author(s):  
Takumaru Sagawa ◽  
Seiichi Nakano ◽  
Yohei Bito ◽  
Yusuke Koike ◽  
Sachiko Okuda ◽  
...  

Author(s):  
Derek Bain ◽  
Dana Fisk ◽  
Camila Gomez Serrano ◽  
Samantha Orlando ◽  
Patricia Iglesias

A supercharger is a mechanical device that can be added to an engine of a car to increase engine power. It works by sucking air in at atmospheric pressure into the rotors and compressing it at high revolutions per minute. With the rotors spinning at high speeds, the supercharger gears are exposed to high values of friction and wear, which results in a reduction of their service life. Ionic liquids (ILs) are substances that possess unique lubricating abilities when added to base oil or when used as neat lubricants. Properties include low volatility, non-flammability, as well high thermal resistance. These liquids are able to form ordered layers and tribofilms on the contacting surfaces which further protects the surface materials. In this work, the effect of adding ILs to low viscosity synthetic oil used to lubricate gears and to organic oil was investigated in the reduction of friction and overall wear of superchargers. Mobil 1 5W-30 Full Synthetic Engine Oil (MS) was used as a control and compared to coffee bean oil (CB). Additionally, the performance of these oils was observed with ionic liquids as additives at 1 wt. %. The chosen IL consisted of the cation Trihexyltetradecylphosphonium, [P6,6,6,14]+, with the anion Bis(trifluoromethylsulfonyl) amide, [NTf2]−. Lubricated flat disks of AISI 52100 stainless steel and 420C steel balls were studied using a Pin-on-Disk configuration. A total sliding distance of 500 meters was tested with a wear track diameter of 20 mm. Wear volume and average friction coefficient were measured according to ASTM-G99. Results showed that the addition of the ILs to the CB and MS reduced friction coefficient of the steel disks at medium speeds, and wear values achieved were comparable to the friction observed. The wear width values were also found to be reduced at medium speeds.


2020 ◽  
Vol 142 (12) ◽  
Author(s):  
Dongya Zhang ◽  
Zhongwei Li ◽  
Xian Wei ◽  
Liping Wang ◽  
Jinbao Xu ◽  
...  

Abstract Recently, the synergistic tribological properties between molybdenum dialkyldithiocarbamate (MoDTC) and metal detergents have been the focus of significant attention due to the high requirements of engine oil. In this study, an SRV tribometer and four-ball machine were used to study the tribological performance of MoDTC combined with three types of metal detergents with different base numbers. Meanwhile, the detergency of the three metal detergents was also investigated using the hot tube test and crankcase simulation test. The results showed that (i) a high-based detergent possessed an excellent detergency performance compared with that of low-based detergents. (ii) The tribological properties of the base oil with a content of 0.75% MoDTC were superior to those of other contents at elevated temperatures. (iii) The metal detergents with a higher base number showed the best thermal stability, detergency performance, and anti-wear performance among the three types of metal detergents. The anti-wear mechanism was that the synergistic action of active elements in MoDTC and metal detergents promoted the generation of a tribological film.


2011 ◽  
Vol 328-330 ◽  
pp. 203-208 ◽  
Author(s):  
Cheng Bin Chen ◽  
Da Heng Mao ◽  
Chen Shi ◽  
Yang Liu

Nano-WS2(tungsten disulfide nanoparticles)lubricating oil additive, prepared by the nanometer WS2particulates and semi-synthetic engine base oil as raw materials, was added into Great Wall engine oil with different mass ratio. With a contrast study on these oil samples, the results show that it can improve the extreme pressure, antiwear and viscosity-temperature properties of the engine oil effectively by adding a certain amount of nano-WS2additive, and the optimal concentration is 2wt%. The oil film strength, sintering load and viscosity index of this lubricating oil is respectively 1.35 times, 1.58 times and 1.05 times as that of Great Wall engine oil. In addition, when tested under the grinding conditions of 392 N, 1450 r /min and 30 min, the diameter of worn spot reduces 0.018mm, and the average friction coefficients of friction pairs decrease 16.3%, both of which are lubricated by the oil containing nano-WS2additive. Meanwhile, the experiments testify that the tribological and viscosity-temperature properties of the nano-WS2additive are better than that of the Henkel MoS2additive.


Author(s):  
Moussa Diaby ◽  
Michel Sablier ◽  
Anthony Le Negrate ◽  
Mehdi El Fassi

On the basis of ongoing research conducted on the clarification of processes responsible for lubricant degradation in the environment of piston grooves in EGR diesel engines, an experimental investigation was aimed to develop a kinetic model which can be used for the prediction of lubricant oxidative degradation correlated to endurance test conducted on engines. Knowing that base oils are a complex blend of paraffins and naphtenes with a wide range of sizes and structures, their chemistry analysis during the oxidation process can be highly convoluted. In the present work, investigations were carried out with the squalane (C30H62) chosen for its physical and chemical similarities with the lubricant base oils used during the investigations. Thermo-oxidative degradation of this hydrocarbon was conducted at atmospheric pressure in a tubular furnace, while varying temperature and duration of the tests in order to establish an oxidation reaction rate law. The same experimental procedures was applied to squalane doped with two different phenolic antioxidants usually present in engine oil composition: 2,6-di-tert-butyl-4-methylphenol (BHT), and octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate (OBHP). Thus, the effect of both antioxidants on the oxidation rate law was investigated. Data analysis of the oxidized samples (FTIR spectroscopy, gas chromatography/mass spectrometry GC/MS) allowed to rationalize the thermo-oxidative degradation of squalane. The resulting kinetic modelling provides a practical analytical tool to follow the thermal degradation processes, which can be used for prediction of base oil hydrocarbon ageing. If experiments confirmed the role of phenolic additives as an affective agent to lower oxidation rates, the main results lay in the observation of a threshold temperature where a reversed activity of these additives was observed.


Metals ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 120
Author(s):  
Zhijie Li ◽  
Fei Ma ◽  
Dongshan Li ◽  
Shanhong Wan ◽  
Gewen Yi ◽  
...  

Ni–Co–P/Si3N4 composite coatings were fabricated over an aluminum–silicon (Al–Si) substrate using a pulse-current electroplating process, in which the rapid deposition of an intermediate nickel–cobalt layer was used to improve coating adhesion. The microstructure, mechanical, and tribological behaviors of the electroplated Ni–Co–P/Si3N4 composite coating were characterized and evaluated. The results revealed that the electroplated Ni–Co–P/Si3N4 composite coating primarily consisted of highly crystalline Ni–Co sosoloid and P, and a volumetric concentration of 7.65% Si3N4. The electroplated Ni–Co–P/Si3N4 composite coating exhibited hardness values almost two times higher than the uncoated Al–Si substrate, which was comparable to hard chrome coatings. Under lubricated and dry sliding conditions, the electroplated Ni–Co–P/Si3N4 composite coating showed excellent anti-wear performance. Whether dry or lubricated with PAO and engine oil, the composite coating showed minimum abrasive wear compared to the severe adhesive wear and abrasive wear observed in the Al–Si substrate.


Author(s):  
Wang Liping ◽  
Zhang Dongya ◽  
Wu Hongxing ◽  
Xie Youbai ◽  
Dong Guangneng

Oxidation stability plays an important role on the engine oil service performance. In this paper, the phosphorus-free antioxidants of diphenylamine, hindered phenol and dibutyldithiocarbamate, combined with zinc dialkyldithiophosphate were added as antioxidants in the base oil and the fully formulated 5W-30 oil, and the oxidation stabilities were evaluated by pressurized differential scanning calorimetry and Romaszewski oil bench oxidation standard tests. Meanwhile, the tribological properties of the fresh and aged oils were evaluated by a SRV tribo-meter. The results indicated that (i) an optimal ternary complex antioxidant of dibutyldithiocarbamate: diphenylamine: hindered phenol (ratio of 2:1:2) displayed good antioxidation property, and (ii) the fully formulated 5W-30 oil containing optimized ratio phosphorus-free antioxidants had better tribological properties than the commercial SN 5W-30 oil.


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