scholarly journals Geochemical Fractionation and Risk Assessment of Potentially Toxic Elements in Sediments from Kupa River, Croatia

Water ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 2024
Author(s):  
Sanja Sakan ◽  
Stanislav Frančišković-Bilinski ◽  
Dragana Đorđević ◽  
Aleksandar Popović ◽  
Sandra Škrivanj ◽  
...  
Keyword(s):  
Risk Assessment ◽  
Magnetic Susceptibility ◽  
Sequential Extraction ◽  
Ecological Risk ◽  
Risk Index ◽  
River Sediments ◽  
Toxic Element ◽  
Residual Fraction ◽  
Risk Assessment Code ◽  
Binding Forms

This study investigated the quality of Kupa River sediment using sequential extraction, ecological risk, and contamination indexes (Risk assessment code, Index of geoaccumulation, Enrichment factor, Ecological risk factor, Ecological risk index), determination of magnetic susceptibility of sediments, and statistical methods. The BCR sequential extraction technique was used for evaluating various element-binding forms. Most of the elements were considered to be immobile due to the high availability in the residual fraction. Lead was present mainly in the reducible fraction, while more easily mobile and bioavailable forms were predominant for cadmium and barium. Sediment samples from the river catchment exhibited low ecological risk. The most toxic element, Cd, is the main contributor to the total potentially ecological risk. Increased values of contamination factors have been observed for Zn, Cr, and Ba in some localities. Results of the comparison of element contents in sediments in a 15-year period (2018 vs. 2003) indicated that the situation with toxic element content in sediments along Kupa River improved formost of its course. Unfortunately, on the lower course of the river, the situation has worsened. Using the example of Kupa River sediments, it was shown that the magnetic susceptibility method is excellent indetecting increased values of Cr.

scholarly journals Reforestation Impacted Soil Heavy Metal Fractionation and Related Risk Assessment in the Karst Area, Southwest China

Forests ◽  
2021 ◽  
Vol 12 (7) ◽  
pp. 891
Author(s):  
Qian Zhang ◽  
Guilin Han ◽  
Xingliang Xu
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Ecological Risk ◽  
Southwest China ◽  
Risk Index ◽  
Contamination Factor ◽  
Karst Area ◽  
Risk Assessment Code ◽  
Bcr Sequential Extraction ◽  
Soil Heavy Metals

Human agricultural activities have resulted in widespread land degradation and soil contamination in the karst areas. However, the effects of reforestation after agricultural abandonment on the mobility risks and contamination of heavy metals have been rarely reported. In the present study, six soil profiles were selected from cropland and abandoned cropland with reforestation in the Puding karst regions of Southwest China. The Community Bureau of Reference (BCR) sequential extraction method was used to evaluate the compositions of different chemical fractions of soil heavy metals, including Fe, Mn, Cr, Zn, Ni, and Cd. The total contents of Cr, Ni, Zn, Cd, and Mn in the croplands were significantly higher than those in the abandoned croplands. For all soils, Cr, Ni, Zn, and Fe were mainly concentrated in the residual fractions (>85%), whereas Mn and Cd were mostly observed in the non-residual fractions (>65%). The non-residual fractions of Cd, Cr, Ni, and Zn in the croplands were higher than those in the abandoned croplands. These results indicated that the content and mobility of soil heavy metals decreased after reforestation. The individual contamination factor (ICF) and risk assessment code (RAC) showed that Cd contributed to considerable contamination of karst soils. The global contamination factor (GCF) and potential ecological risk index (RI) suggested low contamination and ecological risk of the investigated heavy metals in the croplands, moreover they can be further reduced after reforestation.

scholarly journals Sequential extraction and risk assessment of pollutants from one major tributary of the Ganga

2021 ◽  
Author(s):  
Vinay Kumar ◽  
Pokhraj Sahu ◽  
Markandeya
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
High Risk ◽  
Sequential Extraction ◽  
Hierarchical Cluster ◽  
Residual Fraction ◽  
Toxic Heavy Metals ◽  
Risk Assessment Code ◽  
Bed Sediments ◽  
Gomti River

Abstract The geochemical fractionation of toxic heavy metals Cd, Pb, Cr, Co, Mn, Ni, Cu, Fe and Zn was investigated in 10 different sites of river bed sediments (up, mid and downstream) of Gomti River at Lucknow city. Sequential extraction technique was used to identify the distribution of trace elements binding in different fractions i.e., exchangeable, carbonate, Fe and Mn oxide, organic matter and residual. Heavy metal concentrations were least at upstream and significantly higher in mid and downstream. Fractionation indicated that dominant metals were bound in residual fraction to the bed sediments except for Cd and Pb which were bound in an equivalent fraction. Geo-accumulation index factor reveals that the enrichment of heavy metals in the bio-available fraction is contributed anthropogenically. Hierarchical cluster analysis also shows the metal pollution load in the river. Risk assessment code of Cd and Ni showed very high risk (ranged from 54.41 to 85.56 and 20.57 to 44.92 respectively) followed by Pb (high risk), Zn, Co (medium risk), Cr, Mn, Cu, Fe (low risk) in Gomti River water. Further, concentrations of Cd and Pb at mid Lucknow were 31 and 75%, high enough to pose a substantial risk to the environment.

scholarly journals Soil from an Abandoned Manganese Mining Area (Hunan, China): Significance of Health Risk from Potentially Toxic Element Pollution and Its Spatial Context

2020 ◽  
Vol 17 (18) ◽  
pp. 6554 ◽  
Author(s):  
Xin Luo ◽  
Bozhi Ren ◽  
Andrew S. Hursthouse ◽  
Jonathan R. M. Thacker ◽  
Zhenghua Wang
Keyword(s):  
Risk Assessment ◽  
Health Risk ◽  
Ecological Risk ◽  
Pearson Correlation ◽  
Risk Index ◽  
Mining Area ◽  
Carcinogenic Risk ◽  
Toxic Element ◽  
Hunan Province ◽  
Potentially Toxic Element

This study assessed the significance and potential impact of potentially toxic element (PTE) (i.e., Mn, Pb, Cu, Zn, Cr, Cd, and Ni) pollution in the surface soil from an abandoned manganese mining area in Xiangtan City, Hunan Province, China, on the health of residents. The risks were sequentially evaluated using a series of protocols including: the geo-accumulation index (Igeo), pollution load index (PLI), potential ecological risk index (RI), and implications for human health from external exposures using the hazard quotient (HQ), hazard index (HI) and carcinogenic risk (CR). The results revealed that Mn and Cd were the major pollutants in the soil samples. The ecological risk assessment identified moderate risks, which were mainly derived from Cd (82.91%). The results of the health risk assessment revealed that generally across the area, the non-carcinogenic risk was insignificant, and the carcinogenic risk was at an acceptable level. However, due to local spatial fluctuation, some of the sites presented a non-carcinogenic risk to children. The soil ingestion pathway is the main route of exposure through both non-carcinogenic and carcinogenic risks, with Mn being the major contributor to non-carcinogenic risk, with Cr and Cd the major contributors to carcinogenic risk. In addition, three pollution sources were identified through the Pearson correlation coefficient and principal component analysis (PCA), which included: a. mining activities and emissions from related transportation; b. natural background; c. agricultural management practices and municipal sewage discharge. The study provides information on the effects of spatial variation for the development of the abandoned mining areas and a useful approach to the prioritization of locations for the development and utilization of soil in these areas in China.

scholarly journals An Assessment of Heavy Metal Contamination in the Nakdong River Around the Weir

Water ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 684
Author(s):  
Hee Won Son ◽  
Sun Hee Shim ◽  
Haeseong Oh ◽  
Jung Hyun Choi
Keyword(s):  
Heavy Metals ◽  
Sequential Extraction ◽  
Environmental Protection Agency ◽  
Heavy Metal Contamination ◽  
Environmental Research ◽  
Residual Fraction ◽  
Nakdong River ◽  
Risk Assessment Code ◽  
The Nakdong River ◽  
Reducible Fraction

In this study, the concentrations and characteristics of copper (Cu), zinc (Zn), and lead (Pb) contamination in sediment samples were investigated using aqua regia extraction and Tessier’s five-step sequential extraction. Based on the concentration of metals, the influence of the Hapcheon-Changnyeong weir on sediments in the Nakdong River was assessed. The origins of the contaminants, their bioavailability, and their mobility were determined using sequential extraction. Greater concentrations of heavy metals were found in samples collected closer to the weir. The largest proportion of Cu was identified in the residual fraction based on sequential extraction, whereas Zn was predominantly found in the reducible fraction. Iron-manganese in the reducible fraction of Zn has the potential to leach back to the water body. In addition, the combined concentration of fractions 1 and 2 of Cu comprised more than 20% of total amount that still has potential to affect the water quality. The results of this study were compared with existing sediment standards set out by the NIER (National Institute of Environmental Research), Canada, and US EPA (United States Environmental Protection Agency) guidelines, as well as the risk assessment code (RAC). The concentrations of heavy metals exceeded the standards set by the Canadian guideline by up to four times in particular samples, highlighting the need for continual monitoring.

Research on the Morphological of Lead and Zinc in the Smelting Slag

2015 ◽  
Vol 1088 ◽  
pp. 200-205
Author(s):  
Lin Yu ◽  
Dong Wei Li
Keyword(s):  
Heavy Metals ◽  
Sequential Extraction ◽  
Ecological Risk ◽  
Total Content ◽  
Residual Fraction ◽  
Bcr Sequential Extraction ◽  
Lead And Zinc ◽  
Smelting Slag ◽  
Reducible Fraction

In this paper analysed the forms of heavy metals (Zn Pb Cd and As) of the Smelting Slag for Lead and Zinc,using BCR sequential extraction. Different chemical morphological of heavy metals have different activity and harmfulness. Migration and Utilization of heavy metals were decided by the existent form of heavy metals in the soil,which influenced Bioactivity and Toxicity. The results show that the main forms of Zn and Cd are Oxidizable and Residual fraction, and Pb mainly occurred in Oxidizable and Reducible fraction. however, As mainly occurred in Residual fraction, which the percentage of reachs 99.56%. According to the percentage of fractions extracted in total content (As is 0.44%, Zn is 14.7%, Pb is 85.98%, Cd is 48.86%),the latent ecological risk of heavy metals varied in the descending order of,Pb Cd Zn and As.

scholarly journals Speciation Variation and Comprehensive Risk Assessment of Metal(loid)s in Surface Sediments of Intertidal Zones

2018 ◽  
Vol 15 (10) ◽  
pp. 2125 ◽  
Author(s):  
Baocui Liang ◽  
Xiao Qian ◽  
Shitao Peng ◽  
Xinhui Liu ◽  
Lili Bai ◽  
...  
Keyword(s):  
Risk Assessment ◽  
Surface Sediments ◽  
Yellow River ◽  
Biological Effects ◽  
Risk Index ◽  
Sediment Quality ◽  
Residual Fraction ◽  
Intertidal Zones ◽  
Probable Effect Level ◽  
Effect Level

Speciation variation and comprehensive risk assessment of metal(loid)s (As, Cd, Cr, Cu, Mn, Ni, Pb and Zn) were investigated in surface sediments from the intertidal zones of the Yellow River Delta, China. Results showed that only the concentrations of As, Cd and Pb were significantly different between April and September (p < 0.01). In April, the residual fraction (F4) was predominant for As, Cr, Cu, Ni and Zn. However, the exchangeable and carbonate-associated fraction (F1) was dominant for Cd averaging 49.14% indicating a high environmental risk. In September, the F4 fraction was predominant and the F1 fraction was very low for most metal(loid)s except Cd and Mn. The geo-accumulation index (Igeo), the F1 fraction and potential ecological risk index (PERI) of most metal(loid)s were relatively low in surface sediments for both seasons. But Pb, As and Ni were between the threshold effect level (TEL)and the probable effect level (PEL) for 66.67%, 83.33% and 91.67% in April and As and Ni were between TEL and PEL for 41.67% and 91.67%, which indicated that the concentration of them was likely to occasionally exhibit adverse effects on the ecosystem. Although the Igeo, the F1 fraction or PERI of Cd in both seasons was higher at some sites, the results of sediment quality guidelines (SQGs) indicated that the biological effects of Cd were rarely observed in the studied area.

scholarly journals Geochemistry pollution status and ecotoxicological risk assessment of heavy metals in the Pahang River sediment after the high magnitude of flood event

2020 ◽  
Author(s):  
K. Y. Lim ◽  
N. A. Zakaria ◽  
K. Y. Foo
Keyword(s):  
Heavy Metals ◽  
Ecological Risk ◽  
River Sediment ◽  
Risk Index ◽  
River Sediments ◽  
Sediment Quality ◽  
Contamination Factor ◽  
Potential Ecological Risk ◽  
Flood Event ◽  
Pollution Status

Abstract The present work is aimed at assessing the aftermath effects of the 2014 flood tragedy on the distribution, pollution status and ecological risks of the heavy metals deposited in the surface river sediment. A series of environmental pollution indexes, specifically the enrichment factor (EF), geo-accumulation index (Igeo), contamination factor (CF), modified degree of contamination (mCd), pollution load index (PLI), potential ecological risk index (PERI) and sediment quality guidelines (SQGs) have been adopted. Results revealed that the freshly deposited sediments collected soon after the flood event were dominated by Cu, Fe, Pb, Ni, Zn, Cr and Cd, with the average concentrations of 38.74, 16,892, 17.71, 4.65, 29.22, 42.36 and 0.29 mg/kg, respectively. According to the heavy metal pollution indexes, Pahang River sediments were moderately to severely contaminated with Pb, Ni, Cu, Zn and Cr, while Cd with the highest risk of 91.09 was the predominant element that illustrated an aesthetic ecological risk to the water body after the tragic flood event. The findings highlighted a critical deterioration of the heavy metals content, driven by the catastrophic flood event, which has drastically altered their geochemical cycles, sedimentary pollution status and biochemical balance of the river's environment.

scholarly journals Heavy Metals Distribution, Sources, and Ecological Risk Assessment in Huixian Wetland, South China

Water ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 431
Author(s):  
Liangliang Huang ◽  
Saeed Rad ◽  
Li Xu ◽  
Liangying Gui ◽  
Xiaohong Song ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Ecological Risk ◽  
South China ◽  
Ecological Risk Assessment ◽  
Risk Index ◽  
Pollution Index ◽  
Principal Component ◽  
Potential Ecological Risk ◽  
Anthropogenic Sources

This research has focused on the source identification, concentration, and ecological risk assessment of eight heavy metals in the largest karst wetland (Huixian) of south China. Numerous samples from superficial soil and sediment within ten representative landuse types were collected and examined, and the results were analyzed using multiple methods. Single pollution index (Pi) results were underpinned by the Geoaccumulation index (Igeo) method, in which Cd was observed as the priority pollutant with the highest contamination degree in this area. As for the most polluted landuse type, via applying Nemerow’s synthetical contamination index (PN) and Potential ecological risk index (RI), the river and rape field posed the highest ecological risks, while moderate for the rest. To quantify the drivers of the contaminants, a principal component analysis (PCA) was carried out and weathering of the watershed’s parent carbonate rocks was found to be the main possible origin, followed by anthropogenic sources induced by agricultural fertilizer. Considering the impacts of these potentially toxic elements on public health, the results of this study are essential to take preventive actions for environmental protection and sustainable development in the region.

scholarly journals Evaluasi Potensi Sedimen Perairan Sebagai Sumber Kontaminan Logam Berat (Pb, Cu, Zn) Di Badan Air Pada Wilayah Reklamasi Lumpur Lapindo

2016 ◽  
Vol 12 (2) ◽  
pp. 142
Author(s):  
Novi Anitra ◽  
Barlah Rumhayati ◽  
Catur Retnaningdyah
Keyword(s):  
Risk Assessment ◽  
Sequential Extraction ◽  
Contamination Factor ◽  
Risk Assessment Code

<p>Tujuan dari penelitian ini adalah mengevaluasi potensi sedimen perairan di wilayah reklamasi lumpur Lapindo sebagai sumber kontaminan logam berat (Pb, Cu, Zn) di badan air muara Sungai Porong, Kabupaten Sidoarjo. Evaluasi dilakukan dengan menentukan nilai faktor kontaminasi (<em>Contamination Factor,</em> <em>CF</em>) dan kode penilaian resiko (<em>Risk Assessment Code, RAC) </em>berdasarkan konsentrasi fraksi geokimia logam berat dalam sedimen. Fraksi logam berat ditentukan dengan metode ekstraksi bertahap (<em>sequential extraction</em>) BCR dimodifikasi oleh Chakraborty. Sampel sedimen diambil pada dua lokasi di muara Sungai Porong, yaitu pada lokasi 1 yaitu 7°34'26.76" LS, 112°52'53.76" BT dan lokasi 2 yaitu 7°33'31.35" LS, 112°51'05.56"BT. Sampel diambil dengan menggunakan <em>Eickman Grab sampler</em>, disimpan dalam wadah gelap pada suhu 4<sup>0</sup>C. Konsentrasi logam berat ditentukan dengan Spektrofotometri Serapan Atom. Hasil penelitian menunjukkan bahwa pada kedua lokasi nilai CF(Cu) lebih tinggi dibandingkan CF(Pb) dan CF(Zn). Hal ini menunjukkan bahwa Cu memiliki waktu retensi lebih singkat dibandingkan kedua logam lainnya dalam sedimen. Dengan kata lain, Cu lebih mudah terlepas dari sedimen dan menuju badan air sehingga dapat mengkontaminasi badan air. Berdasarkan nilai RAC, sedimen di lokasi 2 memiliki potensi lebih besar melepaskan logam Cu dalam  fraksi 1 (fraksi logam berat terlarut dalam air pori sedimen) dan fraksi 2 (fraksi logam berat mudah tertukar dan dalam bentuk karbonat) yang dapat dimanfaatkan langsung oleh biota di badan air. Dapat disimpulkan bahwa meskipun mangrove yang ditanam di wilayah reklamasi Lumpur Lapindo dapat mengabsorpsi logam berat tetapi sedimen perairan di wilayah tersebut memiliki potensi sebagai sumber kontaminan Cu, terutama di wilayah reklamasi yang berhubungan dengan laut.</p>

scholarly journals Chemical Speciation, Bioavailability and Risk Assessment of Potentially Toxic Metals in Soils Around Petroleum Product Marketing Company as Environmental Degradation Indicators

2021 ◽  
Author(s):  
D. A Ayeni ◽  
Festus Mayowa ADEBIYI
Keyword(s):  
Risk Assessment ◽  
Ecological Risk ◽  
Chemical Speciation ◽  
Contamination Factor ◽  
Speciation Analysis ◽  
Residual Fraction ◽  
Potentially Toxic Metals ◽  
Analytical Technique ◽  
Accumulation Index ◽  
Product Marketing

Abstract The study aims at investigating chemical speciation, bioavailability and risk assessment of some selected metals in soils around refined petroleum depot using the concentrations of the metals as variables to ascertain the impacts of the activities within the petroleum depot. Surface-soils were got from within the premises of Pipelines and Product Marketing Company, Ibadan, Nigeria, while control samples were got at 200 m away from the study location. Electrical conductivity and pH were measured using a calibrated dual purpose meter, while elemental analysis was done using Atomic absorption spectroscopy analytical technique. The results showed that the soils exhibited low ecological risk; minor enrichment for Mn, moderately severe enrichment for Ni and Co, severe enrichment for Cr and extremely severe enrichment for Pb, Zn and Cd; low contamination factor by Pb, Ni, Mn, Cr, Co, and Fe and moderate contamination by Zn and Cd. Geo - accumulation index results indicated unpolluted with Ni, Mn, Cr, Co, and Fe, unpolluted to moderately polluted with Pb and Zn and moderately to strongly polluted with Cd. Inter-element clustering results indicated chemical affinity and/or similar genetic origin among the elements. Speciation analysis suggested that Fe, Co, Cr, Cd, and Ni occurred in the residual fraction; Pb, and Zn in the carbonate fraction, while Mn have its highest percentage in the Fe-Mn oxides fraction. Percentage mobility and bioavailability showed that most of the metals are immobile and non-bioavailable. Study concluded that the oil-impacted soils were contaminated with most of the metals, but with low ecological risk.

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