scholarly journals Soil from an Abandoned Manganese Mining Area (Hunan, China): Significance of Health Risk from Potentially Toxic Element Pollution and Its Spatial Context

Author(s):  
Xin Luo ◽  
Bozhi Ren ◽  
Andrew S. Hursthouse ◽  
Jonathan R. M. Thacker ◽  
Zhenghua Wang

This study assessed the significance and potential impact of potentially toxic element (PTE) (i.e., Mn, Pb, Cu, Zn, Cr, Cd, and Ni) pollution in the surface soil from an abandoned manganese mining area in Xiangtan City, Hunan Province, China, on the health of residents. The risks were sequentially evaluated using a series of protocols including: the geo-accumulation index (Igeo), pollution load index (PLI), potential ecological risk index (RI), and implications for human health from external exposures using the hazard quotient (HQ), hazard index (HI) and carcinogenic risk (CR). The results revealed that Mn and Cd were the major pollutants in the soil samples. The ecological risk assessment identified moderate risks, which were mainly derived from Cd (82.91%). The results of the health risk assessment revealed that generally across the area, the non-carcinogenic risk was insignificant, and the carcinogenic risk was at an acceptable level. However, due to local spatial fluctuation, some of the sites presented a non-carcinogenic risk to children. The soil ingestion pathway is the main route of exposure through both non-carcinogenic and carcinogenic risks, with Mn being the major contributor to non-carcinogenic risk, with Cr and Cd the major contributors to carcinogenic risk. In addition, three pollution sources were identified through the Pearson correlation coefficient and principal component analysis (PCA), which included: a. mining activities and emissions from related transportation; b. natural background; c. agricultural management practices and municipal sewage discharge. The study provides information on the effects of spatial variation for the development of the abandoned mining areas and a useful approach to the prioritization of locations for the development and utilization of soil in these areas in China.

Processes ◽  
2021 ◽  
Vol 9 (9) ◽  
pp. 1532
Author(s):  
Jing Bai ◽  
Wen Zhang ◽  
Weiyin Liu ◽  
Guohong Xiang ◽  
Yu Zheng ◽  
...  

A field survey was conducted to determine the pollution grade, sources, potential ecological risk, and health risk of soil potentially toxic elements (PTEs) in Xikuangshan Mine (XKS), the largest antimony (Sb) deposit in the world. A total of 106 topsoil samples were collected from 6 sites in XKS to measure the concentrations of PTEs Cr, Zn, Cd, Pb, As, Hg, and Sb. The results show that the average concentrations of these elements at all six sites were generally greater than their corresponding background values in Hunan province, especially Sb, Hg, and As. Correlation and principal component analyses suggested that Cd, Zn, Pb, Hg, and Sb were primarily released from mining and other industrial and human activities, while Cr and As were mainly impacted by the parent material from pedogenesis. A risk index analysis showed that, overall, sites were at very high ecological risk, and Sb is the highest ecological risk factor, followed by Cd and Hg. According to health risk assessment, oral ingestion is the main non-carcinogenic and carcinogenic risk exposure route. The higher potentially non-carcinogenic and carcinogenic risks happen to the local children who live in the vicinity of mining area. It revealed that the mining and smelting processes of XKS have negatively influenced the local people, therefore, we should pay increasing attention to this practical issue and take effective measures to protect the ecology of XKS.


2021 ◽  
Author(s):  
Fangfang Miao ◽  
Yimei Zhang ◽  
Shuai Li ◽  
Yaxiao Duan ◽  
Yuxian Lai ◽  
...  

Abstract Soil heavy metal contaminated sites with multiple sources of pollution have caused worldwide public concern. However, the lack of correlation of risk assessment or source identification of heavy metal leads to unclear direction of source governance. Although previous studies have involved different risk assessment, few attempts have been made to establish a link between them. In order to design a comprehensive risk assessment system, it is necessary to identify the specific source risks and the correlation and comparison between environmental risk assessment. In this paper, a methodology was established by combining source apportionment of ecological risks and human health risks (SERA) to characterize the sources and source-specific risks of heavy metals in soil. Positive matrix factorization (PMF) model was used to identify and classify potential sources of heavy metals in the study area. According to the results, they will be incorporated into the environmental risk model to evaluate environmental risk of the identified sources of heavy metals. The results showed that concentrations of Cd and Hg were highly above the background values, indicating a moderate enrichment. It was worth noting that the source contributed ecological risk index (SCEI) of Hg, with the value of 51.16 contributed mainly by the pollutant sources of waste treatment, has reached moderate ecological risk. The SCEI of Cd contributed by industrial activities (the wastewater and dyeing process) showed the most predominant source of contribution. The source contributed human health risk index (SCHI) of As contributed most by pollutant sources of agriculture activities. Overall, the modified total health risk posed by soil heavy metals SCHI was 1.11E+00, showing potential risk to the residents. This study provides a new insight for the treatment of mutil-sources of soil heavy metal pollution and also some reference value for the improvement of the risk assessment system.the main finding: Exploring a methodology (SERA) to quantitatively characterize the relationship between pollutants sources and environmental risk assessment based on source contribution.


Water ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 2024
Author(s):  
Sanja Sakan ◽  
Stanislav Frančišković-Bilinski ◽  
Dragana Đorđević ◽  
Aleksandar Popović ◽  
Sandra Škrivanj ◽  
...  

This study investigated the quality of Kupa River sediment using sequential extraction, ecological risk, and contamination indexes (Risk assessment code, Index of geoaccumulation, Enrichment factor, Ecological risk factor, Ecological risk index), determination of magnetic susceptibility of sediments, and statistical methods. The BCR sequential extraction technique was used for evaluating various element-binding forms. Most of the elements were considered to be immobile due to the high availability in the residual fraction. Lead was present mainly in the reducible fraction, while more easily mobile and bioavailable forms were predominant for cadmium and barium. Sediment samples from the river catchment exhibited low ecological risk. The most toxic element, Cd, is the main contributor to the total potentially ecological risk. Increased values of contamination factors have been observed for Zn, Cr, and Ba in some localities. Results of the comparison of element contents in sediments in a 15-year period (2018 vs. 2003) indicated that the situation with toxic element content in sediments along Kupa River improved formost of its course. Unfortunately, on the lower course of the river, the situation has worsened. Using the example of Kupa River sediments, it was shown that the magnetic susceptibility method is excellent indetecting increased values of Cr.


Author(s):  
Xin Luo ◽  
Bozhi Ren ◽  
Andrew S. Hursthouse ◽  
Feng Jiang ◽  
Ren-jian Deng ◽  
...  

Abstract Potentially toxic elements (PTEs) in manganese ore areas are prevalent in rainwater runoff and pose a major threat to human health. In this study, field investigation and geostatistical analysis methods of Positive Matrix Factorization (PMF) and Geographic Information System (GIS) were used to systematically study the pollution in rainwater runoff from a manganese mining area in Xiangtan, China, to evaluate source contributions in the health risk assessment of PTEs. The average concentrations (mg/L) of six PTEs were: 0.3357 (Mn), 0.0450 (Ni), 0.0106 (Cu), 0.0148 (Zn), 0.0068 (Cd) and 0.0390 (Pb). The Coefficients of Variation (CV) for Mn and Zn were >180% and >130%, with the other analytes having values below 70%. The GIS and PMF analysis produced more refined spatial source apportionments, such as mining, smelting, transportation, agricultural production and natural sources. The results of the health risk assessment showed that the non-carcinogenic risk was negligible, and the carcinogenic risk was potentially dangerous but acceptable for both adults and children. In addition, the children's total carcinogenic risk value was greater than that of adults, highlighting their vulnerability. This study demonstrates the potential of PMF to provide a framework to spatially prioritize treatment objectives within the mining region to improve environmental conditions.


2021 ◽  
Vol 33 (1) ◽  
Author(s):  
Prince Chapman Agyeman ◽  
Kingsley John ◽  
Ndiye Michael Kebonye ◽  
Luboš Borůvka ◽  
Radim Vašát ◽  
...  

Abstract Background Human activities considerably contribute to polluting potentially toxic element (PTEs) levels in soils, especially agricultural soils. The consistent introduction of PTEs in the environment and the soil pose health-related risks to humans, flora and fauna. One hundred and fifteen samples were collected in the district of Frydek Mistek (Czech Republic) in a regular grid form. The soil samples were air-dried, and the concentrations of PTEs (i.e. lead, arsenic, chromium, nickel, manganese, cadmium, copper, and zinc) were determined by ICP-OES (inductively coupled plasma optical emission spectrometry). The purpose of this study is to create digitized soil maps that expose the human-related health risks posed by PTEs, estimate pollution indices, ascertain the spatially distributed patterns of PTEs, source apportionment and quantify carcinogenic and non-carcinogenic health risks using the sample location approach. Results The results revealed that the pollution assessment of the soils in the study area using diverse pollution assessment indexes (pollution index, pollution load index, ecological risk and risk index), based on the application of the local background value and the European average value, displayed a range of pollution levels due to differences in the threshold limits from differing geochemical background levels. The principal components analysis and positive matrix factorization, respectively, identified the sources of pollution and the distribution of PTE sources. Mapping the health index and total carcinogenic risk highlighted hotspots of areas within the study area that require immediate remediation. The self-organizing map (SeOM) revealed a diversified colour pattern for the factor scores. A single neuron exhibited a high hotspot in all factor loadings on different blocks of neurons. Children’s CDItotal (Chronic Daily Intake total) values for non-carcinogenic risk and carcinogenic risk were found to be greater than adults’, as were their HQ (hazard quotients) and CR (carcinogenic risk) values. According to the health index of non-carcinogenic risk, 6.1% of the study area sampled posed a potential risk to children rather than adults. Corresponding to the sampled pointwise health risk assessment, 13.05% of the sampled locations are carcinogenic to children. The estimated health risk in the agricultural soil was high, with both carcinogenic and non-carcinogenic risks that could threaten persons living in the study area, particularly children. Conclusion In general, the continuous application of agriculturally related inputs such as phosphate fertilizers and other anthropogenic activities (e.g., steel industry) can increase the level of PTEs in soils. The use of mean, maximum, and minimum values in health risk estimation does not provide a comprehensive picture of a research area’s health state. This study recommends using a sampled pointwise or location health risks assessment approach, which allows researchers to identify high-risk environments that exceeds the recommended threshold as well as areas on the verge of becoming high risk, allowing for rapid remedial action.


2021 ◽  
Author(s):  
Fangfang Miao ◽  
Yimei Zhang ◽  
Yu Li ◽  
Qinglu Fang ◽  
Yinzhuang Zhou

Abstract Soil heavy metal contaminated sites with multiple sources of pollution have caused worldwide public concern. However, the lack of correlation of risk assessment between source identification of heavy metal led to unclear direction of source governance. A methodology was established by combining source apportionment of human health risks with ecological enrichment to characterize source-identified risks of heavy metals based on Ordinary kriging interplotation. Principal component analysis (PCA) and positive matrix factorization (PMF) model were used to identify and classify potential sources of heavy metals synthetically. The integrated results were incorporated into the health risk model to evaluate potential non-carcinogenic and carcinogenic risk of soil heavy metals. A case study was conducted in Suzhou city of China. The results showed that concentrations of Cd and Hg were highly above the background values, accounting for percentages of 239.6% and 415.9% above background values, respectively. The source contributed human health risk index of As contributed 76.9% to non-carcinogenic risk by pollutant sources of agriculture activities. The Non-cancer health risk index for children and adults was 1.08 and 1.00 respectively. The cancer health risk was 3.67E-03 for children and 3.97E-04 for adults. Cr originated from indutriy activities, accounting for 29.5% of total heavy metals, and constituted the largest carcinogenic impact on the population. This study provided a new insight for the treatment of mutil-sources of soil heavy metal pollution and also some reference value for the improvement of the risk assessment system.


2020 ◽  
Vol 20 (2) ◽  
pp. 1-10
Author(s):  
J. Seidu ◽  
A. Ewusi

This study seeks to evaluate the hydrogeochemical characteristics of water in the Tarkwa mining area using the Piper and Chadha plots and to carry out a health risk assessment using the US Environmental Protection Agency (USEPA) health risk assessment model. A total of 39 groundwater sample points were used for this study. Results from the Piper and Chadha diagrams show that the dominant water types in the study area are Ca-HCO3 and Mixed Ca-Mg-Cl water types which indicates that groundwater in the area can be classified as fresh water. The hazard quotient (HQ) value for heavy metals estimated, suggested an acceptable level of noncarcinogenic inimical health risk. In relation to the HQ value, the Hazard Index (HQ) calculated was less than 1 suggesting that inhabitants will not be exposed to a potential health risk for the injection of heavy metals. Carcinogenic risk estimated for As (1.80×10-4) was higher than the acceptable risk. The carcinogenic risk estimated therefore indicated that, drinking of groundwater over a long period will increase the probability of cancer. It can be concluded that currently the groundwater in the Tarkwa area is safe for domestic purposes.   Keywords: Hydrochemical Characteristics, Human Risk Assessment, Tarkwa Mining Area


2019 ◽  
Vol 11 (18) ◽  
pp. 4828 ◽  
Author(s):  
Na Wang ◽  
Jichang Han ◽  
Yang Wei ◽  
Gang Li ◽  
Yingying Sun

Xunyang is rich in various metal minerals and is one of the four major metal mining areas in Shaanxi province, China. To explore the effects of soil heavy metals and metalloid pollution on the environment and human health around the mining areas, four places—Donghecun (D), Gongguan (G), Qingtonggou (Q) and Nanshagou (N)—were selected as the sampling sites. Potential ecological risk (PER) and health risk assessment (HRA) models were used to analyze the environmental and health risks around the mining areas. The concentration of heavy metals (Cd, Cr, Pb, Zn, Ni, Cu, Hg) and metalloid (As) in cultivated land in the vicinity of Xunyang mining areas indicated that, except for Cu, the remaining elements detected exceeded the threshold values at some sites. The geo-accumulation index (IGeo) revealed that soils in G and Q could be identified as being extremely contaminated. PER indicated that there was significantly high risk at G and Q for Hg. In N, Pb recorded the highest E r i , which also demonstrates a considerable pre-existing risk. HRA indicated that the hazard index (HI) for both carcinogenic and non-carcinogenic risks was much higher among children than among adults, and the ingestion pathway contributed the greatest risk to human health, followed by the dermal pathway and inhalation. Because the HI values of the metals and metalloid in the study areas were all lower than 1, there was no significant non-carcinogenic risk. However, the carcinogenic risk for Cr is relatively higher, surpassing the tolerable values in G, Q, and N. This study analyzed the ecological risks and human health risks of heavy metals and metalloid in farmland soils near the sampling mining areas, and demonstrated the importance of environmental changes caused by land development in the mining industry.


2021 ◽  
pp. 112349
Author(s):  
Ayub Ebadi Fathabad ◽  
Hossein Tajik ◽  
Moslem Lari Najafi ◽  
Khadijeh Jafari ◽  
Amin Mousavi Khaneghah ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document